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    Global change, inter-sphere interaction and Earth system science
    Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 1-6.   DOI: 10.13745/j.esf.sf.2025.3.88
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    Global change is the result of the synergistic interaction between natural processes and human activities, representing a structural transformation of the Earth system dominated by human actions. Its core lies in the contradiction between the Earth system’s limited carrying capacity and humanity’s unlimited developmental demands, manifesting as changes in climate, ecosystems, and socio-economic systems. Interactions among the Earth’s spheres are key drivers of global change. Precise analysis and prediction of the mechanisms, dynamic evolution, and corresponding climatic, environmental, and ecological effects of these interactions can help uncover the underlying mechanisms of global change, accurately assess the risks of abrupt shifts in the Earth system, and design feasible pathways for sustainable development. This special issue focuses on cutting-edge scientific questions related to global change and inter-sphere interactions, elaborating on mechanisms of critical interfacial processes of the Earth system and their feedback relationships with human activities through Earth system observation, modeling, and governance. The collection reviews the current state of development and progress in research on global change and inter-sphere interactions, identifies challenges and frontier scientific issues in Earth system science, and outlines future directions. The aim is to provide robust theoretical support for addressing global change, fostering harmonious humans-nature coexistence, and achieving sustainable development of socio-ecological systems.

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    Big Science program on CHEMICAL EARTH: Global distribution and cycle of key elements
    WANG Xueqiu
    Earth Science Frontiers    2025, 32 (1): 1-10.   DOI: 10.13745/j.esf.sf.2024.10.33
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    The Big Science Program on CHEMICAL EARTH was first proposed by Wang et al. in 2008. An initiative was lunched in 2016 by the UNESCO International Centre on Global-scale Geochemistry and accepted by the UNESCO in 2023. The goal was to establish a digital CHEMICAL EARTH presenting all naturally occuring chemical elements on Earth to provide data services for sustainable global development; the scientific and technical aims were to understand the spatiotemporal distribution and cyclying of key elements on Earth, and to develop high-quality laboratory chemical analysis and big data mining technology. This article summaries the major achievements to date. (1) A Global Geochemical Baselines Network is established covering 33% of the world’s land area. It provides spatial distribution patterns and geochemical baselines of 76 chemical elements, allowing delineation of REE, Li, Cu and Au super-enrichment targets and, whereby, the discovery of giant HREE deposits in Yunnan. (2) A global distribution map of eight toxic heavy metals in soil is completed. It finds that Europe has the highest pollution risks compared to China and the United States, with 48% of its land area exceeding the pollution risk limits for the studied heavy metals. This results from Europe’s long history of industrial development without early pollution control technology, allowing large-scale toxins release into the environment. (3) China Geochemical Observation Network is established based on three rounds of resampling campaigns throughout China. It finds significant increase of Cd, Hg, As, and Ca in the past 30 years, and that cycling of Hg occurs in the form of nano cinnabar (HgS) grains, not mercury vapor as traditionally recognized. (4) The program promotes public access to geochemical big data by providing QR codes, which allow anyone to query big data through websites and mobile phones. Geochemical big data show that farmlands in China’s major grain-produing regions overall are of good quality in terms of food safety.

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    Medium-deep geothermal exploration and development technology and typical applications
    SUN Huanquan, GAO Nan’an, WU Chenbingjie, GUO Dianbin, FANG Jichao, ZHAO Lei, LIU Jian, ZHOU Zongying
    Earth Science Frontiers    2025, 32 (2): 230-241.   DOI: 10.13745/j.esf.sf.2025.1.60
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    In the context of the global energy structure transformation and the increasing demand for clean energy, medium-deep geothermal resources, as a practical, localized, and stable renewable energy source, are receiving significant attention from the international community. China’s geothermal resources exhibit distinct regional characteristics, with higher geothermal potential in the eastern and southwestern regions. It is estimated that the theoretical energy reserves of China’s medium-deep geothermal resources are equivalent to 1250 billion tons of standard coal. At present, China has established a relatively mature technical system for the exploration and development of medium-deep geothermal resources, covering all aspects from exploration to efficient development, greatly enhancing the accuracy of resource exploration and development efficiency. In geothermal exploration and evaluation technologies, comprehensive analysis of geothermal system reveals the enrichment patterns and formation mechanisms of geothermal resources; Comprehensive geophysical exploration focuses on fracture structural and water-bearing reservoirs to delineate target areas; Geothermal resource site selection and evaluation technology has guided the geothermal exploration work in North China, with a success rate of over 80% for the deployed exploration wells. In high-efficiency geothermal development technologies, Multi-field coupling simulations optimize extraction parameters to prevent thermal breakthrough while meeting production demands.; Geothermal energy development drilling and completion technology adapts to local conditions to refine well structure and drilling and completion processes, effectively ensuring the safe and efficient construction of geothermal wells; Natural recharge technology for geothermal water and heat extraction without water consumption technology achieve full-cycle recharge of geothermal water and sustainable development of geothermal energy. Notable large-scale applications include the Xiong’an area (Bohai Bay Basin) and Xianyang region (Guanzhong Basin), representing carbonate and sandstone reservoir development respectively. Based on geological modeling and numerical simulation, specific well network layout and development parameter optimization schemes have been proposed for the above two regions, providing reference for efficient, environmentally friendly, and sustainable development of geothermal resources in areas with similar geological conditions.

