Earth Science Frontiers ›› 2020, Vol. 27 ›› Issue (5): 88-98.DOI: 10.13745/j.esf.sf.2020.5.39

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Genetic mineralogy of jadeitite from Polar Urals, Russia

MENG Fancong1(), BAI Shengjin1,2, Alexander B. MAKEYEV3, Ksenia V. KULIKOVA4   

  1. 1. Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China
    2. School of Earth Sciences and Resources, China University of Geosciences(Beijing), Beijing 100083, China
    3. Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Moscow 119017, Russia
    4. Institute of Geology, Komi Science Center of Uralian Division, Russian Academy of Sciences, Syktyvkar 167982, Russia
  • Received:2020-04-15 Revised:2020-05-28 Online:2020-09-25 Published:2020-09-25

Abstract:

Subduction zones are major sites for mass circulation between the crust and mantle, while jadeitite is a recorder of the process. In this paper, we summarized the research advance of jadeitite from Polar Urals (Russia). Jadeitite occurs in serpentinized harzburgite as veins or lenses and is composed of jadeite and omphacite. Two generations can be identified based on the color and texture of jadeite. The oscillatory zoning and fluid inclusions (H2O+CH4 in composition) in jadeite indicated it is crystallized from fluids. Zircons from jadeitite are hydrothermal at origin, and are enriched in HREE, with LaN/YbN and LuN/GdN ratios ranging between 0.001-0.01, and 10-83, respectively. Cerium shows positive anomalies, with Ce/Ce* values ranging from 2.8 to 72, and δEu from 0.53 to 1.02. The 176Hf/177Hf ratios of zircons ranged from 0.282708 to 0.283017, with initial Hf isotope compositions ranging from +6 to +17. These characteristics resemble those of zircons from depleted mantle-derived magmas. The δ 18O isotope compositions of zircons ranged from 5.03‰ to 6.04‰ with an average of 5.45‰±0.11‰, similar to those of mantle rocks, suggesting that zircons were acquired from precursor igneous rocks and then transported and reworked by fluids from the subducting slab, or isotopic equilibration was reached between fluid and host harzburgite. Chondrite-normalized REE patterns of jadeitite displayed weak U-shaped distribution, with LaN/YbN ratios of 0.82-2.42, and very weak positive Eu anomalies (δEu=1.2-1.6). Jadeitite was enriched in Sr, Ba, Zr and Hf and depleted in Nb, relative to primitive mantle values. The initial Sr isotopic compositions of jadeitite ranged from 0.703400 to 0.703519 (t=368 Ma), and the initial Nd-isotope ratios (εNd =+0.77-+5.61) differed from those of ancient ocean water, oceanic sediments and eclogite, metagranite, and metasediments in the nearby Marun-Keu complex. Mineralogical and petrological evidences support jadeitite precipitation from material mainly produced by fluid interaction with mafic-ultramafic rocks in a subduction zone environment.

Key words: jadeitite, jadeite, zircon, geochemistry, fluids in subduction zone, Polar Urals, Russia

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