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Big Science program on CHEMICAL EARTH: Global distribution and cycle of key elements
WANG Xueqiu
2025, 32(1): 1-10. 
DOI: 10.13745/j.esf.sf.2024.10.33

Abstract ( 145 )   HTML ( 37 )   PDF (7723KB) ( 277 )  

The Big Science Program on CHEMICAL EARTH was first proposed by Wang et al. in 2008. An initiative was lunched in 2016 by the UNESCO International Centre on Global-scale Geochemistry and accepted by the UNESCO in 2023. The goal was to establish a digital CHEMICAL EARTH presenting all naturally occuring chemical elements on Earth to provide data services for sustainable global development; the scientific and technical aims were to understand the spatiotemporal distribution and cyclying of key elements on Earth, and to develop high-quality laboratory chemical analysis and big data mining technology. This article summaries the major achievements to date. (1) A Global Geochemical Baselines Network is established covering 33% of the world’s land area. It provides spatial distribution patterns and geochemical baselines of 76 chemical elements, allowing delineation of REE, Li, Cu and Au super-enrichment targets and, whereby, the discovery of giant HREE deposits in Yunnan. (2) A global distribution map of eight toxic heavy metals in soil is completed. It finds that Europe has the highest pollution risks compared to China and the United States, with 48% of its land area exceeding the pollution risk limits for the studied heavy metals. This results from Europe’s long history of industrial development without early pollution control technology, allowing large-scale toxins release into the environment. (3) China Geochemical Observation Network is established based on three rounds of resampling campaigns throughout China. It finds significant increase of Cd, Hg, As, and Ca in the past 30 years, and that cycling of Hg occurs in the form of nano cinnabar (HgS) grains, not mercury vapor as traditionally recognized. (4) The program promotes public access to geochemical big data by providing QR codes, which allow anyone to query big data through websites and mobile phones. Geochemical big data show that farmlands in China’s major grain-produing regions overall are of good quality in terms of food safety.

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Super enrichment of critical elements: Implications for stratgic mineral resources
WNAG Xueqiu, LI Longxue, WU Hui, WANG Wei
2025, 32(1): 11-22. 
DOI: 10.13745/j.esf.sf.2024.10.40

Abstract ( 111 )   HTML ( 20 )   PDF (3521KB) ( 191 )  

The strategic mineral resources contain 56 critical elements, most of which have low crustal abundance and require 10-1000 folds of enrichment to form ore deposits. This results in extremely uneven distribution of mineral resources. Thus the delineation of super enrichment area is the key to the resource prospecting and discovery of large-sized ore deposits. The enrichment intensity of elements can be quantitatively expressed by the metallogenic acumulatioin index (m.a.i), the tonnagea acumulatioin index (t.a.i) and the anomalous concentration index (a.c.i). Statistical analyses of 35 strategic mineral species, including precious, non-ferrous, ferrous, rare and dispersed elements, rare earth elements and radioactive metals, revealed that (1) elements with a m.a.i greater than 1000 were antimony, bismuth, rhenium and gold; a m.a.i of >100-1000 were silver, tungsten, tin, chromium, lithium, cesium, tellurium, indium, uranium and platinum group elements; and a m.a.i of >10-100 were copper, nickel, chromium, beryllium, rubidium, scandium, niobium, tantalum, zirconium and primary rare earth elements. Iron, aluminium, titanium and ion-adsorbed rare earth elements had a m.a.i ≤10. (2) Large-sized ore deposits should have a t.a.i greater than 107, generally 1010, and a a.c.i greater than 2.0. Indicators for element super enrichment also included anomaly greater than >100-1000 km2, with anomalous hierarchical structure across more than three layers, and with occurence of at least four associated elements. The element enrichment factor and potential resources in a geochemical block may be estimated using areal and cubic metal contents. The qualitative and quantitative geochemical characteritics of element super enrichment provide evaluation criteria for the assessment and discovery of large-sized mineral deposits.

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Quantatitive robustness assessment of low-density geochemical mapping: An example of China’s cobalt
LIU Dongsheng, WANG Xueqiu, NIE Lanshi, ZHANG Bimin, ZHOU Jian, LIU Hanliang, WANG Wei, CHI Qinghua, XU Shanfa
2025, 32(1): 23-35. 
DOI: 10.13745/j.esf.sf.2024.10.34

Abstract ( 65 )   HTML ( 8 )   PDF (7972KB) ( 103 )  

Robustness is a fundamental scientific concern in low-density geochemical mapping, which has long garnered close attention from mapping researchers. However, quantitative understanding of robustness has been lacking due to the lack of effective quantitative assessment methods. In this study, using cobalt element data from two low-density mapping sources—the China Geochemical Baselines project (CGB) and the Regional Geochemical National Reconnaissance project (RGNR)—robustness is quantitatively assessed based on 1546 representative catchments through the utilization of local spatial correlation coefficients; the spatial distribution features and influencing factors are also discussed. On a national scale, robustness was influenced by sediment cobalt (Co) content and geochemical landscape conditions; on a local scale, it was affected by differential erosion in cobalt-rich and Co-poor source areas. In Co-poor environments (sediment Co<13 μg/g) the robustness index (R) value fluctuated around 0.4, while in Co-rich environments (sediment Co>13 μg/g) it increased from 0.4 to above 0.6 with rising Co content. Regions such as karst terrains, tropical rainforests, and semi-arid low hills had R values as high as 0.58 to 0.74, whereas alluvial plains and forested swamp regions had R values below 0.32. This study provides a reference for quantitative evaluaton of low-density mapping, deomonstrating that low-density geochemical mapping has good robustness and promising prospect in the global-scale geochemical mapping.

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Geochemical baseline of nickel in China: Characteristics and influence of geological setting
LI Longxue, WANG Xueqiu, CHI Qinghua, LIU Dongsheng, LIU Hanliang, ZHANG Bimin, ZHOU Jian, XU Shanfa, NIE Lanshi, WANG Wei, LIU Qingqing
2025, 32(1): 36-49. 
DOI: 10.13745/j.esf.sf.2024.10.27

Abstract ( 63 )   HTML ( 10 )   PDF (8149KB) ( 117 )  

The strategic value of nickel (Ni) continues to rise with the increase in demand for nickel from China’s new energy industries and infrastructure projects. Quantitative evaluation of nickel content and distribution is critical for nickel prospecting and for alleviating nickel shortage in China. The China Geochemical Baselines project (CGB) has established the geochemical baseline of Ni in China from 3382 top and 3380 deep catchment sediment/alluvial soil samples and 11602 rock samples. The Ni baseline (median value) and background levels in rock were 12.1×10-6 and 22.2×10-6, respectively, comparable to the Ni abundance level in exposed crust in eastern China, where ultrabasic and basic rocks had respectively baseline levels of 1317×10-6 and 63.4×10-6, much higher than intermediate (17.5×10-6) and felsic (3.19×10-6) rocks. In surface and deep layers of catchment sediment/alluvial soil the Ni baseline levels were 23.6×10-6 and 22.4×10-6, respectively, slightly lower compared to other continents (countries) and close to the average Ni level obtained from the Regional Geochemistry National Reconnaissance project (RGNR). Parent rock types, especially ultrabasic-basic rocks, predominantly controlled the distribution of Ni-enriched catchment sediments/alluvial soils. Nickel-enrichment areas (> 85th percentile) were mainly in regions with widespread ultrabasic-basic outcrops, such as ophiolite belts, large igneous provinces, and black shales along the middle-lower Yangtze River. Nickel anomalies correlated well with magmatic Ni deposits. The geological setting mainly controlled Ni geochemical baselines in the sampled environments, whereas strong chemical weathering and well developed carbonate rocks could also contribute to Ni enrichment. The geochemical baseline of nickel provide a reference and data basis for further quantitative resource evaluation and establishment of environmental baselines.

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Characteristics of boron geochemical anomalies and prediction of boron resource potential in China
LIU Qingqing, WANG Xueqiu, ZHANG Bimin, ZHOU Jian, WANG Wei, LIU Hanliang, LIU Dongsheng, ZHOU Yining, CHANG Chan
2025, 32(1): 50-60. 
DOI: 10.13745/j.esf.sf.2024.10.35

Abstract ( 59 )   HTML ( 8 )   PDF (3410KB) ( 98 )  

Boron (B) is a new strategic mineral widely used in modern high-tech industries. In recent years the exploration of boron mineral resource has received increasing attention as the demand for boron contineous to rise. The overall distribution characteristics of boron in China is very important for boron prospecting. Based on analyses of the 3380 deep soil samples collected by the China Geochemical Baseline (CGB) project, this paper reveals the geochemical and anomaly distribution characteristics of boron in China. We found that the average boron concentration in deep sediments/alluvial soil of China was 46.4 mg/kg, showing a trend of high in the south and low in the north, with contiguous distribution across five geochemical zones: northeastern China and eastern Inner Mongolia (Ⅰ); northwestern China (Ⅱ); northern China (Ⅲ); Qinghai-Tibet (Ⅳ) and southern China (Ⅴ). Taking 70.9 and 52.4 μg/g (cumulative frequency 85%) as the lower anomaly thresholds in the south and the north, respectively, we identified a total of 37 geochemical anomalies, which were classified into ten geochemical provinces and nine individual anomalies. According to the spatial distribution of boron anomalies, combined with the geological background and distribution of boron deposits, we further delineated nine metallogenic prospective areas. We suggest that more efforts should be made to explore boron-rich salt lake deposits, and that hard rock (marine sedimentary) boron deposits should be the next exploration target.