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    Surface-Earth response to deep-Earth processes and consequential natural disasters
    LIU Jing, SUN Zhaotong, WANG Wenxin, LI Yunshuai, YAO Wenqian, CUI Fengzhen, LIU Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 7-22.   DOI: 10.13745/j.esf.sf.2025.3.11
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    The interaction between deep- and surface-Earth processes is an important component of Earth system science research. Deep-Earth processes drive the material and energy cycling between the deep and shallow Earth through various mechanisms, such as tectonics and volcanism, thereby influencing the Earth’s surface system. These influences are specifically manifested in the following ways: (1) Tectonics, by reshaping landscapes, regulate erosion and sedimentation processes at the watershed scale. (2) Volcanism and tectonics drive climate change on geological timescales, by affecting atmospheric composition and circulation patterns, with silicate weathering playing a significant role in regulating atmospheric CO2 levels. (3) Deep-Earth processes have a dual impact on ecosystem evolution, potentially causing species extinction while also promoting biodiversity. (4) Earthquakes and geological disasters impact the stability of socio-ecological systems; the impacts may be further exacerbated by global climate change. The cascading disasters triggered by earthquakes and their long-term impacts on social systems warrant attention and research efforts in disaster-prone China. With the advancement of observational technologies, earth system science studies will achieve a deeper understanding of the coupling mechanisms between deep- and surface-Earth systems. This includes quantifying the intensity of interaction, predicting the evolution of natural disasters, and enhancing the resilience of socio-ecological systems to such disasters. This paper provides a systematical review of the cross-scale coupling of deep earth-surface earth-socio-ecological processes, helping to understand the earth system evolution.

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    A new paradigm for mineral resource prediction based on human intelligence-artificial intelligence Integration
    CHENG Qiuming
    Earth Science Frontiers    2025, 32 (4): 1-19.   DOI: 10.13745/j.esf.sf.2025.7.20
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    Mineral resources serve as a critical material basis supporting socio-economic development, with their formation and distribution governed by the complex interactions between deep Earth processes and surface environmental conditions. With the ever-growing global demand for mineral resources, traditional mineral resource prediction methods face significant challenges in their application to covered regions, deeply buried deposits, and non-traditional exploration regions. In recent years, the rapid development of big data and artificial intelligence (AI) technologies has provided significant opportunities for mineral resource research, offering transformative tools for mineral prediction and assessment. This paper systematically reviews the theoretical evolution of mineral prediction and explores a new AI- and big data-powered paradigm, which includes an expanded concept of “ore deposits”, multi-system integrated modeling involving the Earth system, metallogenic system, exploration system, and prediction-evaluation system, intelligent integration of geological survey data and long-tail scientific data, and the deep integration of human intelligence (HI) and artificial intelligence (AI). Based on several representative case studies from recent research projects completed by the author’s team, including integrated mineral prediction in covered regions, quantitative prediction of deep mineral resources, and the construction of a global porphyry copper deposit knowledge graph, this paper demonstrates the innovative application of nonlinear theory and AI techniques in addressing key scientific issues related to mineral prediction. Building on this, the paper anticipates that future data-driven and intelligence-integrated research paradigms will fundamentally transform the paradigm of mineral prediction approaches, significantly enhancing their accuracy and efficiency. This shift will accelerate the transformation of Earth science research from traditional, experience-based practices to intelligent and quantitative methodologies, providing essential theoretical and technological support for the next generation of strategic breakthroughs in mineral exploration.

