Petrogenesis of reductive S-type granites in the Pengshan district, northern Jiangxi Province, and their implications for tin enrichment: Insights from zircon trace elements

doi:10.13745/j.esf.sf.2023.9.3

Abstract

Abstract:

The Pengshan tin-polymetallic metallogenic ore field is situated at the transitional junction of the Middle-Lower Yangtze metallogenic belt and the Jiangnan tungsten-polymetallic metallogenic belt. Previous research has indicated that granites associated with large-scale tin mineralization typically stem from highly differentiated peraluminous magmas. However, the precise threshold of oxygen fugacity governing the distribution and migration of tin with mineral phases in reducing magmas remains unknown. It is unclear whether the zonation of tin and tungsten mineralization in northern Jiangxi Province is controlled by the characteristics of the magmatic source or by oxygen fugacity. This study delves into the petrogenesis of granites, the tin source, the redox conditions during the early stages of magmatic evolution, and their influence on the distribution, extraction, and migration of tin within the magma. Through detailed in situ zircon microanalysis of the Pengshan pluton, the findings reveal that the P content of zircon is generally high. The slope of three trend lines fitted by P-(∑REE+Y) is 0.91, 0.85, and 0.81, respectively, aligning with the characteristics of S-type granites (∑REE+Y)<1.15×P. In the Eu/Eu^*-Yb_N/Gd_N diagram, a negative correlation is observed in all rock groups, indicating that the Eu/Eu^* ratios of zircons are constrained by the co-crystallization of titanite and plagioclase. The Hf-Ce⁴⁺/Ce³⁺ zircon and Ti-zircon ratios reflect the degree of reduction in each rock unit within the Pengshan pluton. The zircon Eu anomaly (Eu/Eu^*) and Ce⁴⁺/Ce³⁺ zircon ratio exhibit decreasing trends across the three rock units comprising the Pengshan pluton: post-metallogenic granite porphyry→biotite monzogranite batholith→metallogenic muscovite granite. The sandy-argillaceous sedimentary rocks and spilite formed from marine paleo-volcanic eruptive deposits around 1.5 to 1.3 billion years ago likely served as the initial source of tin in the region. The oxygen fugacity of the muscovite granite is lower than that of the Shimensi deposit, and zircon trace elements indicate that the tin-rich magma possesses lower oxygen fugacity compared to the tungsten-rich magma.

Key words: reductivity, S-type granite, Sn enrichment, zircon, northern Jiangxi Province, Pengshan

CLC Number:

YIN Qingqing, TANG Juxing, XIANG Xinkui, ZHAO Xiaoyan, WANG Fangyue, XU Yumin, GUO Hu, YU Zhendong, XIE Jinling, DAI Jingjing, PENG Bo. Petrogenesis of reductive S-type granites in the Pengshan district, northern Jiangxi Province, and their implications for tin enrichment: Insights from zircon trace elements[J]. Earth Science Frontiers, 2024, 31(3): 133-149.

Figures/Tables 8

Fig.1 Geological map of the Pengshan Sn-polymetallic ore field in Jiangxi Province. Modified after [13,16]. 1—Quaternary;2—D3 glutenite;3—S shale;4—O2+3 limestone;5—O1 dolomite;6— 2+3 mud-banded limestone;7— 1 limestone-bearing shale;8—Z2 silicalite,shale-bearing limestone and glutenite;9—Z1 glutenite;10—Shuangqiaoshan Group quartz-keratophyre and spilite-bearing slate;11—spessartine;12—granite-porphyry;13—silicified fracture belt;14—fault;15—ore deposits and mineral occurrences.

Fig.2 The hand specimen and microscope photos of rocks from the Pengshan pluton. a—the hand specimen of biotite monzonitic granite;b—the hand specimen of muscovite granite;c—the hand specimen of granite-porphyry;d—the microscope photo of biotite monzonitic granite;e—the microscope photo of muscovite granite;f—the microscope photo of granite-porphyry. Kfs—K-feldspar; Pl—plagioclase;Q—quartz;Bi—biotite;Ms—muscovite;Ser—sericite.

Fig.3 Chondrite-normalized REE distribution patterns (a) and box plots of LREE and ∑REE contents (b) in zircons from the Pengshan pluton. Chondrite-normalized values are from [54]; typical distributions patterns of magmatic and hydrothermal zircons are from [38]. G1—Biotite monzonitic granite; G2—Muscovite granite; G3—Granite porphyry.

Table 1 Zircon element composition,Ti-in-zircon temperature,oxygen fugacity (fO2),and Ce4+/Ce3+ ratio data from the Pengshan pluton