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Copper mineralization pattern and machine learning-based copper prospectivity prediction in Laos
ZHANG Bimin, WANG Xueqiu, ZHOU Jian, WANG Wei, LIU Hanliang, LIU Dongsheng, Sounthone LAOLO, Phomsylalai SOUKSAN, XIE Miao, DONG Chunfang, LIU Qingqing, LU Yuexin, WANG Haonan, HE Bin
2025, 32(1): 61-77. 
DOI: 10.13745/j.esf.sf.2024.10.43

Abstract ( 67 )   HTML ( 9 )   PDF (9668KB) ( 109 )  

Laos is located in the southeastern segment of the Tethyan metallogenic domain, in the southern extension of the Sanjiang metallogenic belt. It has abundant mineral resources but is lacking high-level geological research. Metallogenic and mineral prospectivity modeling, therefore, is an effective way to achieving major breakthroughs in mineral exploration in Laos. The 1∶1000000 national-scale geochemical mapping project in Laos has provided high-quality geochemical baseline data and maps for mineral resource and environmental evaluation. This paper utilizes data obtained from the mapping project, combined with the metallogenic pattern of known minerals in Laos, and applies machine learning techniques to predict propective copper resource areas. The results show that (1) the formation of copper deposits in Laos is significantly controlled by tectonic-magmatic-sedimentary processes. The main types of copper deposits are porphyry, skarn, hydrothermal, and sandstone. (2) The copper content in stream sediments of Laos ranged between 1.20-459 μg/g, with an average value of 21.96 μg/g and a median value of 16.50 μg/g. Among the seven tertiary tectonic units, the average copper content was higher in the Changshan block and three suture zones than in other tectonic units. Geochemical maps reveal uneven distribution of copper, with occurrence of several large, high background and anomaly areas. (3) A quantitative, multisource information prediction model for copper deposits in Laos was constructed, with model factors such as single-element anomalies, multielement combination anomalies, multielement combinations indicative of acidic rocks, the distribution of ore-controlling structures, and the distribution of carbonate and clastic rocks. (4) Using the Random Forest metallogenic prediction method, nine metallogenic prospective areas were delineated, which have great prospecting potential for various types of copper deposits, such as porphyry and skarn.

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Characterization of gold distribution in sediments and prediction of gold prospectivity in Laos
WANG Wei, WANG Xueqiu, ZHANG Bimin, LIU Dongsheng, LIU Hanliang, Sounthone LAOLO, Phomsylalai SOUKSAN, CHI Qinghua, ZHOU Jian, HAN Zhixuan
2025, 32(1): 78-90. 
DOI: 10.13745/j.esf.sf.2024.10.28

Abstract ( 53 )   HTML ( 10 )   PDF (4037KB) ( 87 )  

Under the Belt and Road initiative China and Laos have carried out national-scale 1∶1000000 geochemical mapping in Laos. This study marked the first national-scale geochemical study of gold, a dominant mineral species, in Laos, where the geochemical background and spatial distribution characteristics of gold in Laos were preliminarily investigated, and the geochemical anomaly and prospective areas of gold in Laos were delineated. A total of 2079 geochemical samples were collected and analyzed for gold element, using foam adsorption-graphite furnace atomic absorption spectrometry (FAS-GAAS), a high-precision analytical technique, and strict quality control measures. Gold contents in Laos aquatic sediments ranged between 0.10-913.70 ng/g, with mean and median (background) values of 2.44 and 1.00 ng/g, respectively. Gold occurred across the country with scattered distribution, mainly along extended large fractures affected by tectonic activities and magmatism. Using 85% quantile (1.99 ng/g) as the anomaly detecton limit, 17 gold anomaly areas were identified, with eight reaching a geochemical province scale (>1000 km2); seven prospective gold mineralization zones were classified according to anomaly identification, taking into consideration the spatial distribution of gold, geologic background, regional tectonics and mineral distribution. The results provide basic information for gold exploration in Laos and fill the gap of geochemical mapping for gold exploration in Laos.

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Geochemical characteristics and metallogenic potential analysis of porphyry copper deposits in Pakistan
ZHANG Jing, LI Tianhu, WANG Zhihua, Naghmah HAIDER, HONG Jun, ZHANG Huishan, LIANG Nan
2025, 32(1): 91-104. 
DOI: 10.13745/j.esf.sf.2024.10.45

Abstract ( 55 )   HTML ( 8 )   PDF (14140KB) ( 93 )  

The paper utilizes the geochemical data of stream sediments based on the national-scale (1∶1000000) geochemical mapping project in the outcrop area across Pakistan for the first time. This study aims to determine the geochemical background of copper in the study area, as well as the regional geochemical characteristics and geochemical anomalies associated with large porphyry copper deposits in Pakistan. The geochemical features of the main stratigraphic units and magmatic rocks within this region were examined. The average copper concentration in the outcrop areas of Pakistan is 23.48×10-6, with a background value of 18.6×10-6. This is comparable to the copper abundance found in northwest regions of China and the Tibetan Plateau. The magmatic rocks related to mineralization in porphyry systems are mainly Cenozoic and Mesozoic acid magmatic rocks, with average copper concentrations of 39.09×10-6 and 28.28×10-6, respectively, indicating that copper-rich porphyries are the main source of material. A modeling analysis of the elemental association of Cu, Au, Mo, Ag, Pb, Zn, Co and Cr has been conducted based on the national-scale geochemical data, indicating that the national-scale geochemical anomalies serve as indicators of large and super-large porphyry copper deposits. Based on the theory of geochemical block, the Pfd (Prospecting Favoralble Degress) and Qm (Quality of Mineral) were calculated and sorted by applying the principle and technical innovation of mineral resource potential prediction. On the basis of the geochemical model of typical porphyry copper deposits, with Cu, Mo, Au, Ag as primary indicator elements, and Pb, Zn, Co, Cr as secondary reference indicator elements, combined with the geological background, four prediction areas for porphyry copper deposits were identified. Furthermore, an analysis of the metallogenic potential of these identified prospecting areas was conducted.

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Geochemical distribution and metallogenic potential of Pb-Zn in Pakistan and its implications for mineral prospecting in sediment-hosted Pb-Zn deposits in the Tethys belt
ZHANG Huishan, SONG Yucai, LI Wenchang, MA Zhongping, ZHANG Jing, HONG Jun, LIU Lei, LÜ Pengrui, WANG Zhihua, ZHANG Haidi, YANG Bo, Naghmah HAIDER, Yasir Shaheen KHALIL, Asad Ali NAREJO
2025, 32(1): 105-126. 
DOI: 10.13745/j.esf.sf.2024.10.44

Abstract ( 64 )   HTML ( 10 )   PDF (17572KB) ( 103 )  

Pakistan, which is located between the Tibetan and Iranian Plateaus, is an important part of the Tethys Domain, where some lead-zinc deposits and ore occurrences have been revealed. The metallogenic pattern and the extend of lead-zinc mineralization zones, however, are unclear due to lack of systematic geological investigation, and the metallogenic potential of lead and zinc in Pakinstan remains undetermined. The low-density geochemical survey is an effective method to address the above issues. Based on the results of the 1∶1000000 low-density geochemical survey in Pakistan, this paper describes the geochemical background and geochemical anomaly distribution characteristics of lead and zinc in Pakistan. Combined with the regional geology and metallogeny, types, and key ore-controlling factors of lead-zinc deposits, favorable prospective areas are delineated and potential ore deposit types are proposed, providing the foundation for lead and zinc prospecting and exploration. The results show that the content of lead in stream sediments in the bedrock outcrop area of Pakistan ranged between 0.37-155.90 μg/g, with an average value of 13.44 μg/g, which is higher than the Clark value of the crust. The content of zinc varied from 1.78 to 288.70 μg/g, with an average value of 52.10 μg/g, which is lower than the Clark value of the crust. According to 92% cumulative frequency as the lower limit of anomaly (Pb = 18.4 μg/g, Zn = 76.0 μg/g), a total of 18 lead geochemical anomalies, 24 zinc geochemical anomalies, nine lead-zinc prospective areas were delineated, and three main metallogenic series were identified. It is suggested that the Khuzdar-Rasbela and Quetta areas of south-central Pakistan have great prospecting potential for SEDEX and MVT lead-zinc deposits. This region—connecting with the Sanandagi-Sirjan lead-zinc metallogenic belt of Iran to the west, extending to the Tianshuihai-Sanjiang lead-zinc metallogenic belt of China to the east—is an important component of the giant metallogenic belt of the Tethys hosting sedimentary lead-zinc deposits, and this type of lead-zinc deposits may also be found in other metallogenic belts and areas of the Tethys belt.