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    Advances in tectonics-geomorphology-climate-ecosystem dynamics
    XU Sheng, YANG Ye, ZHANG Maoliang, SHAO Yanxiu, LI Yunshuai, XU Hai, LIU Jing, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 23-34.   DOI: 10.13745/j.esf.sf.2025.3.12
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    The interactions between tectonics, geomorphology, climate, and ecosystems constitute the foundation of surface-Earth system dynamics. Investigating these complex interactions and their implications is a central objective of systems science. For instance, tectonic processes not only drive landscape evolution but also exert significant influence on climate change and ecosystem dynamics. Conversely, climate change drives landscape transformation and ecosystem shifts, while ecosystems, through biogeochemical cycles, provide feedback mechanisms that influence landscape evolution and climate regulation. The evolution of the surface-Earth system inherently depends on the synergistic interactions among these components. Over geological timescales, plate tectonics and landscape reorganization have triggered regional climate shifts and biological turnovers. On modern timescales, these couplings maintain the dynamic equilibrium of Earth’s surface environment. Systematic research into these interactions is critical for understanding the sustainability of the surface-Earth system. This study reviews the coupling relationships between tectonics, climate, and landscapes, as well as between landscapes, climate, and ecosystems. It aims to uncover the dynamics of tectonics-geomorphology-climate-ecosystem interactions and establish a systematic framework for surface-Earth system science. The Tibetan Plateau, with its unique tectonic activity, complex geomorphology, diverse climatic zones, and sensitive ecosystems, serves as a natural laboratory for studying these dynamics. Comprehensive investigations into the interactions on the Tibetan Plateau will address key scientific questions in surface-Earth system science and offer valuable insights into global environmental change. Advancing research on tectonics-geomorphology-climate-ecosystem dynamics requires quantitative studies on the coupling and co-evolution of these factors. This can be achieved through interdisciplinary integration, field observations, laboratory analyses, big data approaches, and deep learning in artificial intelligence. Developing dynamic coupling models of Earth’s systems will enhance our understanding of the interactions among Earth’s spheres and provide theoretical support to tackle challenges posed by global change.

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    Challenges and research pathways for the evolution of water resources supply and demand in the Beijing-Tianjin-Hebei Region
    CHEN Xi, GAO Man, DONG Jianzhi, WANG Zhe
    Earth Science Frontiers    2025, 32 (3): 436-444.   DOI: 10.13745/j.esf.sf.2025.3.42
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    In the past one hundred years, water demand and supply in the Beijing-Tianjin-Hebei region increased greatly due to rapid socio-economic development, accelerated urbanization, expansion of crop land as well as climate change. It has resulted in substantial reduction of regional water resources that cannot meet the total water requirement. This situation has substantially alleviated in the recent years when executions of comprehensive measures of large-scale intra-basin water transfer, water conservation, and economic structure adjustments. As the low-carbon and greening development policy has announced for controlling global change and will be executed in future, the socio-economy and ecological environment in the region will be further adjusted. It brings new challenges and opportunities to make schemes of balancing available water resources and demands. This study divides the hydrological regime and the evolution of water resources supply/demand in the Beijing-Tianjin-Hebei region into three stages, based on the characteristics of water resources and supply/demand relationship, and their causes, treating measures and pathways. The shifts in the drives of the water resources evolution in different stages of the “S-type” curve are systematically analyzed. The impact of low-carbon development, green growth, and climate change adaptation on the transformation of water resource supply and demand patterns is elucidated. Then, we propose the approaches to enhance the local water recovery capacity through the study of the water cycle mechanism, as well as pathways to improve the water resource security capacity in response to extreme climate change. This study will provide scientific support for the sustainable utilization of water resources in the Beijing-Tianjin-Hebei region and other water-scarce areas.