样品	分析号			w_B/10^-6
样品	分析号			La			Ce					Pr				Nd				Sm				Eu					Gd					Tb					Dy					Ho					Er				Tm							Yb				Lu			Y			Ti
黑云母二长花岗岩	TLX-5-01			0.01			43.96					0.33				4.66				10.17				0.70					44					16					182					68					292				60							542				99			2 064			8.14
	TLX-5-02			0.02			0.99					0.03				0.74				4.13				0.13					32					12					133					40					139				26							210				36			1 187			5.75
	TLX-5-03			6.53			26.07					2.48				13.05				7.68				0.34					33					13					169					65					307				65							629				119			2 027			7.93
	TLX-5-04			—			6.96					0.05				1.37				3.89				0.18					26					11					141					54					256				56							526				98			1 630			6.13
	TLX-5-05			0.06			18.37					0.16				2.72				7.52				0.28					1					15					195					77					360				81							805				153			2 350			4.23
	TLX-5-06			0.01			4.79					0.06				1.05				3.12				0.40					20					8					95					38					169				36							348				66			1 089			11.72
	TLX-5-07			—			7.78					0.06				0.94				3.98				0.31					27					11					145					58					264				57							532				101			1 717			6.62
	TLX-5-08			—			8.26					0.12				1.71				5.51				0.94					33					13					170					67					313				69							662				127			2 060			9.19
	TLX-5-09			0.02			27.49					0.15				2.19				7.96				0.51					57					26					352					141					663				149							1 440				262			4 459			3.85
	TLX-5-10			0.09			3.43					0.07				0.90				4.69				0.07					37					20					311					133					664				158							1 565				296			4 245			76.17
	TLX-5-11			—			4.95					0.03				1.02				4.23				0.24					34					17					238					98					474				108							1 043				197			3 124			4.46
	TLX-5-12			0.02			8.01					0.06				1.54				4.27				0.31					29					11					132					49					217				46							427				82			1 409			9.03
	TLX-5-13			0.02			6.02					0.05				0.90				3.78				0.24					31					14					208					84					413				100							987				190			2 657			5.36
	TLX-5-14			0.01			3.40					0.03				0.54				2.07				0.10					17					8					120					50					253				59							588				114			1 515			3.60
	TLX-5-15			—			5.23					0.02				0.75				2.94				0.19					22					11					159					66					329				76							770				145			2 067			4.92
	TLX-5-16			—			3.09					0.02				0.64				1.87				0.07					15					8					112					46					230				56							588				114			1 364			3.65
	TLX-5-17			0.00			20.94					0.11				2.28				5.51				0.49					34					13					158					60					266				56							520				97			1 746			11.31
	TLX-5-18			0.08			6.20					0.08				1.68				4.64				0.29					34					16					218					88					415				95							922				173			2 696			6.26
	TLX-5-19			0.01			5.23					0.03				1.35				4.84				0.15					37					19					279					119					592				137							1 343				251			3 892			2.86
	TLX-5-20			0.01			1.97					0.04				0.99				5.93				0.17					47					27					404					164					835				213							2 266				432			5 223			2.85
	TLX-5-21			0.00			15.03					0.09				0.95				3.39				0.35					26					12					169					70					355				83							828				157			2 235			2.90
	TLX-5-22			0.00			6.69					0.07				0.98				3.50				0.25					28					12					163					64					298				65							614				114			1 894			6.84
	TLX-5-23			0.01			1.68					0.03				0.95				5.87				0.15					55					31					442					154					634				128							1 097				169			5 264			3.56
	TLX-5-24			0.02			5.99					0.14				2.81				5.54				1.02					34					12					152					58					258				55							524				98			1 644			14.13
	TLX-5-25			0.09			9.01					0.60				5.68				8.36				0.44					34					14					173					66					303				68							673				123			2 018			5.87
样品	分析号			w_B/10^-6																						Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*					^BCe/ Ce^*						^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品	分析号			Hf				Th			U			P				Nb				Ta				Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*					^BCe/ Ce^*						^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
黑云母二长花岗岩	TLX-5-01			13 007				598			387			491				7.96				3.01				14.75					60					1 302					1 362					0.10					47.85						760								32				-13.51		2.13
	TLX-5-02			13 274				41			234			779				0.78				0.68				7.99					6					628					634					0.04					17.54						728								2				—		—
	TLX-5-03			11 411				166			374			1 413				3.50				2.22				22.78					56					1 401					1 457					0.07					2.74						758								10				-13.93		1.78
	TLX-5-04			12 265				141			289			892				2.27				1.54				24.86					12					1 167					1 180					0.05					33.32						733								29				-16.64		-0.36
	TLX-5-05			11 392				420			935			1 053				6.86				3.85				24.83					29					1 726					1 755					0.05					43.56						701								35				-16.64		0.48
	TLX-5-06			10 750				58			99			654				0.97				0.62				20.76					9					780					790					0.15					31.60						797								22				-14.98		-0.16
	TLX-5-07			12 108				124			244			857				1.98				1.50				24.13					13					1 194					1 208					0.09					81.09						740								45				-16.14		-0.03
	TLX-5-08			12 076				86			194			1 112				2.09				1.47				24.01					17					1 454					1 470					0.21					36.12						772								26				-15.11		0.26
	TLX-5-09			12 825				587			1 673			2 023				13.59				7.27				30.36					38					3 090					3 129					0.07					106.26						693								85				-16.66		0.67
	TLX-5-10			14 491				217			1 374			2 162				70.42				7.28				50.69					9					3 184					3 193					0.02					46.55						1 033								37				-13.81		-3.20
	TLX-5-11			13 297				186			811			1 597				4.91				3.32				37.53					10					2 207					2 217					0.06					46.76						705								39				-18.62		-1.62
	TLX-5-12			12 059				96			139			874				1.54				0.96				17.96					14					992					1 007					0.09					33.53						770								24				-15.08		0.33
	TLX-5-13			13 601				116			534			1 531				2.90				2.24				38.08					11					2 027					2 038					0.07					65.05						721								56				-17.53		-0.94
	TLX-5-14			13 328				78			367			865				2.40				1.99				40.81					6					1 209					1 215					0.05					56.95						687								57				-18.99		-1.51
	TLX-5-15			13 341				102			468			1 209				3.16				2.45				42.71					9					1 578					1 587					0.07					64.12						714								61				-17.82		-1.04
	TLX-5-16			13 891				60			423			859				2.04				1.55				46.23					6					1 170					1 175					0.04					32.63						688								47				-19.16		-1.71
	TLX-5-17			10 509				232			278			895				3.44				1.85				18.66					29					1 203					1 232					0.11					51.87						793								43				-13.45		1.45
	TLX-5-18			12 418				108			406			1 589				3.19				2.01				32.35					13					1 961					1 974					0.07					23.81						735								27				-16.91		-0.68
	TLX-5-19			13 504				230			1 061			2 207				7.41				5.00				43.71					12					2 776					2 787					0.03					32.24						668								35				-19.66		-1.66
	TLX-5-20			15 641				159			2 570			3 288				5.78				4.67				58.22					9					4 388					—					0.03					27.98						668								20				-21.87		-3.87
	TLX-5-21			13 696				317			723			1 014				7.64				3.29				38.58					20					1 700					1 720					0.11					131.26						669								132				-17.69		0.28
	TLX-5-22			13 099				110			215			1 040				1.89				1.36				26.31					11					1 359					1 370					0.08					56.81						744								44				-16.30		-0.26
	TLX-5-23			14 296				67			772			2 797				2.35				2.21				24.26					9					2 710					2 718					0.02					25.50						686								9				-21.24		-3.73
	TLX-5-24			11 813				57			101			917				1.00				0.83				18.42					16					1 193					1 208					0.23					9.79						816								9				-14.32		0.08
	TLX-5-25			12 531				91			236			1 312				2.38				1.38				23.73					24					1 455					1 479					0.08					5.44						730								7				-16.05		0.33
样品		分析号	w_B/10^-6