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Geochemical distribution of Li/Be in Pakistan: Implications for Li/Be prospecting
HONG Jun, Tahseenullah KHAN, LI Wenyuan, Yasir Shaheen KHALIL, MA Zhongping, ZHANG Jing, WANG Zhihua, ZHANG Huishan, ZHANG Haidi, LIU Chang, Asad Ali NAREJO
2025, 32(1): 127-141. 
DOI: 10.13745/j.esf.sf.2024.10.32

Abstract ( 59 )   HTML ( 8 )   PDF (10018KB) ( 118 )  

Lithium (Li) and beryllium (Be) are strategic metal resources with significant applications in emerging industries such as new materials and information technology. Pakistan is located at the convergence of the Eurasian, Indian and Arabian tectonic plates with favorable Li/Be mineralization conditions. However, due to limited geological investigations the full scope of Li/Be resource potential in Pakistan remains unknown. Low-density geochemical survey (1∶1 million scale) is an effective method for the study of Li/Be mineral distribution and rapid delineation of Li/Be prospective areas. In this paper, the geochemical background of Li/Be in Pakistan is analyzed based on a 1∶1 million low-density geochemical survey. Combined with analysis of the geological background of Li/Be mineralization, the paper aims to determine the prospective areas of Li/Be ore deposits to provide a basis for the prospecting and exploration of rare metal resources in Pakistan. In stream sediments of outcrop areas throughout Pakistan, Li concentrations ranged from 1.56 to 118.2 μg/g, with an average of 20.06 μg/g, while Be concentrations ranged from 0.07 to 7.16 μg/g, averaging 1.22 μg/g. Using 92% cumulative frequency data, 18 lithium and 12 beryllium geochemical anomaly areas were delineated, and prospective areas were selected accordingly. The Karakorum terrane and the Himalayan Fold Belt were identified as prospective areas for pegmatite-type lithium ore deposits, while the eastern part of the Chagai magmatic arc was identified for saline brine-type lithium ore deposits. The Karakorum terrane was found to be the most favorable area for further exploration of lithium and beryllium mineral resources.

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Discovery of iron-copper polymetallic mineralization in the Pamir, Tajikistan and its implications for the exploration of VMS-type copper-lead-zinc deposits in the Paleo-Tethys domain
ZHANG Huishan, ZHANG Jing, HONG Jun, XI Dehua, MA Zhongping, MENG Guanglu, LUO Yanjun, ZHANG Haidi, LIU Mingyi, LÜ Pengrui, YANG Bo, CAO Jifei
2025, 32(1): 142-161. 
DOI: 10.13745/j.esf.sf.2024.12.36

Abstract ( 58 )   HTML ( 6 )   PDF (28634KB) ( 101 )  

VMS deposits from thePaleo-Tethys stage are only exposed in the Sanjiang region of China. Whether this type of deposit exists in other parts of the Tethys or its metallogenic potential remains critical scientific and practical issues of interest. The Pamir region of Tajikistan, located between the Qinghai-Tibet Plateau and the Iranian Plateau, is an important component of the Tethys domain. The region remains underexplored due to limited geological work, a lack of systematic geological surveys and investments, and the absence of significant breakthroughs in mineral exploration to date. Geochemical surveys serve as an effective method for analyzing the distribution characteristics of metallic elements such as copper, lead, and zinc, while also enabling the rapid identification and prioritization of promising exploration areas and targets.

Based on the geochemical survey data at scales of 1∶1000000 and 1∶250000 jointly conducted by the China Geological Survey and the Tajikistan Geological Survey, this study focused on 1∶50000 geochemical surveys in anomalous areas and conducting anomaly verification, followed by anomaly verification and genetic analysis of the discovered mineralized bodies, while also exploring the regional mineralization potential. The research findings are as follows: (1) The primary anomalous element associations in the Tokhtamesh area of the Pamirs include Fe, Cu, Pb, Zn, Ag, Sb, Au, and As. The anomalies are large in scale, high in intensity, and show distinct zonation in concentration, with anomalies clearly controlled by strata and fault structures. Two prospective exploration target zones, labeled Z01 and Z02, were identified. These zones show potential for discovering massive sulfide copper-lead-zinc deposits and hydrothermal vein-type gold deposits. (2) Anomaly verification revealed six iron-copper polymetallic mineralization bodies, with three phases of mineralization identified. The first phase is the main mineralization period, forming VMS-type copper-lead-zinc mineralization bodies within Permian strata (Z01 target zone: Mineralization bodies I and II). The second phase is a hydrothermal reformation period involving deformation and metamorphism, forming bed-parallel and cross-layer vein-like iron-copper mineralization bodies (Mineralization bodies III, IV, V, and VI) and modifying the preexisting VMS-type copper-lead-zinc bodies. The third stage corresponds to the supergene oxidation period, during which weathering and erosion oxidized the previously formed mineralized bodies, resulting in zoning phenomena. It is inferred that the Z02 prospecting target area still holds potential for discovering VMS-type copper-lead-zinc deposits. (3) The Pamir-Tianshuihai area of Tajikistan-China demonstrate good metallogenic potential for VMS copper-lead-zinc deposits, with nine prospective exploration areas predicted. It is proposed that the Permian strata of the Paleo-Tethys stage within the Tethys region offer promising prospects for the exploration of VMS massive sulfide deposits, representing an important direction for future exploration efforts.

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Geochemical distribution of Pb and Zn in the Eastern High Atlas, Morocco: Implications for Pb-Zn ore prospecting
WU Fafu, ZHAO Kai, SONG Song, LUO Junqiang, ZHANG Huishan, YU Wenming, LIU Jiangtao, CHENG Xiang, LIU Hao, ZENG Xiongwei, HE Yaoyan, XIANG Peng, WANG Jianxiong, HU Peng
2025, 32(1): 162-182. 
DOI: 10.13745/j.esf.sf.2024.10.41

Abstract ( 44 )   HTML ( 4 )   PDF (9754KB) ( 83 )  

The Moroccan High Atlas tectonic belt is located at the west end of the Tethyan metallogenic domain with favorable geological conditions for mineralization. Numerous Mississippi Valley-type lead-zinc deposits (MVT) have been discovered in this region. However, the mineralization potential of lead and zinc is unclear due to lack of long-term, high-level geological investigation. Medium- to large-scale geochemical surveys are effective tools for resource exploration, as detailed geochemical anomaly information can help to quickly delineate prospective mineralization areas, thereby improving the exploration efficiency and success rate. In this study, a 1∶100000 geochemical survey was conducted over an area of more than 10000 km2 in the eastern section of the Moroccan High Atlas tectonic belt. The results revealed that the lead content in stream sediments ranged from 5.7 to 43,210.0 μg/g, averaging 45.0 μg/g, and the zinc content ranged from 12.2 to 75,420.0 μg/g, averaging 86.4 μg/g. Both values are higher than the Clarke values of the Earth’s crust. Using the 92% cumulative frequency as the anomaly threshold (Pb=36.9 μg/g, Zn=78.3 μg/g), a total of 73 lead and 68 zinc geochemical anomalies were delineated. By analyzing the regional geochemical distribution characteristics of lead and zinc, combined with the regional geological background and mineralization conditions, three major lead-zinc metallogenic belts were identified, and nine lead-zinc ore prospective areas were delineated. This study suggests that the region has significant potential for discovering MVT deposits, providing important directions for future mineral exploration efforts.

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Geochemical characteristics and metallogenic potential of nickel in Papua New Guinea
ZHAO Yuhao, YANG Zhiming, ZHU Yiping, Kumul CONRAD, DU Denghu, Mosusu NATHAN, WANG Tiangang, JIANG Hantao, YAO Zhongyou
2025, 32(1): 183-193. 
DOI: 10.13745/j.esf.sf.2024.10.30

Abstract ( 50 )   HTML ( 6 )   PDF (5724KB) ( 75 )  

Located at the convergent boundary of the Pacific and Indo-Australian Plates, Papua New Guinea (PNG) consists of three tectonic units and features two nickel mineralization types. National-scale geochemical mapping was conducted in PNG between 2015-2018, where 1399 samples of stream sediments were collected from the Highlands Region, Papua Peninsula, and New Guinea Islands. This paper reports preliminary study of the geochemical background, spatial distribution characteristics, and metallogenic potential of nickle in PNG. The nickle concentration ranged between 2.7-2430.0 μg/g, with a median value of 42.0 μg/g, close to the Ni abundance in the Earth’s upper crust and higher than the geochemical baselines of nickle in Europe, Australia, North America, and China. With widely developed mafic-ultramafic magmatic rocks, the Central Arc Land Collision Zone-consisting the Papuan Fold Belt, New Guinea Thrust Belt, Finisterre Terrane, Aure Fold Belt, Eastern Fold Belt, and Eastern Papuan Composite Terrane—had higher nickle baseline level than the Melanesian Arc. The ophiolitic complexes, such as the April ophiolite, Marum ophiolite, and Papua ultramafic belt, showed good correlation with Ni-enrichment areas. Seven nickle geochemical provinces and eight nickel anomaly areas with laterite mineralization potential were delineated.