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    Isotope geochemistry and its application in Earth system sphere interactions and global change
    CHEN Jiubin, ZHENG Wang, LIU Yi, SUN Ruoyu, YUAN Wei, MENG Mei, CAI Hongming, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 137-155.   DOI: 10.13745/j.esf.sf.2025.3.2
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    The Earth system comprises the geosphere, biosphere, and anthroposphere, which interconnected each other. A central focus of Earth system science lies in investigating the exchange of materials and energy within and between these spheres, as well as their dynamical mechanisms. Such exchanges are governed primarily by hydrological and biogeochemical cycles of major and trace elements, making the biogeochemical cycling of elements the link among Earth’s subsystems and a critical mechanism driving or modulating global change. Furthermore, under rapid socioeconomic development, human activities profoundly alter these biogeochemical cycles, inducing unprecedented transformations in the Earth system. Key challenges in Earth system science include precisely characterizing biogeochemical cycles, unraveling their dynamical mechanisms, predicting their future trajectories, and evaluating their ecological impacts. Isotopic techniques provide robust tools for tracing cross-sphere material fluxes and biogeochemical processes, playing an indispensable role in studying sphere interactions and global change. This paper reviews recent advances in applying traditional and non-traditional stable isotopes to track sphere interactions and global change, synthesizes typical isotopic signatures across Earth’s subsystems, delineates isotopic fractionation mechanisms at sphere interfaces, traces anthropogenic impacts on environmental-ecological systems, and identifies critical scientific challenges and frontiers in isotope geochemistry within the Earth system science framework. Future research should integrate isotopic approaches with emerging fields like geography, ecology, molecular biology, Earth system modeling, artificial intelligence, and big data analytics to refine isotope-enabled theoretical frameworks for biogeochemical cycling under multi-sphere, multi-process, and multi-element coupling. Such integrative efforts will deepen understanding of sphere interactions, human-global change linkages, and environmental-life coevolution.

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    Progress and scientific frontiers in numerical simulation of the Earth system
    ZHU Jialei, DONG Jianzhi, ZHANG Yonggen, SUN Shaobo, JIANG Zhe, ZHOU Haoran, ZHAO Xi, LI Pan, CHEN Wei, WANG Lichun, LI Xin, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 118-136.   DOI: 10.13745/j.esf.sf.2025.3.9
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    Earth system models are essential tools for understanding and predicting global change and have made significant strides in recent years. These advancements are evident in the more detailed representation of coupled processes across Earth’s spheres and the integration of increasingly sophisticated physical and chemical processes within them. The reduction in model uncertainties has been driven by the adoption of innovative methods and cutting-edge technologies. Nonetheless, challenges persist, including limitations in capturing complex interactive processes, difficulties in simulating socio-ecological systems, and the need to enhance the modeling of regional extreme events. Moving forward, efforts should prioritize fostering interdisciplinary collaboration, harnessing emerging technologies to improve data acquisition and predictive accuracy, and deepening research into socio-ecological processes and their impacts. Such initiatives will bolster the ability to model and predict regional extreme events while paving the way for next-generation Earth system models that seamlessly integrate land, ocean, atmosphere, and human interactions. These advancements are vital for supporting sustainable development and providing a robust scientific foundation to address and anticipate global changes.

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    Development and prospect of ecohydrology under global change
    CHEN Xi, DONG Jianzhi, WANG Lichun, ZHANG Yonggen, WANG Xuejing, DI Chongli, GAO Man, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 52-61.   DOI: 10.13745/j.esf.sf.2025.3.13
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    Under the context of global change, the spatiotemporal scope of eco-hydrological research has expanded significantly. Eco-hydrology studies originally focused on the mutual feedback between water and living organisms, which now encompass the interactions and evolutionary mechanisms of water, non-living elements (e.g., atmosphere, soil, and rocks), and human activities. Based on the concept of Earth system science, and considering current research gaps and paradigm shifts, this paper reviews eco-hydrological processes from multiple dimensions including the Soil-Plant-Atmosphere Continuum (SPAC), the Earth’s Critical Zone, and watersheds. It first discusses the mechanisms of water, energy, and matter transfer and exchange between bedrock, soil, vegetation, and atmospheric interfaces. The paper then elucides the co-evolution of bedrock weathering, soil formation, and eco-hydrological processes under the influence of climate change and human activities, and their impacts on the hydrological cycle and material balance. It also highlights the importance of watersheds as crucial intermediate units connecting global and local scales. In response to the water and ecological resources sustainability, the paper disscusses potential breakthroughs for eco-hydrological research in the context of artificial intelligence, including multi-source data fusion, modeling methods that integrate physical processes with machine learning, and interdisciplinary collaborative research paradigms. As such, this paper aims to shed lights into the synergistic development of ecology, hydrology, and society, which may enhance the ecosystem quality and promoting green socio-economic development.