样品		分析号	La			Ce						Pr					Nd				Sm				Eu					Gd					Tb					Dy					Ho					Er				Tm						Yb				Lu		Y				Ti
白云母花岗岩		ZJL-5-01	0.02			2.20						0.06					1.35				4.54				0.36					35					12					141					48					196				40						353				65		1 440				10.10
		ZJL-5-02	1.50			11.90						0.92					7.60				11.23				0.66					63					22					266					95					402				80						698				121		2 937				9.16
		ZJL-5-03	0.03			7.19						0.07					1.22				5.16				0.20					41					19					251					87					347				71						602				99		2 870				3.42
		ZJL-5-04	0.00			0.65						0.05					1.02				4.48				0.15					41					19					214					63					229				42						344				56		2 114				4.19
		ZJL-5-05	1.01			7.78						1.61					11.43				27.94				0.55					132					74					717					157					575				154						1 751				264		5 851				8.97
		ZJL-5-06	0.05			2.95						0.21					4.40				9.41				0.97					52					19					204					73					298				59						528				91		2 210				22.20
		ZJL-5-07	0.19			3.56						0.13					1.47				3.21				0.15					22					9					105					34					125				24						215				37		1 030				5.90
		ZJL-5-08	0.00			0.72						0.02					0.64				3.69				0.17					32					15					167					51					182				33						266				42		1 622				5.41
		ZJL-5-09	0.01			0.60						0.03					0.90				4.26				0.18					46					25					317					111					453				89						789				134		3 789				4.22
		ZJL-5-10	—			4.60						0.05					1.71				3.97				0.19					26					11					117					38					151				29						255				43		1 150				6.18
		ZJL-5-11	0.01			1.88						0.07					2.37				8.17				0.43					56					21					202					55					180				30						245				40		1 712				7.70
		ZJL-5-12	0.01			1.28						0.06					0.99				4.70				0.16					41					18					217					72					271				52						441				74		2 316				6.01
		ZJL-5-13	0.03			3.84						0.38					5.26				10.99				0.79					65					23					267					93					364				69						602				102		2 812				13.24
		ZJL-5-14	0.01			1.36						0.06					0.79				4.41				0.34					40					16					172					54					199				38						329				57		1 634				5.78
		ZJL-5-15	0.00			2.00						0.10					2.47				7.93				0.45					53					19					203					59					209				37						303				50		1 766				8.81
		ZJL-5-16	0.13			56.43						0.63					10.39				23.08				2.38					125					41					454					158					636				122						1 044				175		4 796				46.85
		ZJL-5-17	—			1.20						0.09					1.58				5.72				0.30					44					17					193					66					267				53						473				83		2 039				8.99
		ZJL-5-18	0.00			0.94						0.06					1.19				4.83				0.18					36					15					144					38					121				19						152				23		1 223				6.46
		ZJL-5-19	—			1.00						0.05					1.20				5.28				0.25					35					14					152					50					191				35						298				48		1 488				7.04
		ZJL-5-20	0.02			1.40						0.07					1.54				4.81				0.23					38					15					166					53					210				40						353				59		1 661				8.40
样品		分析号	w_B/10^-6																									Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*				^BCe/ Ce^*				^CT_Ti-in-zircon/ ℃									^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品		分析号	Hf				Th			U				P				Nb				Ta						Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*				^BCe/ Ce^*				^CT_Ti-in-zircon/ ℃									^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
白云母花岗岩		ZJL-5-01	12 284				57			187				891				0.96				0.73						12.33					9					889					898					0.09				12.76						781					10					-14.62			0.54
		ZJL-5-02	12 248				209			204				1 506				1.91				1.15						13.32					34					1 748					1 782					0.08				5.38						772					10					-12.30			3.07
		ZJL-5-03	15 585				149			792				1 442				2.02				1.52						17.88					14					1 517					1 531					0.04				57.78						683					49					-16.09			1.51
		ZJL-5-04	13 980				49			522				1 205				1.47				1.15						10.10					6					1 007					1 013					0.03				6.56						700					3					-19.56			-2.42
		ZJL-5-05	45 346				105			9 847				6 379				10.89				39.77						15.98					50					3 824					3 875					0.03				3.88						770					3					-16.22			-0.80
		ZJL-5-06	11 470				83			176				897				1.11				0.76						12.31					18					1 324					1 342					0.13				3.34						867					3					-12.51			0.88
		ZJL-5-07	13 005				45			201				722				1.05				0.56						12.01					9					571					579					0.06				12.33						730					15					-14.89			1.47
		ZJL-5-08	14 129				39			426				1 036				0.93				0.83						9.97					5					788					793					0.05				15.22						722					5					-18.58			-2.01
		ZJL-5-09	14 202				43			591				2 037				1.42				1.57						20.88					6					1 963					1 969					0.04				7.35						700					6					-19.40			-2.28
		ZJL-5-10	13 236				90			193				615				1.31				0.86						11.88					11					670					681					0.06				14.54						734					16					-14.56			1.70
		ZJL-5-11	13 351				77			396				970				1.13				0.84						5.28					13					829					842					0.06				6.40						755					2					-17.16			-1.39
		ZJL-5-12	13 519				61			410				1334				1.31				1.13						13.01					7					1 186					1 193					0.03				14.30						732					8					-17.22			-0.90
		ZJL-5-13	12 650				129			208				1165				1.10				0.86						11.17					21					1 586					1 607					0.09				3.55						809					3					-13.44			1.11
		ZJL-5-14	13 120				49			284				1 043				0.94				0.83						10.02					7					904					911					0.08				22.20						728					9					-16.95			-0.53
		ZJL-5-15	13 323				74			266				954				0.72				0.66						6.88					13					933					946					0.07				6.06						768					2					-15.72			-0.26
		ZJL-5-16	10 252				1 039			551				1 071				8.98				3.01						10.08					93					2 754					2 847					0.14				28.11						962					28					-7.09			4.61
		ZJL-5-17	12 558				46			157				1 118				0.62				0.55						12.92					9					1 197					1 206					0.06				6.42						770					4					-15.80			-0.38
		ZJL-5-18	13 629				51			342				763				1.00				0.74						5.08					7					548					555					0.04				7.49						738					2					-21.26			-5.10
		ZJL-5-19	12 817				34			141				894				0.59				0.62						10.18					8					825					832					0.06				8.52						746					3					-16.57			-0.60
		ZJL-5-20	12 876				51			237				918				0.91				0.71						11.27					8					935					943					0.05				6.65						763					5					-15.97			-0.40
样品	分析号				w_B/10^-6
样品	La					Ce					Pr				Nd				Sm				Eu				Gd					Tb					Dy					Ho					Er				Tm					Yb			Lu				Y					Ti
花岗斑岩	HHJB-5-01			1.26					32.74					0.83				10.22				18.90				2.94				91					30					336					118					493			98							858		154				3 595				43.39
	HHJB-5-02			3.51					18.40					1.14				5.25				5.08				0.36				30					12					164					66					306			68							650		123				1 954				6.89
	HHJB-5-03			0.03					6.89					0.10				1.63				4.84				0.54				31					12					154					60					268			57							532		102				1 733				8.83
	HHJB-5-04			—					12.94					0.06				1.06				3.45				0.27				29					12					169					70					341			77							747		144				2 131				2.25
	HHJB-5-05			—					9.13					0.07				1.56				4.29				0.40				30					11					141					55					249			55							510		96				1 581				26.28
	HHJB-5-06			0.03					25.56					0.37				5.26				11.42				0.75				55					20					235					87					367			74							661		119				2 584				6.41
	HHJB-5-07			0.08					9.06					0.19				2.20				6.61				0.66				36					14					180					69					311			67							634		119				2 068				8.36
	HHJB-5-08			0.01					10.86					0.07				1.66				5.23				0.48				33					13					165					64					287			61							565		103				1 886				6.48
	HHJB-5-09			7.12					49.65					2.99				20.63				20.30				1.85				85					28					312					110					461			92							814		141				3 247				13.16
	HHJB-5-10			14.44					54.68					5.70				31.72				16.39				1.50				56					18					207					75					318			64							570		105				2 141				9 952.31