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Geochemical characteristics and metallogenic prediction of gold in Papua New Guinea
XU Ming, XI Wanwan, ZHAO Yuhao, Conrad KUMUL, WU Datian, Nathan MOSUSU, WANG Tiangang, ZHU Yiping, YAO Zhongyou
2025, 32(1): 194-204. 
DOI: 10.13745/j.esf.sf.2024.10.36

Abstract ( 44 )   HTML ( 2 )   PDF (4865KB) ( 74 )  

Papua New Guinea (PNG), which is located at the convergence edge between the Pacific plate and the Indo-Australian plate, consists of three tectonic units. There are two main types of gold mineralization in PNG: epithermal and porphyry. National-scale geochemical mapping was conducted in PNG between 2015-2018, using 1399 stream sediment samples collected from the Highland Region, Papua Peninsula, and New Guinea Islands. In this preliminary study we analyzed the geochemical background, spatial distribution characteristics and metallogenic potential of gold in PNG. The gold concentration ranged between 0.2-6188.0 ng/g, with a median value of 1.5 ng/g, which is higher than the gold upper crustal aboundance, and slightly lower than the gold geochemical baselines of China and Australia. The Central Arc-Land Collision Zone—consisting of the Papuan Fold Belt, the New Guinea Thrust Belt, Finisterre Terrane, the Aure Fold Belt, the Eastern Fold Belt, the Eastern Papuan Composite Terrane, and the Finisterre Terrane, with widespread development of medium-acidic intrusive rocks, alkaline intrusive rocks, and alkaline volcanic rocks—has a higher median value of gold than the Melanesian Arc. The calc-alkaline intrusive complex of the New Guinea thrust belt, and the calc-alkaline intrusive complex and the potassium-rich volcano-intrusive complex of the Melanesian magmatic arc strongly correlate with higher gold concentration. Altogether seven gold geochemical provinces and nine gold anomalies with epithermal or porphyry mineralization potential are delineated.

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Geochemical spatial distribution of copper and mineral prospectivity prediction in Peru
HU Qinghai, WANG Xueqiu, ZHANG Bimin, CHI Qinghua, WANG Qiang, SUN Binbin, ZHOU Jian, WANG Wei, Igor ESPINOZA VERDE, Alex AGURTO CORNEJO, Joel OTERO AGUILAR, PAN Wei, LIU Hanliang, TIAN Mi, WU Hui
2025, 32(1): 205-218. 
DOI: 10.13745/j.esf.yx.2024.10.37

Abstract ( 44 )   HTML ( 6 )   PDF (8723KB) ( 87 )  

Peru, as an important part of the Andean metallogenic belt, is located on the west coast of South America. It is rich in mineral resources, and its copper reserves and copper production ranks second in the world. This paper carried out a global scale geochemical mapping project in Peru for the first time, and obtained a total of 416 catchment sediment samples. Copper contents in catchment sediments in Peru ranged from 2.38 to 495 μg/g, with a background (median) value of 24.0 μg/g. The average copper content in the surface (deep) catchment sediments of the whole Peruvian region and of the coastal zone, the Andes mountains and the Amazon plain were 31.4 (31.6), 45.6 (32.2), 47.5 (48.2) and 21.3 (24.9) μg/g (μg/g), respectively. The geochemical map showed that the spatial distribution of copper in Peru as a whole had a trend of high in the west and low in the east, with higher copper content in the western coastal zone and the central Andes mountains and lower copper content in the eastern Amazon plain. Using a cumulative frequency of 75% as the lower limit of anomaly, five copper geochemical anomalies were delineated, two of which reached the scale of geochemical giant province, and another two of geochemical province. The paper also discusses the source and influencing factors of copper geochemical anomaly and the impact on mineral resources. The favorable tectonic evolution environment of Peru provide favorable conditions for the formation of large and super-large copper deposits. The continuous subduction and transformation of the Nazca plate of the Pacific Ocean to the South American continent led to partial melting of the oceanic crust, resulting in strong and extensive medium-acidic magmatic activity. In addition, the copper content in the magma is enriched on a large scale, and the local area is enriched and metallogenic under specific environment. This tectonic movement led to several geochemical blocks in the spatial distribution of Cu elements in Peru, which may also be one of the reasons for the formation of Cu geochemical anomalies. In future studies these geochemical blocks can be used to search for copper ore concentration areas or large and super-large copper deposits, delineate prospective areas, reduce prospecting risks, improve the prospecting efficiency and shorten the prospecting period. Geochemical prospecting conducted in the research area can provide basic information and data for the exploration, development and utilization of copper deposits in Peru.

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Geochemical characteristics and quality evaluation of soils in the Mantaro Basin, central Peru
LIU Jun’an, ZHU Yiping, JIANG Hantao, César De La Cruz POMA, Oliberth Pascual GODOY, Luis Enrique Vargas RODRÍGUEZ, GUO Weimin, YAO Chunyan, WANG Tiangang, ZHANG Ming, YAO Zhongyou
2025, 32(1): 219-235. 
DOI: 10.13745/j.esf.sf.2024.10.38

Abstract ( 47 )   HTML ( 8 )   PDF (13964KB) ( 82 )  

In order to enhance the geoscientific collaboration between China and Peru using China’s advanced geochemical investigation and research methods, the China Geological Survey (CGS) and Peru Instituto Geológico, Minero y Metalúrgico (INGEMMET) jointly conducted a multipurpose geochemical survey in the Mantaro Basin of central Peru. The samples were collected and analyzed in Chinese laboratory according to applicable Chinese national standards. According to the results, the soil of the study area was in general weakly alkaline, with strong enrichment of Au and relatively enriched indicators such as I, C, Corg, Cd, and N. The soil nutrient indicators N and P were relatively abundant, but K was lacking. The comprehensive nutrient grade was mainly “relatively rich” (Grade 2), accounting for 74.1% of the total area, indicating good soil fertility. In terms of soil environmental assessment, Zn and Pb showed slight to severe pollution in a small number of areas, while Cd and As contamination was widespread. The comprehensive grade of soil environment was predominantly “slightly to lightly polluted”, with the polluted areas mainly concentrated within 5 km from either side of the Mantaro River, while the heavily polluted areas were mainly distributed close to the Mantaro River and Huancayo City with large population density. The heavy metal pollution was serious, and the spatial distribution of pollution was closely related to the Mantaro River. The comprehensive geochemical grade of soil quality was mainly “moderate” to “severe”, constituting 83.18% of the area, with only 16.82% of the area graded “good to high quality”. In summary, the Mantaro Basin was found to have relatively rich soil nutrients, severe heavy metal pollution, and a moderate to poor overall soil quality. Recommendations to relevant agencies include strengthening environmental management and control of heavy metal pollution sources in the Mantaro River and its upstream areas.

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Geochemical background and anomaly characteristics of copper in soils of Mexico on a global scale
YAO Chunyan, JIANG Hantao, ZHU Yiping, ZHENG Lu, LI Hanwu, WANG Tiangang, LIU Jun’an, Uribe Luna JESUS
2025, 32(1): 236-243. 
DOI: 10.13745/j.esf.sf.2024.10.42

Abstract ( 43 )   HTML ( 3 )   PDF (4489KB) ( 72 )  

Mexico is a major economic power in Latin America and an important mineral producer in the world. Based on data obtained from Mexico global-scale geochemical mapping using 287 deep soil (C layer) samples, this paper produced a C-layer copper geochemical map with a scale of 1∶8000000. The geochemical background and spatial distribution characteristics of copper in soil were studied from a global-scale perspective, and the major copper geochemical anomalies of Mexico were delineated. The main findings are: (1) the copper content in soils of Mexico ranged from 3.6 to 129.0 μg/g, with the mean and median values being 20.3 and 15.9 μg/g, respectively, and the background value being 15.6 μg/g. The Chiapas Plateau and the Southern Madre Island Arc had significantly higher median copper content than other tectonic units, and had the highest background copper value in the whole country. (2) The geochemical map showed uneven distribution of copper content in soil, with the general trend of high in the south, low in the north, and high in the west, low in the east. (3) The geochemical map identified ten copper geochemical anomalies, eight of which reached mega-province scale and two reached province scale. Based on the fit between copper geochemical information and existing mineral deposits, it is considered that the Sierra Madre del Sur and Chiapas Mountains in southern Mexico are important prospective areas for copper in Mexico.