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    Advance of 3D smart geological modeling
    YE Shuwan, HOU Weisheng, YANG Jie, WANG Haicheng, BAI Yun, WANG Yongzhi
    Earth Science Frontiers    2025, 32 (4): 182-198.   DOI: 10.13745/j.esf.sf.2025.4.72
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    High-precision 3D geological modeling serves as a crucial foundation for the rapid advancement of digital twin technology, providing essential support for resource prediction, engineering planning, and disaster prevention. Traditional 3D geological modeling methods often rely on manual interaction, struggling to meet the demands of precise structural representation and real-time updates in complex geological conditions. To overcome these limitations, the recent introduction of machine learning and deep learning approaches offers new intelligent solutions, significantly improving model automation and the representation of complex geological structures. This paper systematically reviews the development of 3D geological modeling, summarizing technical characteristics across three distinct stages: semi-intelligent modeling, machine learning-based modeling, and deep learning-based modeling. Furthermore, we comprehensively analyze the integrated applications of deep learning with uncertainty analysis, transfer learning, principal component analysis and multiple-point geostatistics. Considering existing challenges such as sparse data processing, computational complexity, model interpretability, and real-time updating capabilities, we propose future research trends, including multimodal data fusion, embedding of geological knowledge, lightweight model optimization, uncertainty quantification and Large Language Models. With ongoing progress in intelligent modeling techniques, the accuracy, reliability, and adaptability of 3D geological models are expected to continuously improve, further advancing the application and engineering practice of digital twin technology in geology.

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    Super enrichment of critical elements: Implications for stratgic mineral resources
    WNAG Xueqiu, LI Longxue, WU Hui, WANG Wei
    Earth Science Frontiers    2025, 32 (1): 11-22.   DOI: 10.13745/j.esf.sf.2024.10.40
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    The strategic mineral resources contain 56 critical elements, most of which have low crustal abundance and require 10-1000 folds of enrichment to form ore deposits. This results in extremely uneven distribution of mineral resources. Thus the delineation of super enrichment area is the key to the resource prospecting and discovery of large-sized ore deposits. The enrichment intensity of elements can be quantitatively expressed by the metallogenic acumulatioin index (m.a.i), the tonnagea acumulatioin index (t.a.i) and the anomalous concentration index (a.c.i). Statistical analyses of 35 strategic mineral species, including precious, non-ferrous, ferrous, rare and dispersed elements, rare earth elements and radioactive metals, revealed that (1) elements with a m.a.i greater than 1000 were antimony, bismuth, rhenium and gold; a m.a.i of >100-1000 were silver, tungsten, tin, chromium, lithium, cesium, tellurium, indium, uranium and platinum group elements; and a m.a.i of >10-100 were copper, nickel, chromium, beryllium, rubidium, scandium, niobium, tantalum, zirconium and primary rare earth elements. Iron, aluminium, titanium and ion-adsorbed rare earth elements had a m.a.i ≤10. (2) Large-sized ore deposits should have a t.a.i greater than 107, generally 1010, and a a.c.i greater than 2.0. Indicators for element super enrichment also included anomaly greater than >100-1000 km2, with anomalous hierarchical structure across more than three layers, and with occurence of at least four associated elements. The element enrichment factor and potential resources in a geochemical block may be estimated using areal and cubic metal contents. The qualitative and quantitative geochemical characteritics of element super enrichment provide evaluation criteria for the assessment and discovery of large-sized mineral deposits.

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    The weathering evolution during the Eocene-Oligocene Transition in the surrounding regions of the Tibetan Plateau and its response to global and regional climate changes
    CUI Hao, WEI Gangjian
    Earth Science Frontiers    2025, 32 (3): 274-287.   DOI: 10.13745/j.esf.sf.2025.3.23
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    The Eocene-Oligocene Transition (EOT) represents one of the most significant global cooling events of the Cenozoic era, marking a key shift in the Earth’s climate system from a “greenhouse” to an “icehouse” mode. While deep-sea sediment records consistently document this cooling event, numerous terrestrial records reveal significant spatial variability in climate responses across different regions, highlighting the importance of the interaction between global climate background and regional environments. The uplift of the Tibetan Plateau has significantly influenced global continental weathering patterns and is closely linked to Cenozoic global climate changes. Therefore, the evolution of continental weathering around the plateau provides an excellent indicator of both global and regional climate changes. This paper summarizes the weathering evolution records from the margins of the Tibetan Plateau during the Late Eocene to Oligocene, combining our weathering history from the Lühe Basin (35.5-25.5 Ma) in the southeastern Tibetan Plateau, to explore the commonalities and differences in weathering evolution during this period. The results show that in most regions of the northern Tibetan Plateau, weathering intensity decreased from the Late Eocene, coupled with cooling and aridification processes, while at the southeastern margin exhibited multi-stage temperature fluctuations and a sustained humid climate. This regional difference is mainly driven by the combined effects of global cooling, tectonic uplift, and the evolution of the monsoon system. This study provides crucial insights into the weathering patterns and driving mechanisms of different regions of the Tibetan Plateau during the EOT.