	HHJB-5-11			0.07					4.30					0.07				0.63				2.56				0.36				21					10					148					66					346			84							862		166				2 106				14.99
	HHJB-5-12			0.07					20.56					0.18				1.84				4.13				0.59				24					9					109					41					187			40							371		70				1 177				7.92
	HHJB-5-13			—					8.28					0.02				1.12				2.83				0.14				22					9					123					51					237			51							477		86				1 451				4.17
	HHJB-5-14			0.22					13.48					0.35				4.91				10.43				1.73				54					18					227					83					358			72							652		115				2 399				43.15
	HHJB-5-15			0.02					5.89					0.12				1.76				4.79				0.37				34					15					193					75					342			73							693		127				2 226				13.18
	HHJB-5-16			0.06					14.95					0.19				2.97				6.47				0.55				38					16					199					74					335			71							652		117				2 203				9.41
	HHJB-5-17			0.02					10.72					0.10				1.78				5.33				0.34				32					12					155					60					269			58							532		98				1 728				7.05
	HHJB-5-18			0.22					6.79					0.29				2.74				4.34				3.37				31					13					183					77					361			80							744		137				2 317				5.15
	HHJB-5-19			0.02					6.44					0.20				2.69				6.77				1.01				38					13					160					61					266			55							512		93				1 764				11.28
	HHJB-5-20			1.80					11.57					1.06				11.49				23.35				3.28				133					43					471					162					648			125							1 095		191				4 735				64.66
	HHJB-5-21			0.13					19.38					0.16				3.02				7.24				0.47				40					14					176					67					284			60							542		99				1 933				11.20
	HHJB-5-22			0.05					5.69					0.17				2.52				6.66				0.42				48					19					240					94					429			93							860		156				2 911				8.08
	HHJB-5-23			—					6.10					0.06				1.03				4.89				0.30				30					13					167					66					311			68							658		122				2 035				6.48
	HHJB-5-24			0.05					6.40					0.18				1.57				4.90				0.35				29					14					186					75					364			82							787		145				2 365				5.68
	HHJB-5-25			0.03					27.83					0.29				4.99				11.95				1.63				61					21					247					90					381			78							682		123				2 730				8.73
	HHJB-5-26			0.10					22.84					0.48				7.42				14.10				1.11				77					26					299					110					460			92							820		146				3 292				10.33
	HHJB-5-27			0.03					8.53					0.13				1.67				4.52				0.27				33					13					173					68					311			67							624		113				2 054				7.37
	HHJB-5-28			1.41					6.70					0.39				3.41				4.71				0.54				32					14					200					85					407			89							827		152				2 587				4.72
	HHJB-5-29			0.01					5.46					0.06				1.52				5.98				0.59				35					14					172					67					300			64							593		108				2 026				10.16
	HHJB-5-30			0.08					10.08					0.22				4.82				9.26				1.46				49					19					224					83					364			76							696		124				2 555				12.79
样品	分析号			w_B/10^-6																								Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*				^BCe/ Ce^*			^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$						^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品	分析号			Hf						Th			U			P				Nb				Ta				Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*				^BCe/ Ce^*			^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$						^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
花岗斑岩	HHJB-5-01			10 140						747			317			629				3.99				1.55				11.39					67					2 178					2 245					0.22				13.80				952					52							-9.87			2.00
	HHJB-5-02			13 084						126			265			1 133				2.57				1.95				26.16					34					1 419					1 453					0.09				7.91				744					125							-14.23			1.78
	HHJB-5-03			12 185						104			145			964				1.32				0.98				20.71					14					1 216					1 230					0.14				29.22				768					116							-14.97			0.49
	HHJB-5-04			14 422						233			682			827				8.09				5.31				30.77					18					1 590					1 608					0.08				92.18				649					500							-17.96			0.58
	HHJB-5-05			12 558						134			212			824				2.45				1.58				20.79					15					1 145					1 161					0.11				37.62				887					168							-12.55			0.46
	HHJB-5-06			11 932						551			369			515				4.35				2.11				14.53					43					1 618					1 661					0.09				24.60				738					93							-14.38			1.80
	HHJB-5-07			11 800						154			223			979				2.28				1.25				21.31					19					1 430					1 449					0.13				28.84				763					107							-14.94			0.64
	HHJB-5-08			12 910						170			260			777				2.00				1.43				20.54					18					1 292					1 310					0.11				48.19				739					175							-15.35			0.81
	HHJB-5-09			9 315						715			381			984				4.50				1.93				11.53					103					2 043					2 146					0.14				5.51				809					39							-11.62			2.94
	HHJB-5-10			12 134						301			352			1 858				41.67				3.84				12.36					124					1 413					1 538					0.15				2.07				2 807					30							2.32			-0.09
	HHJB-5-11			13 551						158			688			1 030				11.87				5.11				49.70					8					1 703					1 711					0.15				65.06				823					380							-15.79			-1.52
	HHJB-5-12			12 546						255			358			452				5.76				2.67				19.01					27					850					877					0.18				58.41				758					285							-14.10			1.60
	HHJB-5-13			13 125						160			392			645				2.44				1.52				26.39					12					1 056					1 068					0.05				43.78				699					265							-16.96			0.19
	HHJB-5-14			9 680						230			224			783				2.93				1.28				14.61					31					1 581					1 612					0.22				13.60				951					54							-10.82			1.07
	HHJB-5-15			12 391						106			261			1287				2.56				1.39				24.38					13					1 553					1 566					0.09				21.09				809					107							-14.77			-0.21
	HHJB-5-16			13 087						249			407			955				4.23				2.30				20.51					25					1 502					1 528					0.11				25.60				774					134							-14.41			0.91
	HHJB-5-17			12 736						197			260			928				2.55				1.31				20.42					18					1 215					1 234					0.08				41.88				746					157							-15.23			0.73
	HHJB-5-18			14 980						156			601			1 225				3.54				2.56				28.74					18					1 627					1 644					0.89				9.10				718					97							-17.21			-0.54
	HHJB-5-19			11 709						120			153			730				1.21				0.94				16.23					17					1 199					1 216					0.19				14.05				793					52							-14.62			0.28
	HHJB-5-20			9 509						350			255			1 215				5.34				2.08				9.92					53					2 868					2 921					0.18				4.77				1 008					15							-10.44			0.53
	HHJB-5-21			12 023						354			307			753				3.58				1.80				16.54					30					1 282					1 312					0.08				35.90				792					142							-13.48			1.45
	HHJB-5-22			12 434						145			266			1 393				1.67				1.32				21.87					15					1 938					1 953					0.07				13.93				759					67							-15.95			-0.29
	HHJB-5-23			12 723						128			283			1 072				2.19				1.55				26.76					12					1 435					1 447					0.08				65.54				739					179							-16.30			-0.14
	HHJB-5-24			13 572						155			566			1 206				3.78				2.65				32.27					13					1 682					1 696					0.09				29.82				727					147							-16.99			-0.54
	HHJB-5-25			10 020						476			298			556				3.90				1.63				13.60					47					1 683					1 730					0.18				31.15				767					104							-13.28			2.21
	HHJB-5-26			11 868						464			403			961				4.36				2.09				12.94					46					2 030					2 076					0.10				13.62				784					58							-13.58			1.52
	HHJB-5-27			12 416						172			291			1 066				2.22				1.47				23.06					15					1 401					1 416					0.07				32.24				751					159							-15.54			0.33
	HHJB-5-28			14 364						117			467			1 299				2.07				1.51				31.21					17					1 806					1 823					0.13				6.33				710					81							-17.15			-0.28
	HHJB-5-29			11 437						102			176			1 062				1.31				0.93				20.73					14					1 353					1 366					0.13				32.76				782					90							-15.14			0.01
	HHJB-5-30			11 353						208			238			976				2.06				1.37				17.10					26					1 635					1 661					0.21				9.35				806					47							-13.98			0.65