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Geochemical distribution of gold in the China-Mongolia boundary region and its implications for gold prospecting
LIU Hanliang, WANG Xueqiu, NIE Lanshi, CHI Qinghua, WANG Wei, SHOJIN Davaa, ENKHTAIVAN Altanbagana, ZHOU Jian, DU Yude
2025, 32(1): 244-256. 
DOI: 10.13745/j.esf.sf.2024.10.39

Abstract ( 55 )   HTML ( 8 )   PDF (6053KB) ( 104 )  

The Sino-Mongolian border area has excellent geological conditions for ore formation and is one of the world’s most important metal mineralization provinces. The area is situated on one of the three largest porphyry copper-gold-molybdenum metallogenic belts in the world with enormous resource potential—it is a hotspot for international and domestic geoscience research and exploration. Based on the 1∶1 million geochemical mapping data of the Sino-Mongolia border areas, the geochemical parameters and regional geochemical distribution of gold in the catchment sediments are discussed in this paper. The median and average gold anomaly values of the catchment sediments were 0.79×10-9 and 1.34×10-9, respectively. The North China Block and the Altay Tectonic Belt had the highest gold contents, with the regional concentration coefficients of 1.43 and 1.36, respectively, consistent with regions faverable for gold enrichment. The outer, middle and inner zones of gold geochemical anomalies were identified according to cumulative frequencies of 85% (1.55×10-9), 92.5% (2.22×10-9) and 97.5% (4.03×10-9), respectively. A total of 28 geochemical prospective areas were delineated, providing important exploration targets for gold and other precious metal deposits in this area. The paper fills the gap in the study of gold geochemical distribution, and provides important data for comparing precious metal deposits in the Sino-Mongolia border area.

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Framework and implementation of field informatization technology for geochemical exploration
ZHOU Yining, GAO Yanfang, CHANG Chan, LIU Qingqing, WANG Xueqiu
2025, 32(1): 257-265. 
DOI: 10.13745/j.esf.sf.2024.12.35

Abstract ( 42 )   HTML ( 5 )   PDF (5757KB) ( 80 )  

Geochemical field sampling is a critical component of geochemical exploration. There has long been a significant lack of specialized software support for information technology in geochemical field sampling. With the rapid development of information technology, traditional field geochemical survey models are accelerating their transformation towards intelligence, convenience, and modernization. Therefore, it has become an inevitable trend to informatize the entire process of geochemical field sample collection. This article systematically summarizes the key development directions and core technical characteristics of geochemical field investigations and geological survey informatization based on the latest progress in geological survey informatization both domestically and internationally. It also delves into the functional requirements and characteristics of future geochemical field survey systems. The research aims to promote the digitalization and informatization of geochemical field sample collection, laying the foundation for constructing an information product system that covers the entire geochemical exploration process while also enhancing the overall service capacity of geological survey informatization. This will ultimately help establish a product system for the informatization of the entire geochemical exploration process and improve the quality of geological survey informatization services.

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Application of 2D-EMD/PCA in gold and key metals prospecting in Jiaodong
CHEN Yongqing, ZHENG Aoyue, FEI Jinna, ZHAO Jie, ZHAO Pengda
2025, 32(1): 266-282. 
DOI: 10.13745/j.esf.sf.2024.10.26

Abstract ( 46 )   HTML ( 3 )   PDF (19206KB) ( 73 )  

With the continuous rise in global demand for mineral resources in recent years from manufacturing industry and global economy, it is an urgent need to develop new methods for proven and hidden mineral resources. However, multistage mineralization results in complex, overlapping distribution of ore-forming elements in geological units, and most minerals are often associated with multiple elements. To address this problem we used a combination of two-dimensional empirical mode decomposition (2D-EMD) and principal component analysis (PCA) to extract local and regional multielement anomaly components from the drainage sediment geochemical data in the Jiaodong gold polymetallic ore field. The prospective areas were identified from complex, overlapping anomalies, and the multielement mineral resource potential of the study area was evaluated by geochemical block method. The results provide a scientific basis for the exploration and evaluation of symbiotic minerals. Specifically, (1) Au-Ag-Cd and Be-La-Mo-Nb-Th-U-Y multielement combinations were established by PCA; (2) the local and regional anomaly components of the multielement combinations were identified by 2D-EMD based on their principal component scores; (3) the prospective area of the two multielement combinations could be delineated using local anomaly components, and the high background belt could be identified by regional anomaly components. Combined with the local anomaly components and the spatial distribution of granite, we infer that Au-Ag-Cd mineralization is related to the Linglong granite and Guojialing granodiorite intrusions, and Be-La-Mo-Nb-Th-U-Y mineralization is related to the Guojialing granodiorite and Weideshan monzonite intrusions. The Guojialing granodiorite rock mass may have dual metallogenetic characteristics of both precious and critical metals.

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Quantitative delineation and evaluation of Sn-W and Pb-Zn polymetallic prospecting target areas in the Tengchong Block by SVD and PCA
ZHENG Aoyue, FEI Jinna, CHEN Yongqing, NING Yanyun, CAO Yilin, ZHAO Pengda
2025, 32(1): 283-301. 
DOI: 10.13745/j.esf.sf.2024.10.29

Abstract ( 46 )   HTML ( 8 )   PDF (22756KB) ( 76 )  

Concentration of ore-forming elements or element groups in a geological unit is a result of multistage geological processes. Ore-forming element groups can be identified by principal component analysis (PCA) performed on geochemical mapping data using stream sediments. The principal component scores of the ore-forming element groups can then be used to further identify the regional and local anomalies by singular value decomposition (SVD). Regional anomalies indicate high background regions favorable for mineralization formed under various geological processes (e.g., magmatism, sedimentism, metamorphism) during crustal evolution, while local anomalies are associated with ore-forming events and can be used to identify ore prospecting targets by superimposition with regional anomalies. In this study, the ore-forming element groups were created using 1∶200000 national-scale geochemical mapping data. In total, 15 ore prospecting targets were identified in the Tengchong Block, including eight Sn-W and seven Pb-Zn-Ag prospecting targets. The estimated potential resources of Sn-W are approximately 915 Mt and Pb-Zn-Ag are about 792 Mt.

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Geochemical exploration of blind sulfide-rich ore deposits: Sulphur gas geochemical detection
WANG Qiang, CHENG Zhizhong, YAN Tingjie, LIN Chenggui, DU Zezhong, YUAN Huixiang, LI Xiaolei
2025, 32(1): 302-321. 
DOI: 10.13745/j.esf.sf.2024.10.31

Abstract ( 60 )   HTML ( 9 )   PDF (6358KB) ( 96 )  

Sulfur gas geochemical detection has long been applied in mineral exploration. However, this method has not been widely used due to the high activity and reactivity of sulfur gases, low reproducibility of test results, and high cost. Today, as mineral exploration shifts from near-surface, easy-to-discover ore deposits to deep concealed ones, and with the successful development of portable, economical, efficient, real-time gas detection systems, a new opportunity arises to improve and promote this method. This paper reviews research progress, challenges, and future development directions regarding to concealed sulfide-rich deposits. Equilibrium thermodynamic models, simulation experiments on weathering and oxidation of sulfide minerals, and field studies suggest that gas geochemical anomalies of concealed sulfide-rich ore deposits are influenced by their mineral compositions, cover characteristics, geochemical landscapes, and physicochemical characteristics of sulfur gases. In regolith-covered terrains, portable multi-component gas analyzers can be used to obtain on-site, real-time measurements of soil gases including sulfur gases; more importantly, sulfur gas anomalies in soils tend to appear directly above the blind deposits if the blind deposits are covered by regolith directly. In bedrock outcrops, sulfur gases can be measured by rock thermal desorption; and the spatial relationship between the blind deposits and sulfur gas anomalies is primarily influenced by the development of permeable channels such as faults and fractures. Case studies indicate the sulfur gas geochemical detection is effective for mineral exploration in semi-arid and arid terrains and has great potential for mineral exploration in semi-humid and humid terrains. Future research directions should focus on three aspects: the formation and evolutionary process of sulfur gases in surface environment to ascertain the dominant controlling factors; the effectiveness of geochemical detection of sulphur-containing gases under different geochemical landscapes, especially in semi-humid and humid terrains; and the miniaturization and intelligent upgrading of portable soil gas detection equipment.