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    Current status, challenges, and future directions of research on hydrological processes, water environment, and water resources in the urban Earth’s critical zone
    SANG Liyuan, GUO Wei, ZHANG Jingwen, LIU Yixuan, ZHANG Tongkun, ZHANG Zhuqing, YUE Zhanpeng, LI Danyang, ZHANG Run, ZHANG Xu, TANG Weiping, LIU Zhanhang, DING Hu, LANG Yunchao, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 445-461.   DOI: 10.13745/j.esf.sf.2025.3.28
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    Urbanization and urban development are among the most significant human activities impacting the ecological environment. Accompanied by population growth and increased consumption levels, urbanization has triggered a series of complex water resource and water environment issues. Inadequate urban drainage systems, particularly in developing countries, exacerbate the deterioration of water environments and pose a serious threat to urban health and sustainable development goals. Therefore, it is a key scientific issue to explore the complex relationship between the three-dimensional urban subsurface structure, hydrological processes and water resources management from the perspective of earth system science. This study, based on the ‘Earth’s critical zone science’ and ‘social-ecological system science theory’, systematically reviews the coupling mechanisms between urban surface structures, dynamic changes in the water cycle, water quality, and the sustainable utilization of water resources. By integrating physical, chemical, and biological processes, this study reveals the impact mechanisms of impervious surface expansion on the precipitation-runoff-infiltration dynamic balance, pollutant transport, and the supply-demand distribution of water resources. We emphasizes the importance of the coupling between social and natural systems for the optimization of water resource management. In addition, the study combines the linkage between hydrological processes and ecosystem services, analyses the role of hydrological dynamics in regulating the functioning of ecosystem services and human well-being, and initially proposes a framework for the sustainable management of urban water resources based on the social-ecological system theory. This framework provides scientific support for understanding the coupling mechanism of structure-process-function of urban hydrological systems. This review not only helps to understand the complex relationship between urban hydrological dynamics and ecological services, and to break down the barriers between hydrological subdisciplines, but also provides a theoretical basis and practical guidance for managing urban water resources and setting policies.

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    Biodegradation mechanisms and biological enhancement of microplastics in the environment
    DING Jiayan, LIU Xiangyu, CHEN Xuwen, TANG Lei, GAO Yanzheng
    Earth Science Frontiers    2025, 32 (3): 248-262.   DOI: 10.13745/j.esf.sf.2025.3.45
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    As a type of emerging pollutants, microplastics have become pervasive contaminants affecting ecosystem safety and human health. Microbial biodegradation of microplastics has attracted significant attention due to its environmentally friendly and sustainable attributes. Recent advancements have been achieved in the microbial biodegradation of pollutants through biofilms, enzyme engineering, and gene regulation. Biofilms influence the microplastics degradation by altering surface properties, leaching additives, enzyme or radical attacks, and permeation decomposition. Extracellular enzymes cleave the macromolecular structures, while intracellular enzymes modify substrate structures and process metabolites. Current research focuses on constructing highly efficient enzyme systems. Genetic engineering has enabled the cultivation of engineered bacteria, while bioinformatics aids in identifying functional genes and elucidating the degradation pathways. Metagenomic modification has been used to enhance biodegradation efficiency. This article reviews recent progress in microbial biodegradation of microplastics, encompassing diverse degrading microorganisms, clear degradation metabolic pathways and mechanisms. Multiple microorganisms including bacteria, fungi, and microalgae possess degradation capabilities. Composite microbial consortia synergistically drive the degradation process. Bacteria mainly degrade microplastics by secreting hydrolases and oxidases, which can break the macromolecular chains or change the chemical structure of plastics. Fungi, on the other hand, rely on the secretion of intracellular and extracellular enzymes as well as biological surfactants to break down microplastics into monomers. The mycelium can also enhance the degradation effect. Microalgae can promote degradation by means of photosynthesis, secreting toxins, enzymes, and extracellular polymeric substances. Microplastic degradation typically occurs in four stages: bio-deterioration, fragmentation, assimilation, and mineralization. Different microorganisms exhibit varying efficiencies and mechanisms for microplastics degradation such as polyethylene and polystyrene. By summarizing current research findings, this review provides a theoretical foundation for further in-depth exploration of microbial biodegradation mechanisms and offers potential methods and techniques for eliminating the microplastics in the environment.