Table 1 Zircon element composition,Ti-in-zircon temperature,oxygen fugacity (fO2),and Ce4+/Ce3+ ratio data from the Pengshan pluton

样品	分析号			w_B/10^-6
样品	分析号			La			Ce					Pr				Nd				Sm				Eu					Gd					Tb					Dy					Ho					Er				Tm							Yb				Lu			Y			Ti
黑云母二长花岗岩	TLX-5-01			0.01			43.96					0.33				4.66				10.17				0.70					44					16					182					68					292				60							542				99			2 064			8.14
	TLX-5-02			0.02			0.99					0.03				0.74				4.13				0.13					32					12					133					40					139				26							210				36			1 187			5.75
	TLX-5-03			6.53			26.07					2.48				13.05				7.68				0.34					33					13					169					65					307				65							629				119			2 027			7.93
	TLX-5-04			—			6.96					0.05				1.37				3.89				0.18					26					11					141					54					256				56							526				98			1 630			6.13
	TLX-5-05			0.06			18.37					0.16				2.72				7.52				0.28					1					15					195					77					360				81							805				153			2 350			4.23
	TLX-5-06			0.01			4.79					0.06				1.05				3.12				0.40					20					8					95					38					169				36							348				66			1 089			11.72
	TLX-5-07			—			7.78					0.06				0.94				3.98				0.31					27					11					145					58					264				57							532				101			1 717			6.62
	TLX-5-08			—			8.26					0.12				1.71				5.51				0.94					33					13					170					67					313				69							662				127			2 060			9.19
	TLX-5-09			0.02			27.49					0.15				2.19				7.96				0.51					57					26					352					141					663				149							1 440				262			4 459			3.85
	TLX-5-10			0.09			3.43					0.07				0.90				4.69				0.07					37					20					311					133					664				158							1 565				296			4 245			76.17
	TLX-5-11			—			4.95					0.03				1.02				4.23				0.24					34					17					238					98					474				108							1 043				197			3 124			4.46
	TLX-5-12			0.02			8.01					0.06				1.54				4.27				0.31					29					11					132					49					217				46							427				82			1 409			9.03
	TLX-5-13			0.02			6.02					0.05				0.90				3.78				0.24					31					14					208					84					413				100							987				190			2 657			5.36
	TLX-5-14			0.01			3.40					0.03				0.54				2.07				0.10					17					8					120					50					253				59							588				114			1 515			3.60
	TLX-5-15			—			5.23					0.02				0.75				2.94				0.19					22					11					159					66					329				76							770				145			2 067			4.92
	TLX-5-16			—			3.09					0.02				0.64				1.87				0.07					15					8					112					46					230				56							588				114			1 364			3.65
	TLX-5-17			0.00			20.94					0.11				2.28				5.51				0.49					34					13					158					60					266				56							520				97			1 746			11.31
	TLX-5-18			0.08			6.20					0.08				1.68				4.64				0.29					34					16					218					88					415				95							922				173			2 696			6.26
	TLX-5-19			0.01			5.23					0.03				1.35				4.84				0.15					37					19					279					119					592				137							1 343				251			3 892			2.86
	TLX-5-20			0.01			1.97					0.04				0.99				5.93				0.17					47					27					404					164					835				213							2 266				432			5 223			2.85
	TLX-5-21			0.00			15.03					0.09				0.95				3.39				0.35					26					12					169					70					355				83							828				157			2 235			2.90
	TLX-5-22			0.00			6.69					0.07				0.98				3.50				0.25					28					12					163					64					298				65							614				114			1 894			6.84
	TLX-5-23			0.01			1.68					0.03				0.95				5.87				0.15					55					31					442					154					634				128							1 097				169			5 264			3.56
	TLX-5-24			0.02			5.99					0.14				2.81				5.54				1.02					34					12					152					58					258				55							524				98			1 644			14.13
	TLX-5-25			0.09			9.01					0.60				5.68				8.36				0.44					34					14					173					66					303				68							673				123			2 018			5.87
样品	分析号			w_B/10^-6																						Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*					^BCe/ Ce^*						^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品	分析号			Hf				Th			U			P				Nb				Ta				Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*					^BCe/ Ce^*						^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
黑云母二长花岗岩	TLX-5-01			13 007				598			387			491				7.96				3.01				14.75					60					1 302					1 362					0.10					47.85						760								32				-13.51		2.13
	TLX-5-02			13 274				41			234			779				0.78				0.68				7.99					6					628					634					0.04					17.54						728								2				—		—
	TLX-5-03			11 411				166			374			1 413				3.50				2.22				22.78					56					1 401					1 457					0.07					2.74						758								10				-13.93		1.78
	TLX-5-04			12 265				141			289			892				2.27				1.54				24.86					12					1 167					1 180					0.05					33.32						733								29				-16.64		-0.36
	TLX-5-05			11 392				420			935			1 053				6.86				3.85				24.83					29					1 726					1 755					0.05					43.56						701								35				-16.64		0.48
	TLX-5-06			10 750				58			99			654				0.97				0.62				20.76					9					780					790					0.15					31.60						797								22				-14.98		-0.16
	TLX-5-07			12 108				124			244			857				1.98				1.50				24.13					13					1 194					1 208					0.09					81.09						740								45				-16.14		-0.03
	TLX-5-08			12 076				86			194			1 112				2.09				1.47				24.01					17					1 454					1 470					0.21					36.12						772								26				-15.11		0.26
	TLX-5-09			12 825				587			1 673			2 023				13.59				7.27				30.36					38					3 090					3 129					0.07					106.26						693								85				-16.66		0.67
	TLX-5-10			14 491				217			1 374			2 162				70.42				7.28				50.69					9					3 184					3 193					0.02					46.55						1 033								37				-13.81		-3.20
	TLX-5-11			13 297				186			811			1 597				4.91				3.32				37.53					10					2 207					2 217					0.06					46.76						705								39				-18.62		-1.62
	TLX-5-12			12 059				96			139			874				1.54				0.96				17.96					14					992					1 007					0.09					33.53						770								24				-15.08		0.33
	TLX-5-13			13 601				116			534			1 531				2.90				2.24				38.08					11					2 027					2 038					0.07					65.05						721								56				-17.53		-0.94
	TLX-5-14			13 328				78			367			865				2.40				1.99				40.81					6					1 209					1 215					0.05					56.95						687								57				-18.99		-1.51
	TLX-5-15			13 341				102			468			1 209				3.16				2.45				42.71					9					1 578					1 587					0.07					64.12						714								61				-17.82		-1.04
	TLX-5-16			13 891				60			423			859				2.04				1.55				46.23					6					1 170					1 175					0.04					32.63						688								47				-19.16		-1.71
	TLX-5-17			10 509				232			278			895				3.44				1.85				18.66					29					1 203					1 232					0.11					51.87						793								43				-13.45		1.45
	TLX-5-18			12 418				108			406			1 589				3.19				2.01				32.35					13					1 961					1 974					0.07					23.81						735								27				-16.91		-0.68
	TLX-5-19			13 504				230			1 061			2 207				7.41				5.00				43.71					12					2 776					2 787					0.03					32.24						668								35				-19.66		-1.66
	TLX-5-20			15 641				159			2 570			3 288				5.78				4.67				58.22					9					4 388					—					0.03					27.98						668								20				-21.87		-3.87
	TLX-5-21			13 696				317			723			1 014				7.64				3.29				38.58					20					1 700					1 720					0.11					131.26						669								132				-17.69		0.28
	TLX-5-22			13 099				110			215			1 040				1.89				1.36				26.31					11					1 359					1 370					0.08					56.81						744								44				-16.30		-0.26
	TLX-5-23			14 296				67			772			2 797				2.35				2.21				24.26					9					2 710					2 718					0.02					25.50						686								9				-21.24		-3.73
	TLX-5-24			11 813				57			101			917				1.00				0.83				18.42					16					1 193					1 208					0.23					9.79						816								9				-14.32		0.08
	TLX-5-25			12 531				91			236			1 312				2.38				1.38				23.73					24					1 455					1 479					0.08					5.44						730								7				-16.05		0.33