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Special Section on The India-Eurasia Collision and Its Long-Range Effect (Part 11)
A brief analysis on the dynamic sources of the uplift and exhumation of the Tianshan Mountains during the Meso-Cenozoic based on the spatio-temporal differences of rock cooling in the Central Asia
WANG Guocan, ZHAO Zihao, SHEN Tianyi, MA Cheng, ZHOU Yabo
2025, 32(1): 322-342. 
DOI: 10.13745/j.esf.sf.2024.7.51

Abstract ( 63 )   HTML ( 3 )   PDF (12436KB) ( 64 )  

This paper characterized the spatio-temporal differences in rock rapid cooling events during the Meso-Cenozoic through frequency analysis and phased interpolation based on systematically collected apatite fission track ages, U-Th/He ages, and fission track length data from the Tianshan Mountains and northern Central Asia. And it also discussed the relationship between rock rapid cooling events and the dynamics of plate boundaries by considering tectonic deformation in different regions across various stages. The results indicate that the Tianshan Mountains experienced four primary rapid cooling events, which occurred in the Late Triassic, Late Jurassic-Early Cretaceous, Late Cretaceous-Paleogene, and Middle-Late Cenozoic periods. The rapid cooling event in the Late Triassic, mainly observed in the western segment of the Tianshan, is linked to rock uplift and exhumation resulting from reverse thrusting, potentially controlled by the collision between the western Turan block and the paleo-Asian continent. During the Late Jurassic-Early Cretaceous, rapid cooling was primarily found in the western Kyrgyz Tianshan and the easternmost Tianshan, where both events were associated with thrusting-controlled rock uplift and exhumation. The uplift in the western Kyrgyz Tianshan is probably connected to the far-field effects of the collision between the southern Lhasa block and the paleo-Asian continent, while uplift in the easternmost Tianshan was likely influenced by the far-field effects of the closure of the northern Mongol-Okhotsk Ocean. The rapid cooling event during the Late Cretaceous-Paleogene is primarily characterized by thermal cooling along major faults. In the western Kyrgyz Tianshan, western Chinese Tianshan, and the Jueluotage region in the southern part of the eastern Tianshan, this rapid cooling due to faulting mainly occurred in the latest Cretaceous-Paleogene and can be attributed to the accretion of island arcs such as Kohistan-Dras, as well as the final collision between the Indian and Eurasian plates. But in the Harlik Mountains, located in the northern part of the Eastern Tianshan, this rapid cooling mainly happened in the middle Late Cretaceous, slightly earlier than in other regions but was synchronised with the post-collision extensional collapse of the northern Mongolia-Okhotsk orogenic belt. The faulting associated with this rapid cooling in the Harlik Mountains demonstrates a dextral transtensional movement within a northeast-southwest tensile stress field, suggesting a dynamic link between the dextral transtension in the Harlik Mountains and the post-collision collapse in the northern Mongolia-Okhotsk orogenic belt. The strong uplift and exhumation event in the mid to late Cenozoic is mainly observed in the Pamir and the western segment of the Tianshan, reflecting the far-field effects of intense intracontinental compression caused by the rise of the Tibetan Plateau and its northward expansion following the collision between the Indian and Eurasian plates. In summary, the rapid cooling events in various parts of the Tianshan Mountains during different stages of the Meso-Cenozoic era were the result of the combined effects of various plate boundary dynamics, including multi-block collisions and the subsequent rise of the Tibetan Plateau in the southern Tethys tectonic domain, as well as the closure of the Mongol-Okhotsk Ocean and the resulting post-collision extensional collapse in the northern tectonic domain.

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Crustal thickness evolution of the Central Lhasa Terrane inferred from trace elements in zircon of Tangra Yumco
LIU Xiaohui, LIU Yimin, DING Lin, GUO Xiaoyu, HUANG Xingfu, LI Huilin, GAO Rui
2025, 32(1): 343-366. 
DOI: 10.13745/j.esf.sf.2024.4.60

Abstract ( 57 )   HTML ( 4 )   PDF (8119KB) ( 64 )  

The Lhasa terrane is located in the southern part of the Tibetan Plateau and is one of the regions with the greatest crustal thickness globally. However, the timing and process of crustal thickening in the Lhasa terrane remain debated. Zircon trace element characteristics are controlled by the co-existing relationships between zircon and other trace element carrier minerals, meaning different minerals have varying partition coefficients, thus zircon trace elements can be used to quantitatively reconstruct crustal thickness. This study conducted U-Pb geochronological and trace element geochemical research on zircons from igneous and sedimentary rocks in the Dangra Yongcuo area of the central Lhasa terrane. Using zircon europium anomalies to quantitatively reconstruct crustal thickness, the results reveal that the central Lhasa terrane experienced two crustal thinning events (150-130 Ma and 85-65 Ma) and two crustal thickening events (130-85 Ma and 65-15 Ma) during the Jurassic to Neogene periods. During 150-130 Ma, crustal thinning in the central Lhasa terrane was primarily related to slab retreat of the Bangong-Nujiang Ocean. Between 130-85 Ma, the central Lhasa terrane underwent crustal thickening due to northward subduction of the Neo-Tethys Ocean and southward subduction of the Bangong-Nujiang Ocean. During 85-65 Ma, slab retreat of the Neo-Tethys Ocean and back-arc extension led to another crustal thinning event. From 65-15 Ma, collision and subsequent compression between the Indian and Eurasian plates caused the central Lhasa terrane to thicken again.

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Enrichment background and formation mechanism of middle- and deep-geothermal resources in the Fenwei Graben
LIU Demin, ZHANG Changsheng, LU Wanling, WEI Meihua, QI Yanya, LIU Fei, ZHAO Yue, JIANG Huai
2025, 32(1): 367-379. 
DOI: 10.13745/j.esf.sf.2024.1.10

Abstract ( 75 )   HTML ( 10 )   PDF (7286KB) ( 102 )  

Geothermal resources in the middle and deep layers of the Fenwei Graben exhibit considerable development, yet their genetic mechanism remains elusive. A thorough understanding of the geological background and the cause of thermal convergence is essential for improving exploration and exploitation efficiency. Building on previous research, this paper provides a comprehensive analysis of the deep thermal structural characteristics, structural evolution, genetic mechanisms, and the source, migration pathways, reservoirs, and sealing conditions of the Fenwei Graben. Additionally, it explores the mechanisms of driving thermal convergence in the region. The formation of middle and deep geothermal resources in the Fenwei Graben is rooted in a complex geological framework, with Cenozoic tectonic processes playing a pivotal role in the development of medium- and high-temperature reservoirs. The Cenozoic extension of the Fenwei Graben is primarily driven by the distant effects of the Indian-Eurasian plate collision. Key factors contributing to the formation of geothermal resources in the region include asthenospheric diapir upwelling, the development of low-velocity, high-conductivity zones in the middle and shallow layers, crustal stretching and thinning, and solid-shear ductile deformation. Mantle heat conduction serves as the primary dynamic heat source for the target geothermal reservoir, with shallowly embedded low-velocity, high-conductivity layers within the upper mantle and crust acting as efficient heat conductors and energy accumulation centers. These layers function as direct heat sources and focal points for medium- and deep-thermal reservoirs. The significant extension and tension during the Cenozoic era, combined with distinct structural patterns, provide favorable thermal control structures. Marginal faults and basin-controlling faults, characterized by deep incisions and active Cenozoic tectonics, exhibit excellent heat conduction properties, playing a crucial role in the formation and distribution of geothermal resources. These faults act as efficient pathways for heat conduction and release. The thick Cenozoic loose sediments with extensively developed pores, along with volcanic rocks characterized by low thermal conductivity and excellent heat retention, serve as high-quality thermal capping layers. The metamorphic basement, marked by ductile shear deformation, functions both as the target layer for dry hot rock geothermal resources (solid heat energy) and as an effective heat source layer for shallow hydrothermal geothermal systems. As a result, the Fenwei Graben boasts an exceptional thermal accumulation system, integrating heat sources, pathways, reservoirs, and capping layers, which collectively support the enrichment of high-quality geothermal resources.

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Discovery and significance of natrophilite in the pegmatite from Chakabeishan, Qinghai Province
LÜ Shujun, DONG Guochen, ZHAO Zhidan, LUO Zhibo, QU Kai, LI Xiaowei, YUAN Wanming, WANG Yanjuan, MENG Jia
2025, 32(1): 380-387. 
DOI: 10.13745/j.esf.sf.2024.2.19

Abstract ( 55 )   HTML ( 11 )   PDF (6602KB) ( 44 )  

Natrophilite is a rare phosphate mineral that has not been reported in China, especially its primary mineral, which has not been discovered both domestically and internationally. The literature with a few data suggests that natrophilite is formed by sodium replacement of lithiophilite as a secondary mineral. Lithiophilite is a common mineral in pegmatite, which is generally believed to be a product of the magmatic stage in phosphate rich pegmatites as a primary mineral. In this article, natrophilite and lithiophilite developed on natrophilite were found in the Chakabeishan rare-metal pegmatite. Natrophilite is characterized by euhedral mineral particles without any metasomatism, and has primary mineral features of apatite alteration. And the lithiophilite is irregular and develops on the natrophilite, showing typical metasomatic characteristics. Moreover, electron probe data showed that the Mn/Fe values of natrophilite were 1.692-1.875, and the Mn/Fe values of lithiophilite were 2.519-2.548. This also indicates that the formation of natrophilite occurred earlier than that of lithiophilite. Natrophilite should be the primary mineral, and the lithiophilite should be the secondary mineral. The higher manganese content of the parent magma in the pegmatite area may be a possible reason for the occurrence of natrophilite. The alteration of lithiophilite and fluoroapatite developed on the natrophilite reflect the later oxidation and metasomatism of Li, Mn, Ca, and F rich fluids. Meanwhile, combined with the alteration of spodumene in this area, it is indicated that there is a geochemical cycle of lithium in the Chakabeishan deposit.