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    Investigation into the interface processes of the surface-earth system and the evolution of the pedosphere
    TENG Hui, YU Guanghui, CHEN Chunmei, HAO Liping, ZHANG Jianchao, ZHU Xiangyu, SUN Fusheng, WANG Yuebo, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 35-51.   DOI: 10.13745/j.esf.sf.2025.3.3
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    The soil sphere, a critical interface connecting the atmosphere, hydrosphere, biosphere, and lithosphere, plays a pivotal role in the Earth’s surface system. Here, we review the interfacial processes that govern the formation and evolution of soils, emphasizing their intricate interactions and feedback mechanisms. The formation and evolution of the soil sphere are influenced by physical and chemical weathering processes, gas-water-rock heterogeneous reactions, and biological-organic matter-mineral interactions. These processes vary under different geographical, climatic, and biological conditions, leading to the heterogeneity and material diversity of soils. The paper categorizes interfacial processes into two main types: interactions among inorganic spheres and interactions between the biological and inorganic worlds. Interactions among inorganic spheres include the alteration of rocks by air and water, heat exchange, wind erosion, water-rock reactions, and diagenesis. These processes are crucial for the physical breakdown and chemical transformation of parent materials. Interactions between the biological and inorganic worlds encompass organic carbon input and output through photosynthesis, respiration, and microbial degradation of organic matter, as well as bioweathering, which involves the release of biogenic mineral nutrients and the formation of mineral-organic matter aggregates. The paper also explores the relationship between the soil sphere and the biosphere, highlighting the exchange of matter and energy and the support provided by soils to ecosystems. Additionally, it discusses the role of soils in ecosystem services, such as productivity, biodiversity maintenance, and climate regulation. Finally, the paper emphasizes the importance of multi-temporal and multi-spatial scale studies to understand the impact of surface processes on soil sphere evolution and identifies future research hotspots. Collectively, this paper provides a detailed overview of the interfacial processes that drive soil formation and evolution, highlighting their significance in maintaining ecological balance, supporting human activities, and addressing global environmental challenges.

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    Research progress of coupled hydrological and water environment models in nitrogen cycle of watershed system
    GONG Yaoqi, YUE Fujun, LIU Xin, GUO Tianli, WANG Haoyang, LI Siliang
    Earth Science Frontiers    2025, 32 (3): 183-195.   DOI: 10.13745/j.esf.sf.2025.3.19
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    With the coupled influence of multiple factors, such as climate change and human activity, the excessive input of reactive nitrogen has exacerbated the loss of nitrogen from terrestrial ecosystems to aquatic ecosystems, which has seriously affected the quality of water in the basin. Identifying the spatiotemporal variation characteristics of nitrogen sources and their transformation processes within the watershed system has become a primary objective for preventing and controlling the loss of pollutants and improving regional ecological quality. Understanding the nitrogen cycle in the watershed system faces challenges owing to the diversity of nitrogen sources, complexity of biogeochemical processes, and coupled influence of many factors in the watershed. Among the research approaches, model simulation has become an important tool to reveal the nitrogen transport, transformation and dynamic change processes at the watershed scale owing to its high flexibility, high systematicity, and the ability to simulate and analyze multiple scenarios. This review summarized the characteristics of watershed hydrological models and nitrogen transport models for soil, surface water, and groundwater in watershed, as well as research examples of various models. The models were compared based on their principles, characteristics. Among the many factors affecting the nitrogen cycle, it is analyzed that uncontrolled anthropogenic disturbances and extreme climate change have become important factors disturbing the nitrogen cycle in watersheds. Hydrological process-driven processes and mechanistic studies of water and nitrogen are particularly important. Hydrological biogeochemical models (e.g., CNMM-DNDC, PIHM) constructed based on these models have become an important for obtaining high-precision spatial and temporal distribution patterns of nitrogen in the watershed system and its prediction and analysis. In addition, the combination of big datasets and processes modeling has become an important way to reveal the complexity of the nitrogen cycle process. By synthesizing the applicability of many models to the spatial pattern and intensity of anthropogenic impacts, we sorted the applicable models of nitrogen cycling in the river network area of the coastal plain, which is subjected to strong anthropogenic disturbances. These models may deepen the scientific knowledge of nitrogen cycling under the interactions of surface water, groundwater, and seawater in coastal watersheds of the intertwined zone of sea and land, and assess the quality of the water environment and the environmental effects of the river system of the coastal plain in a more comprehensive and scientific way.