样品		分析号	w_B/10^-6
样品		分析号	La			Ce						Pr					Nd				Sm				Eu					Gd					Tb					Dy					Ho					Er				Tm						Yb				Lu		Y				Ti
白云母花岗岩		ZJL-5-01	0.02			2.20						0.06					1.35				4.54				0.36					35					12					141					48					196				40						353				65		1 440				10.10
		ZJL-5-02	1.50			11.90						0.92					7.60				11.23				0.66					63					22					266					95					402				80						698				121		2 937				9.16
		ZJL-5-03	0.03			7.19						0.07					1.22				5.16				0.20					41					19					251					87					347				71						602				99		2 870				3.42
		ZJL-5-04	0.00			0.65						0.05					1.02				4.48				0.15					41					19					214					63					229				42						344				56		2 114				4.19
		ZJL-5-05	1.01			7.78						1.61					11.43				27.94				0.55					132					74					717					157					575				154						1 751				264		5 851				8.97
		ZJL-5-06	0.05			2.95						0.21					4.40				9.41				0.97					52					19					204					73					298				59						528				91		2 210				22.20
		ZJL-5-07	0.19			3.56						0.13					1.47				3.21				0.15					22					9					105					34					125				24						215				37		1 030				5.90
		ZJL-5-08	0.00			0.72						0.02					0.64				3.69				0.17					32					15					167					51					182				33						266				42		1 622				5.41
		ZJL-5-09	0.01			0.60						0.03					0.90				4.26				0.18					46					25					317					111					453				89						789				134		3 789				4.22
		ZJL-5-10	—			4.60						0.05					1.71				3.97				0.19					26					11					117					38					151				29						255				43		1 150				6.18
		ZJL-5-11	0.01			1.88						0.07					2.37				8.17				0.43					56					21					202					55					180				30						245				40		1 712				7.70
		ZJL-5-12	0.01			1.28						0.06					0.99				4.70				0.16					41					18					217					72					271				52						441				74		2 316				6.01
		ZJL-5-13	0.03			3.84						0.38					5.26				10.99				0.79					65					23					267					93					364				69						602				102		2 812				13.24
		ZJL-5-14	0.01			1.36						0.06					0.79				4.41				0.34					40					16					172					54					199				38						329				57		1 634				5.78
		ZJL-5-15	0.00			2.00						0.10					2.47				7.93				0.45					53					19					203					59					209				37						303				50		1 766				8.81
		ZJL-5-16	0.13			56.43						0.63					10.39				23.08				2.38					125					41					454					158					636				122						1 044				175		4 796				46.85
		ZJL-5-17	—			1.20						0.09					1.58				5.72				0.30					44					17					193					66					267				53						473				83		2 039				8.99
		ZJL-5-18	0.00			0.94						0.06					1.19				4.83				0.18					36					15					144					38					121				19						152				23		1 223				6.46
		ZJL-5-19	—			1.00						0.05					1.20				5.28				0.25					35					14					152					50					191				35						298				48		1 488				7.04
		ZJL-5-20	0.02			1.40						0.07					1.54				4.81				0.23					38					15					166					53					210				40						353				59		1 661				8.40
样品		分析号	w_B/10^-6																									Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*				^BCe/ Ce^*				^CT_Ti-in-zircon/ ℃									^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品		分析号	Hf				Th			U				P				Nb				Ta						Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*				^BCe/ Ce^*				^CT_Ti-in-zircon/ ℃									^DCe⁴⁺/ $Ce z i r c o n 3 +$				^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
白云母花岗岩		ZJL-5-01	12 284				57			187				891				0.96				0.73						12.33					9					889					898					0.09				12.76						781					10					-14.62			0.54
		ZJL-5-02	12 248				209			204				1 506				1.91				1.15						13.32					34					1 748					1 782					0.08				5.38						772					10					-12.30			3.07
		ZJL-5-03	15 585				149			792				1 442				2.02				1.52						17.88					14					1 517					1 531					0.04				57.78						683					49					-16.09			1.51
		ZJL-5-04	13 980				49			522				1 205				1.47				1.15						10.10					6					1 007					1 013					0.03				6.56						700					3					-19.56			-2.42
		ZJL-5-05	45 346				105			9 847				6 379				10.89				39.77						15.98					50					3 824					3 875					0.03				3.88						770					3					-16.22			-0.80
		ZJL-5-06	11 470				83			176				897				1.11				0.76						12.31					18					1 324					1 342					0.13				3.34						867					3					-12.51			0.88
		ZJL-5-07	13 005				45			201				722				1.05				0.56						12.01					9					571					579					0.06				12.33						730					15					-14.89			1.47
		ZJL-5-08	14 129				39			426				1 036				0.93				0.83						9.97					5					788					793					0.05				15.22						722					5					-18.58			-2.01
		ZJL-5-09	14 202				43			591				2 037				1.42				1.57						20.88					6					1 963					1 969					0.04				7.35						700					6					-19.40			-2.28
		ZJL-5-10	13 236				90			193				615				1.31				0.86						11.88					11					670					681					0.06				14.54						734					16					-14.56			1.70
		ZJL-5-11	13 351				77			396				970				1.13				0.84						5.28					13					829					842					0.06				6.40						755					2					-17.16			-1.39
		ZJL-5-12	13 519				61			410				1334				1.31				1.13						13.01					7					1 186					1 193					0.03				14.30						732					8					-17.22			-0.90
		ZJL-5-13	12 650				129			208				1165				1.10				0.86						11.17					21					1 586					1 607					0.09				3.55						809					3					-13.44			1.11
		ZJL-5-14	13 120				49			284				1 043				0.94				0.83						10.02					7					904					911					0.08				22.20						728					9					-16.95			-0.53
		ZJL-5-15	13 323				74			266				954				0.72				0.66						6.88					13					933					946					0.07				6.06						768					2					-15.72			-0.26
		ZJL-5-16	10 252				1 039			551				1 071				8.98				3.01						10.08					93					2 754					2 847					0.14				28.11						962					28					-7.09			4.61
		ZJL-5-17	12 558				46			157				1 118				0.62				0.55						12.92					9					1 197					1 206					0.06				6.42						770					4					-15.80			-0.38
		ZJL-5-18	13 629				51			342				763				1.00				0.74						5.08					7					548					555					0.04				7.49						738					2					-21.26			-5.10
		ZJL-5-19	12 817				34			141				894				0.59				0.62						10.18					8					825					832					0.06				8.52						746					3					-16.57			-0.60
		ZJL-5-20	12 876				51			237				918				0.91				0.71						11.27					8					935					943					0.05				6.65						763					5					-15.97			-0.40
样品	分析号				w_B/10^-6
样品	La					Ce					Pr				Nd				Sm				Eu				Gd					Tb					Dy					Ho					Er				Tm					Yb			Lu				Y					Ti
花岗斑岩	HHJB-5-01			1.26					32.74					0.83				10.22				18.90				2.94				91					30					336					118					493			98							858		154				3 595				43.39
	HHJB-5-02			3.51					18.40					1.14				5.25				5.08				0.36				30					12					164					66					306			68							650		123				1 954				6.89
	HHJB-5-03			0.03					6.89					0.10				1.63				4.84				0.54				31					12					154					60					268			57							532		102				1 733				8.83
	HHJB-5-04			—					12.94					0.06				1.06				3.45				0.27				29					12					169					70					341			77							747		144				2 131				2.25
	HHJB-5-05			—					9.13					0.07				1.56				4.29				0.40				30					11					141					55					249			55							510		96				1 581				26.28
	HHJB-5-06			0.03					25.56					0.37				5.26				11.42				0.75				55					20					235					87					367			74							661		119				2 584				6.41
	HHJB-5-07			0.08					9.06					0.19				2.20				6.61				0.66				36					14					180					69					311			67							634		119				2 068				8.36
	HHJB-5-08			0.01					10.86					0.07				1.66				5.23				0.48				33					13					165					64					287			61							565		103				1 886				6.48
	HHJB-5-09			7.12					49.65					2.99				20.63				20.30				1.85				85					28					312					110					461			92							814		141				3 247				13.16
	HHJB-5-10			14.44					54.68					5.70				31.72				16.39				1.50				56					18					207					75					318			64							570		105				2 141				9 952.31