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Effects of accessory mineral inclusions and signal acquisition time on zircon U-Pb dating and trace element analysis results
HUANG Yu, ZHONG Shihua, LI Sanzhong, ZHAO Hong, XUE Zimeng, GUO Guanghui, LIU Jiaqing, NIU Jinghui
2025, 32(1): 388-400. 
DOI: 10.13745/j.esf.sf.2024.2.23

Abstract ( 56 )   HTML ( 5 )   PDF (4255KB) ( 49 )  

In-situ zircon micro-area U-Pb dating and trace element analysis have become routine techniques in Earth sciences. However, the interpretation of zircon micro-area analysis results is influenced by various factors, including the selection of analysis points, instrument stability, and signal correction. Quantitatively understanding how these factors affect zircon micro-area analysis results is a critical prerequisite for accurately interpreting the geological significance of such data. This study focuses on zircons from the Late Triassic monzogranite porphyry intrusion in the Yemaquan iron-polymetallic deposit in Qinghai Province. LA-ICP-MS zircon in-situ U-Pb dating and trace element analysis were performed to evaluate the effects of accessory mineral inclusions and signal acquisition time on zircon micro-area analysis results. The findings indicate that although shorter signal acquisition times lead to larger errors in U-Pb dating, they do not significantly affect U-Pb ages or trace element analysis results. A comparison of analysis points with and without mineral inclusions shows that the presence of mineral inclusions also does not significantly interfere with dating results. However, if the selected zircon analysis location contains accessory mineral inclusions (e.g., apatite), the resulting data may display a false “light rare earth element enrichment” signature. This can lead to misinterpretations, such as incorrectly inferring magmatic oxygen fugacity characteristics. Therefore, it is crucial to first identify whether accessory mineral inclusions are present at the analysis location before conducting zircon micro-area analysis. Additionally, zircon data contaminated by mineral inclusions must be excluded prior to interpreting the geological significance of zircon trace element data.

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The implications of basement rock diagenesis on reservoir development: A case study of Archean basement rock in Jiyang Depression
MENG Tao, MU Xing, SHI Quanqing, LI Jiyan, LIU Peng, FANG Zhengwei, ZHAO Xian, NIU Huapeng
2025, 32(1): 401-417. 
DOI: 10.13745/j.esf.sf.2024.7.60

Abstract ( 45 )   HTML ( 4 )   PDF (20676KB) ( 36 )  

The Archean basement of the Jiyang Depression has emerged as a key target for oil and gas exploration; however, an unclear understanding of the reservoir formation mechanisms has severely limited exploration and discovery efforts. This paper systematically studies the diagenesis of Archean basement rock in the Jiyang Depression and its influence on reservoir development through field geological investigation, core observation, thin section identification, cathodoluminescence, X-ray diffraction (XRD), scanning electron microscopy, and fluid inclusion analysis. Diagenetic characteristics are identified based on core analysis, flake and elemental analysis results, and fluid inclusion homogenization temperatures. The impacts of these characteristics on reservoir development are characterized through flake face rates and physical property logging data. The results indicate that the lithology of the basement rock in the study area is primarily divided into two categories: magmatic and metamorphic rocks. Magmatic rock has undergone four successive diagenetic stages: condensation consolidation, post-magmatic hydrothermal alterations, weathering denudation leaching, and buried rock formation. During these stages, magmatic rock has experienced processes such as condensation consolidation, compaction, dissolution, filling and cementation, as well as alteration and metasomatism. Eventually, metamorphic rock is formed through metamorphic deformation. Condensation consolidation can create a small number of primary matrix pores, while corrosion processes generate corrosion pores and fractures, contributing to up to 80% of the porosity, which is crucial for enhancing reservoir quality. Conversely, compaction, alteration, and metasomatism tend to destroy these pores, as calcite, clay minerals, and other secondary minerals fill and cement fractures, with a filling degree ranging from 30% to 70%, adversely affecting reservoir space. A comprehensive analysis reveals that the physical properties of gneiss reservoirs are superior to those of granite. Favorable reservoirs are mainly located in the weathering crust and the inner fracture zone. The weathering crust, which is situated at the top of the buried hill of the basement rock, displays longitudinal zoning and is primarily influenced by weathering, leading to the development of I and II reservoirs. The inner fault zone, located in the middle section of the buried hill and aligned along fault lines, predominantly develops II and III reservoirs. The findings of this study provide valuable insights into the genetic research of basement rock reservoirs.

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Geological map of the lower crust in the Early Cretaceous of Shanxi Province: Based on vitrinite reflectance evidence
JIAO Shoutao, LIU Dongna, ZHANG Qi, JIN Zhibin, ZHANG Yusheng, YUAN Jie, ZHOU Ligang, LIU Tieyi, XIE Tuanjie, FAN Zongsheng, YAN Tongtong, ZHOU Xinpeng, ZHANG Shuangkui, WEI Qianqian, YAN Tao, ZHANG Kun, YIN Bihan
2025, 32(1): 418-431. 
DOI: 10.13745/j.esf.sf.2024.10.20

Abstract ( 48 )   HTML ( 6 )   PDF (9195KB) ( 46 )  

A geological map of the Early Cretaceous lower crust in Shanxi Province has been compiled based on granite data, which has added vitrinite reflectance data and recompiled the geological map of the Early Cretaceous lower crust in Shanxi Province. Many new insights have been obtained through comparison,which indicates that vitrinite reflectance is a very useful dataset for lower crustal mapping. Vitrinite reflectance can record the maximum temperature reached after its formation and is one of the widely used and reliable methods for maturity measurement in coalfield and petroleum geology departments. The vitrinite reflectance method is also very useful in petrology and mineral deposit studies. Therefore, it is possible to infer the presence, distribution, and scale of concealed rock mass in deeper layers, as well as the presence and distribution of mantle upwelling at the base of the lower crust based on vitrinite reflectance data. A new method for mineral exploration involves using vitrinite reflectance distribution to locate concealed rock masses and subsequently prospecting for mineral deposits based on these features.

This paper infers that concealed rock mass may exist in the deeper layers of several areas where Ro>3.0% based on the distribution of vitrinite reflectance in Shanxi Province. Among these, the concealed rock mass in Qixian has already been confirmed through drilling verification. There are many coal mines in Shanxi Province, and all anthracite distribution areas are favorable regions for locating concealed rock mass. The paper also revises the geological map of the Early Cretaceous lower crust in Shanxi Province based on vitrinite reflectance data, pointing out that the deeper layers in the central and southern parts of Shanxi Province are extensive regions of Mesozoic (mainly Early Cretaceous) granite distribution, which were also areas of mantle upwelling during the Early Cretaceous.It is inferred based on stratigraphic and granite data that the northern part of Shanxi Province (north of Datong) represents a region with normal crustal thickness, while the southern part represents a region of crustal thickening (part of the eastern China plateau). The southern part is a mantle upwelling region, while the northern part shows no signs of mantle upwelling. Therefore, the lower crust in the southern part is a high-temperature eclogite facies region, while the lower crust in the northern part is a low-temperature eclogite facies region. The lower crust is a fluid-bearing eclogite facies region in areas with surface mineral deposits. The lower crust in the central and western parts of Shanxi Province may represent a transitional zone between eclogite facies and granulite facies, suggesting that the eastern China plateau in Shanxi Province may exhibit a gradual westward subsidence trend.

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Mechanism of groundwater recharge at different depths during the “23·7” heavy rainfall event in North China: A case study of Xiong’an New Area
OUYANG Kaigao, JIANG Xiaowei, DU Yanan, ZHANG Zhiyuan, HAN Pengfei, WU Yenan, WANG Xusheng
2025, 32(1): 432-439. 
DOI: 10.13745/j.esf.sf.2024.6.34

Abstract ( 51 )   HTML ( 5 )   PDF (3237KB) ( 59 )  

The question of whether rainfall can penetrate a thick unsaturated zone to reach the water table has long been a contentious issue in the field of groundwater recharge. The extreme rainfall event that occurred in the North China Plain from July 23rd to 27th, 2023, equivalent to a large-scale infiltration experiment, provided a valuable opportunity to analyze how groundwater recharge is influenced by the depth to the water table. This study focuses on the Baiyangdian region in the Xiong’an New Area, examining the response patterns of groundwater at different depths during this extreme rainfall event, which delivered a cumulative rainfall of 289.2 mm over three days. Data were collected from four automated monitoring wells in the shallow water table area around Baiyangdian and six automated monitoring wells in the deep water table area within Rongcheng County. In the shallow water table area, vertical infiltration reached the water table approximately 16 hours after the onset of the storm, causing the water table to rise by 1.36 to 1.79 meters. In the deep water table area, river water levels rose rapidly after the storm, leading to leakage that formed a groundwater mound. Due to the backwater effect, groundwater levels within 6 km of the Nanjuhe River rose rapidly by 1.38 to 3.67 meters. This study demonstrates that vertical infiltration through the unsaturated zone is the primary source of groundwater recharge in shallow water table areas. In contrast, in deep water table areas near river channels, post-storm river infiltration and the resulting backwater effect are the main sources of groundwater recharge. These findings improve the understanding of groundwater recharge mechanisms at varying depths and provide valuable insights for analyzing water table recovery processes and the effects of ecological water replenishment in the North China Plain and other regions facing groundwater overexploitation.