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    Geochemical characteristics and metallogenic potential analysis of porphyry copper deposits in Pakistan
    ZHANG Jing, LI Tianhu, WANG Zhihua, Naghmah HAIDER, HONG Jun, ZHANG Huishan, LIANG Nan
    Earth Science Frontiers    2025, 32 (1): 91-104.   DOI: 10.13745/j.esf.sf.2024.10.45
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    The paper utilizes the geochemical data of stream sediments based on the national-scale (1∶1000000) geochemical mapping project in the outcrop area across Pakistan for the first time. This study aims to determine the geochemical background of copper in the study area, as well as the regional geochemical characteristics and geochemical anomalies associated with large porphyry copper deposits in Pakistan. The geochemical features of the main stratigraphic units and magmatic rocks within this region were examined. The average copper concentration in the outcrop areas of Pakistan is 23.48×10-6, with a background value of 18.6×10-6. This is comparable to the copper abundance found in northwest regions of China and the Tibetan Plateau. The magmatic rocks related to mineralization in porphyry systems are mainly Cenozoic and Mesozoic acid magmatic rocks, with average copper concentrations of 39.09×10-6 and 28.28×10-6, respectively, indicating that copper-rich porphyries are the main source of material. A modeling analysis of the elemental association of Cu, Au, Mo, Ag, Pb, Zn, Co and Cr has been conducted based on the national-scale geochemical data, indicating that the national-scale geochemical anomalies serve as indicators of large and super-large porphyry copper deposits. Based on the theory of geochemical block, the Pfd (Prospecting Favoralble Degress) and Qm (Quality of Mineral) were calculated and sorted by applying the principle and technical innovation of mineral resource potential prediction. On the basis of the geochemical model of typical porphyry copper deposits, with Cu, Mo, Au, Ag as primary indicator elements, and Pb, Zn, Co, Cr as secondary reference indicator elements, combined with the geological background, four prediction areas for porphyry copper deposits were identified. Furthermore, an analysis of the metallogenic potential of these identified prospecting areas was conducted.

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    Earth Science Frontiers    2025, 32 (3): 0-0.  
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    Land/ocean-atmosphere interface science and global change
    FU Pingqing, HU Wei, ZHAO Xi, XU Zhanjie, DING Shiyuan, WU Libin, DENG Junjun, JIANG Zhe, LI Xiaodong, ZHU Jialei, Liu Cong-Qiang
    Earth Science Frontiers    2025, 32 (3): 92-104.   DOI: 10.13745/j.esf.sf.2025.3.1
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    With the intensification of global change, the land/ocean-atmosphere interface, as a key material and energy exchange area in the Earth system, has become an important window for understanding climate change, ecological evolution, and the feedback mechanism of the Earth system. The land/ocean-atmosphere interface processes involve the exchange of energy and materials between the atmosphere and the land and ocean surfaces. They determine the dynamic changes of terrestrial and marine ecosystems, and directly affect the evolution of the Earth system. The research on the land/ocean-atmosphere interface processes is crucial to a deep understanding of the dynamics of the Earth system, which is one of the most important cutting-edge issues in Earth system science. This paper first synthesizes the research on the land/ocean-atmosphere interface from the perspective of Earth system science, summarizes the land/ocean-atmosphere interface and its role in the Earth system, and the relationship between the material and energy exchange processes in the land/ocean-atmosphere interface and global change. Secondly, we reviewed the impact of the land/ocean-atmosphere interface processes on the atmospheric environment, the impact of the land/ocean-atmosphere interface processes on the elemental (e.g., carbon, nitrogen) and hydrological cycles in ecosystems, as well as the feedbacks between the land-ocean-atmosphere system and global climate change. Finally, the research frontiers and challenges in the field of the land/ocean-atmosphere interface science are proposed, including the construction of a multi-scale interdisciplinary research system for the land/ocean-atmosphere interface science, such as the optimization of the integrated space-air-ground stereoscopic observation system, the Earth system modelling and multi-scale coupling mechanisms of the land/ocean-atmosphere interface processes, the land/ocean-atmosphere interface science research in the era of artificial intelligence, as well as the land/ocean-atmosphere interface processes and their impact in climatic and ecological sensitive areas such as polar, alpine and coastal areas. The land/ocean-atmosphere interface science will play a more important role in the fields of climate change response, ecological environmental protection and sustainable development.

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