	HHJB-5-11			0.07					4.30					0.07				0.63				2.56				0.36				21					10					148					66					346			84							862		166				2 106				14.99
	HHJB-5-12			0.07					20.56					0.18				1.84				4.13				0.59				24					9					109					41					187			40							371		70				1 177				7.92
	HHJB-5-13			—					8.28					0.02				1.12				2.83				0.14				22					9					123					51					237			51							477		86				1 451				4.17
	HHJB-5-14			0.22					13.48					0.35				4.91				10.43				1.73				54					18					227					83					358			72							652		115				2 399				43.15
	HHJB-5-15			0.02					5.89					0.12				1.76				4.79				0.37				34					15					193					75					342			73							693		127				2 226				13.18
	HHJB-5-16			0.06					14.95					0.19				2.97				6.47				0.55				38					16					199					74					335			71							652		117				2 203				9.41
	HHJB-5-17			0.02					10.72					0.10				1.78				5.33				0.34				32					12					155					60					269			58							532		98				1 728				7.05
	HHJB-5-18			0.22					6.79					0.29				2.74				4.34				3.37				31					13					183					77					361			80							744		137				2 317				5.15
	HHJB-5-19			0.02					6.44					0.20				2.69				6.77				1.01				38					13					160					61					266			55							512		93				1 764				11.28
	HHJB-5-20			1.80					11.57					1.06				11.49				23.35				3.28				133					43					471					162					648			125							1 095		191				4 735				64.66
	HHJB-5-21			0.13					19.38					0.16				3.02				7.24				0.47				40					14					176					67					284			60							542		99				1 933				11.20
	HHJB-5-22			0.05					5.69					0.17				2.52				6.66				0.42				48					19					240					94					429			93							860		156				2 911				8.08
	HHJB-5-23			—					6.10					0.06				1.03				4.89				0.30				30					13					167					66					311			68							658		122				2 035				6.48
	HHJB-5-24			0.05					6.40					0.18				1.57				4.90				0.35				29					14					186					75					364			82							787		145				2 365				5.68
	HHJB-5-25			0.03					27.83					0.29				4.99				11.95				1.63				61					21					247					90					381			78							682		123				2 730				8.73
	HHJB-5-26			0.10					22.84					0.48				7.42				14.10				1.11				77					26					299					110					460			92							820		146				3 292				10.33
	HHJB-5-27			0.03					8.53					0.13				1.67				4.52				0.27				33					13					173					68					311			67							624		113				2 054				7.37
	HHJB-5-28			1.41					6.70					0.39				3.41				4.71				0.54				32					14					200					85					407			89							827		152				2 587				4.72
	HHJB-5-29			0.01					5.46					0.06				1.52				5.98				0.59				35					14					172					67					300			64							593		108				2 026				10.16
	HHJB-5-30			0.08					10.08					0.22				4.82				9.26				1.46				49					19					224					83					364			76							696		124				2 555				12.79
样品	分析号			w_B/10^-6																								Yb_N/ Gd_N					w_B/10^-6															^AEu/ Eu^*				^BCe/ Ce^*			^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$						^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
样品	分析号			Hf						Th			U			P				Nb				Ta				Yb_N/ Gd_N					LREE					HREE					∑REE					^AEu/ Eu^*				^BCe/ Ce^*			^CT_Ti-in-zircon/ ℃								^DCe⁴⁺/ $Ce z i r c o n 3 +$						^E$\lg f_{\mathrm{O}_{2}}$		^FΔFMQ
花岗斑岩	HHJB-5-01			10 140						747			317			629				3.99				1.55				11.39					67					2 178					2 245					0.22				13.80				952					52							-9.87			2.00
	HHJB-5-02			13 084						126			265			1 133				2.57				1.95				26.16					34					1 419					1 453					0.09				7.91				744					125							-14.23			1.78
	HHJB-5-03			12 185						104			145			964				1.32				0.98				20.71					14					1 216					1 230					0.14				29.22				768					116							-14.97			0.49
	HHJB-5-04			14 422						233			682			827				8.09				5.31				30.77					18					1 590					1 608					0.08				92.18				649					500							-17.96			0.58
	HHJB-5-05			12 558						134			212			824				2.45				1.58				20.79					15					1 145					1 161					0.11				37.62				887					168							-12.55			0.46
	HHJB-5-06			11 932						551			369			515				4.35				2.11				14.53					43					1 618					1 661					0.09				24.60				738					93							-14.38			1.80
	HHJB-5-07			11 800						154			223			979				2.28				1.25				21.31					19					1 430					1 449					0.13				28.84				763					107							-14.94			0.64
	HHJB-5-08			12 910						170			260			777				2.00				1.43				20.54					18					1 292					1 310					0.11				48.19				739					175							-15.35			0.81
	HHJB-5-09			9 315						715			381			984				4.50				1.93				11.53					103					2 043					2 146					0.14				5.51				809					39							-11.62			2.94
	HHJB-5-10			12 134						301			352			1 858				41.67				3.84				12.36					124					1 413					1 538					0.15				2.07				2 807					30							2.32			-0.09
	HHJB-5-11			13 551						158			688			1 030				11.87				5.11				49.70					8					1 703					1 711					0.15				65.06				823					380							-15.79			-1.52
	HHJB-5-12			12 546						255			358			452				5.76				2.67				19.01					27					850					877					0.18				58.41				758					285							-14.10			1.60
	HHJB-5-13			13 125						160			392			645				2.44				1.52				26.39					12					1 056					1 068					0.05				43.78				699					265							-16.96			0.19
	HHJB-5-14			9 680						230			224			783				2.93				1.28				14.61					31					1 581					1 612					0.22				13.60				951					54							-10.82			1.07
	HHJB-5-15			12 391						106			261			1287				2.56				1.39				24.38					13					1 553					1 566					0.09				21.09				809					107							-14.77			-0.21
	HHJB-5-16			13 087						249			407			955				4.23				2.30				20.51					25					1 502					1 528					0.11				25.60				774					134							-14.41			0.91
	HHJB-5-17			12 736						197			260			928				2.55				1.31				20.42					18					1 215					1 234					0.08				41.88				746					157							-15.23			0.73
	HHJB-5-18			14 980						156			601			1 225				3.54				2.56				28.74					18					1 627					1 644					0.89				9.10				718					97							-17.21			-0.54
	HHJB-5-19			11 709						120			153			730				1.21				0.94				16.23					17					1 199					1 216					0.19				14.05				793					52							-14.62			0.28
	HHJB-5-20			9 509						350			255			1 215				5.34				2.08				9.92					53					2 868					2 921					0.18				4.77				1 008					15							-10.44			0.53
	HHJB-5-21			12 023						354			307			753				3.58				1.80				16.54					30					1 282					1 312					0.08				35.90				792					142							-13.48			1.45
	HHJB-5-22			12 434						145			266			1 393				1.67				1.32				21.87					15					1 938					1 953					0.07				13.93				759					67							-15.95			-0.29
	HHJB-5-23			12 723						128			283			1 072				2.19				1.55				26.76					12					1 435					1 447					0.08				65.54				739					179							-16.30			-0.14
	HHJB-5-24			13 572						155			566			1 206				3.78				2.65				32.27					13					1 682					1 696					0.09				29.82				727					147							-16.99			-0.54
	HHJB-5-25			10 020						476			298			556				3.90				1.63				13.60					47					1 683					1 730					0.18				31.15				767					104							-13.28			2.21
	HHJB-5-26			11 868						464			403			961				4.36				2.09				12.94					46					2 030					2 076					0.10				13.62				784					58							-13.58			1.52
	HHJB-5-27			12 416						172			291			1 066				2.22				1.47				23.06					15					1 401					1 416					0.07				32.24				751					159							-15.54			0.33
	HHJB-5-28			14 364						117			467			1 299				2.07				1.51				31.21					17					1 806					1 823					0.13				6.33				710					81							-17.15			-0.28
	HHJB-5-29			11 437						102			176			1 062				1.31				0.93				20.73					14					1 353					1 366					0.13				32.76				782					90							-15.14			0.01
	HHJB-5-30			11 353						208			238			976				2.06				1.37				17.10					26					1 635					1 661					0.21				9.35				806					47							-13.98			0.65