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Characteristics of water density variation in capillaries of different diameters and its implications for soil water density changes
LI Chao, CHENG Donghui, MA Chenglong, QIAO Xiaoying, HUANG Mengnan, WANG Yishi, YANG Yinke
2025, 32(1): 440-448. 
DOI: 10.13745/j.esf.sf.2024.6.38

Abstract ( 42 )   HTML ( 4 )   PDF (1729KB) ( 30 )  

The density of soil water exhibits significant variation, yet no comprehensive theory currently exists to fully explain this pattern. In this study, quartz tubes with micrometer-scale diameters were used to simulate the pore systems of porous media, and the mass-volume method was employed to measure the density of water in eight quartz tubes with diameters ranging from 50 μm to 530 μm. The results indicate that when the diameter of the quartz tube is less than 75 μm, the density of water exceeds that of bulk water, reaching a maximum of 1.19 g/cm. Conversely, when the diameter ranges between 100 μm and 250 μm, the density of water is slightly lower than that of bulk water, with a minimum of 0.98 g/cm. The variation in water density with quartz tube diameter can be described using an empirical formula similar to the Lennard-Jones potential. The findings suggest that conventional mechanisms such as hydration effects, water-solid interfacial interactions, capillary effects, or cavitation cannot fully account for the observed changes in water density within the quartz tubes. Instead, the analysis indicates that the complex hydrodynamics and rheology within the capillaries: particularly shear thickening at the tube nozzle and its reverse process may be the primary physical mechanism driving the changes in water density across quartz tubes of different diameters. This mechanism represents a departure from traditional theories used to explain variations in soil water density and offers a novel perspective for understanding the phenomenon. It becomes possible to predict the density of water in soils with varying water contents by integrating the observed variation in water density within quartz tubes with soil water content models based on the concept of capillary bundles in porous media. Future research should focus on the fundamental principles of rheology to establish quantitative relationships between shear rate and viscosity, as well as between viscosity and density. Such efforts would enable the theoretical construction of models to describe the density variation of capillary water and soil water.

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Response to climate change of runoff at different time scales in the Baiyangdian Lake Basin based on the Budyko model
YU Tao, HAN Pengfei, WANG Xusheng, JIANG Xiaowei, ZHANG Zhiyuan, WAN Li
2025, 32(1): 449-458. 
DOI: 10.13745/j.esf.sf.2024.7.50

Abstract ( 45 )   HTML ( 4 )   PDF (2671KB) ( 28 )  

Climate change significantly impacts the formation of water resources and the transformation of hydrological elements within basins. Accurately quantifying river runoff responses to climate change is crucial for the sustainable development and efficient utilization of water resources. However, research on hydrological climate elasticity under non-stationary conditions remains relatively limited. This study focuses on eight sub-basins in the mountainous region of the Baiyangdian Lake Basin, employing a newly developed non-stationary runoff elasticity coefficient analysis method based on the Budyko model to examine the annual runoff response to climate change. The proposed method is validated in a Chinese basin, broadening its applicability, and is compared with results obtained using the Budyko model-based elasticity method under multi-year stationary conditions. The results reveal the following: on an annual scale, the annual evapotranspiration ratio and water storage change ratio exhibit a strong linear correlation with the annual aridity index; runoff is more sensitive to changes in precipitation at both annual and multi-year time scales; the annual runoff elasticity coefficient is smaller than the coefficient calculated under multi-year stationary conditions, highlighting the significant regulatory role of basin water storage in runoff responses to climate change. Furthermore, the annual elasticity coefficient is strongly correlated with basin area. This study validates the effectiveness of the newly proposed non-stationary runoff elasticity coefficient method based on the Budyko model and extends its applicability from humid regions to semi-humid and semi-arid areas. These findings provide valuable guidance for the sustainable management of water resources in the Baiyangdian Lake Basin and the Xiong’an New Area.

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Future China-Africa research collaboration in geoscience: Challenges and opportunities
Michael H. STEPHENSON, Hassina MOURI, Gbenga OKUNLOLA, CHENG Li, WANG Meng, ZHAO Yu, GU Liping, WANG Chengshan
2025, 32(1): 459-465. 
DOI: 10.13745/j.esf.sf.2024.12.37

Abstract ( 58 )   HTML ( 10 )   PDF (1880KB) ( 49 )  

At the 19th G20 Summit in Brazil in November 2024, China promoted the development of sustainable solutions to climate change, biodiversity loss, and environmental pollution. This continued the theme of the 2016 G20 Hangzhou Summit, at which China placed development at the center of the G20’s macroeconomic policy coordination for the first time, adopting the G20 Action Plan on the United Nations 2030 Agenda for Sustainable Development and the G20 Initiative on Supporting Industrialization in Africa and Least Developed Countries. In Brazil, China announced actions on advancing modernization in Africa over the next three years with a Chinese commitment of RMB360 billion yuan in financial support. In this article, we examine the potential role of geoscience research and practice in development, particularly in the sustainable use of natural resources, the prevention of climate change impacts, as well as mitigation of geo-hazards and their health implications, indicating the areas where China’s geoscience for Africa is strong and where it requires more effort.

We find that although China is the world’s leading publisher of scientific papers, its contribution to geoscience in Africa (the globe’s fastest-growing economic area), as shown by bibliometric research, appears to be rather small and inconsistent with the research priorities of Africa.

Amongst the priorities for geoscience research in Africa, which are not addressed substantially by the research conducted so far, are sustainable mineral and hydrocarbon development, hydrology and hydrogeology, climate change and resilience, natural hazards, medical geology,agrominerals, and geoscience education and training. A particular opportunity for African nations is the presence of critical minerals -minerals needed for the energy transition and for batteries for electric cars in particular. Africa is well-endowed with many of these critical materials, such as rare earth elements and platinum group metals. Several research groups stress the need for the agency on the part of African institutions to map out these valuable resources, understand their value and the economics and sustainability of their extraction, encourage local business, attract investment, and scrutinize proposals from potential international investors to get the best deals.

A strong point of existing China-led geoscience development includes the Deep-time Digital Earth (DDE) program online computing platform and its artificial intelligence tool GeoGPT, which is being developed in partnership with Zhejiang Laboratory. These are being developed with strong China funding support for free and wide global access, with a particular focus on Africa. These advanced tools will help to place the agency of development squarely in the hands of African scientists and institutions.

In summary, the following are recommended: (1) a more coordinated and strategic approach to China-led geoscience research in Africa; (2) an Africa-centered, geoscience funding initiative that concentrates on relevant topics to the continent such as critical minerals exploration and other geological resources, materials and processes and their health implications on the populations and ecosystems in general, as well as climate change and climate change resilience; and (3) continued support for China-led international initiatives that seek to increase the agency and capacity of Africa geoscience researchers, for example the Deep-time Digital Earth platform.

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Mineral-enhanced biological photosynthesis: New breakthroughs in theory and application
LU Anhuai, DU Yifei, FANG Qian, DING Hongrui, LI Yan
2025, 32(1): 466-469. 
DOI: 10.13745/j.esf.sf.2024.12.122

Abstract ( 71 )   HTML ( 14 )   PDF (2598KB) ( 77 )  

Photosynthesis is the primary determinant of crop yield, with the current energy conversion efficiency of crop photosynthesis being only about 2%, which significantly limits the yield of grain and vegetable crops. Earth Science Frontiers is dedicated to advancing global scientific and technological frontiers and addressing primary economic concerns, having reported on a series of our scientific research findings over nearly three decades. Recently, Earth Science Frontiers has continuously been reporting on groundbreaking research on mineral-enhanced biological photosynthesis and its breakthrough applications in solving the international challenge of improving crop yield and quality in agriculture. Our latest studies have further confirmed that the manganese clusters (Mn4CaO5) in plant chloroplasts have an evolutionary and genetic relationship with birnessite in the mineral membrane on the surface of soils and rocks, and both exhibit similar functions in photocatalytic water splitting. The infrared emission spectra of minerals can affect the function of water and promote the function of photocatalytic water splitting. Classical plant photosynthesis is confined to the absorption and conversion of sunlight by manganese clusters in chloroplasts. In contrast, mineral-based non-classical photosynthesis outside of chloroplasts can expand the utilization range of the solar spectrum through functionalized water; that is, by altering the functionality of irrigation water, the efficiency of solar energy conversion can be improved. This has opened up a new way to improve the efficiency of plant photosynthesis. Based on this theory, we have proposed the innovative “mineral-water-photosynthesis” technology, which has achieved a 20%-50% increase in crop yields in field trials, significantly enhancing the yield and quality of various crops. This represents a pioneering example of how natural minerals can influence water functionality to promote biological photosynthesis.

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