Fig.4 Box plots of TTi-in-zircon versus ΔFMQ (a) and Ce4+/Cezircon3+ versus $\lg f_{\mathrm{O}_{2}}$ (b) in zircons from the Pengshan pluton.G1—Biotite monzonitic granite; G2—Muscovite granite; G3—Granite porphyry.

Fig.5 Relationship between (∑REE+Y) concentrations and P in zircons from the Pengshan pluton, where I-type and S-type granites regions are based on literature [31], with hollow symbols indicating data points not included in trend line fitting

Fig.6 Plots of Eu/Eu* versus YbN/GdN(a),Hf versus Ti (b),Hf versus Eu/Eu* (c),Hf versus Ce/Ce* (d),Hf versus Ce4+/Cezircon3+ (e),and Ti versus Ce4+/Cezircon3+ (f) in zircons from the Pengshan pluton. Titanite fractionation curve in (a) from literature [32]. The three blue dashed lines represent estimated temperatures for a given Ti concentration calculated from the Ti-in-zircon thermometer in (b) and (f)[36].

Fig.7 Plots of Eu/Eu* versus Ce4+/Cezircon3+ (a) and TTi-in-zircon versus $\lg f_{\mathrm{O}_{2}}$ (b) from fitting areas of the Dexing copper deposit based on literature [33], the Shuikoushan Pb-Zn-Au-Ag deposit and Xihuashan tungsten deposit from literature [30], and the Shimenshi W-Cu-Mo deposit from literature [29] in (a); HM: hematite-magnetite, based on literature [66], NNO: nickel-nickel oxide, based on literature [67], FMQ: fayalite-magnetite-quartz, based on literature [66], MW: magnetite-hematite, based on literature [68].

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