地学前缘 ›› 2022, Vol. 29 ›› Issue (3): 1-10.DOI: 10.13745/j.esf.sf.2022.1.47
收稿日期:
2022-01-10
修回日期:
2022-02-02
出版日期:
2022-05-25
发布日期:
2022-04-28
作者简介:
王焰新(1963—),男,教授,中国科学院院士,博士生导师,主要从事环境水文地质研究工作。E-mail: yx.wang@cug.edu.cn
基金资助:
WANG Yanxin(), LI Junxia, XIE Xianjun
Received:
2022-01-10
Revised:
2022-02-02
Online:
2022-05-25
Published:
2022-04-28
摘要:
我国是世界上已知面积最大的水源性高碘国家,碘的长期过量摄入对居民健康产生极大威胁。在不同的环境水文地质条件下,高碘地下水成因模式可概括为:埋藏-溶解型、压密-释放型和蒸发-浓缩型。基于对高碘地下水成因机理的认识,我们利用大数据模型预测了全国高碘地下水赋存情况,发现其高风险区(p>0.5)约占国土面积的19.8%,且涵盖了全部已知的高碘地下水分布区。开展地下水系统中有机碘形态定量表征、碘的水文地球化学行为微观机理识别和迁移活化过程定量模拟研究,将深化对高碘地下水成因与分布规律的认识,为供水水质安全和预防水源性高碘甲肿提供重要的科学依据。
中图分类号:
王焰新, 李俊霞, 谢先军. 高碘地下水成因与分布规律研究[J]. 地学前缘, 2022, 29(3): 1-10.
WANG Yanxin, LI Junxia, XIE Xianjun. Genesis and occurrence of high iodine groundwater[J]. Earth Science Frontiers, 2022, 29(3): 1-10.
图2 高碘地下水成因模式及华北平原、大同盆地典型案例(据文献[14]修改)
Fig.2 Genetic models of high iodine groundwater with examples of case studies of the North China Plain and Datong Basin. Modified after [14].
图3 全国高碘地下水分布预测图(碘浓度>100 μg/L)(据文献[61]修改)
Fig.3 Probability prediction maps of iodine concentrations (exceeding 100 μg/L) in groundwater in China. Modified after [61].
[1] | 韩云波, 唐当柱. 我国全民补碘的现况[J]. 职业与健康, 2020, 36(8): 1142-1145, 1149. |
[2] | 史亮晶, 申元英. 不同水碘地区居民碘营养状况和甲状腺相关疾病的研究进展[J]. 疾病预防控制通报, 2019, 34(2): 93-96. |
[3] |
PEARCE E N, ANDERSSON M, ZIMMERMANN M B. Global iodine nutrition: where do we stand in 2013?[J]. Thyroid, 2013, 23(5): 523-528.
DOI URL |
[4] |
VOUTCHKOVA D D, ERNSTSEN V, HANSEN B, et al. Assessment of spatial variation in drinking water iodine and its implications for dietary intake: a new conceptual model for Denmark[J]. Science of the Total Environment, 2014, 493: 432-444.
DOI URL |
[5] |
VOUTCHKOVA D D, ERNSTSEN V, KRISTIANSEN S M, et al. Iodine in major Danish aquifers[J]. Environmental Earth Sciences, 2017, 76(13): 1-16.
DOI URL |
[6] |
VOUTCHKOVA D D, KRISTIANSEN S M, HANSEN B, et al. Iodine concentrations in Danish groundwater: historical data assessment 1933-2011[J]. Environmental Geochemistry and Health, 2014, 36(6): 1151-1164.
DOI URL |
[7] |
ÁLVAREZ F, REICH M, PÉREZ-FODICH A, et al. Sources, sinks and long-term cycling of iodine in the hyperarid Atacama continental margin[J]. Geochimica et Cosmochimica Acta, 2015, 161: 50-70.
DOI URL |
[8] |
SMEDLEY P L, NICOLLI H B, MACDONALD D M J, et al. Hydrogeochemistry of arsenic and other inorganic constituents in groundwaters from La Pampa, Argentina[J]. Applied Geochemistry, 2002, 17(3): 259-284.
DOI URL |
[9] |
HAMILTON S M, GRASBY S E, MCINTOSH J C, et al. The effect of long-term regional pumping on hydrochemistry and dissolved gas content in an undeveloped shale-gas-bearing aquifer in southwestern Ontario, Canada[J]. Hydrogeology Journal, 2015, 23(4): 719-739.
DOI URL |
[10] |
TOGO Y S, TAKAHASHI Y, AMANO Y, et al. Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: implications for the origin and migration of iodine during basin evolution[J]. Geochimica et Cosmochimica Acta, 2016, 191: 165-186.
DOI URL |
[11] |
LV S M, XIE L J, XU D, et al. Effect of reducing iodine excess on children’s goiter prevalence in areas with high iodine in drinking water[J]. Endocrine, 2016, 52(2): 296-304.
DOI URL |
[12] | 孟凡刚, 申红梅, 刘守军, 等. 2015年全国水源性高碘地区监测结果分析[J]. 中华地方病学杂志, 2017, 36(9): 657-661. |
[13] |
TENG W P, SHAN Z Y, TENG X C, et al. Effect of iodine intake on thyroid diseases in China[J]. The New England Journal of Medicine, 2006, 354(26): 2783-2793.
DOI URL |
TENG W, SHAN Z, TENG X, et al. Effect of iodine intake on thyroid diseases in China[J]. New, 2006, 354(26): 2783-2793. | |
[14] |
WANG Y X, LI J X, MA T, et al. Gan. Genesis of geogenic contaminated groundwater: as, F and I[J]. Critical Reviews in Environmental Science and Technology, 2021, 51(24): 1-39.
DOI URL |
[15] |
LI J X, WANG Y X, XIE X J, et al. Effects of water-sediment interaction and irrigation practices on iodine enrichment in shallow groundwater[J]. Journal of Hydrology, 2016, 543: 293-304.
DOI URL |
[16] |
LI J X, WANG Y X, GUO W, et al. Iodine mobilization in groundwater system at Datong Basin, China: evidence from hydrochemistry and fluorescence characteristics[J]. Science of the Total Environment, 2014, 468/469: 738-745.
DOI URL |
[17] | LI J X, QIAN K, YANG Y J, et al. Iodine speciation and its potential influence on iodine enrichment in groundwater from North China plain[J]. Earth and Planetary Science, 2017, 17: 312-315. |
[18] |
DUAN L, WANG W K, SUN Y B, et al. Iodine in groundwater of the Guanzhong Basin, China: sources and hydrogeochemical controls on its distribution[J]. Environmental Earth Sciences, 2016, 75(11): 1-11.
DOI URL |
[19] |
TANG Q, XU Q, ZHANG F C, et al. Geochemistry of iodine-rich groundwater in the Taiyuan Basin of central Shanxi Province, North China[J]. Journal of Geochemical Exploration, 2013, 135: 117-123.
DOI URL |
[20] |
WANG Y X, ZHENG C M, MA R. Review: safe and sustainable groundwater supply in China[J]. Hydrogeology Journal, 2018, 26(5): 1301-1324.
DOI URL |
[21] |
FUGE R, JOHNSON C C. Iodine and human health, the role of environmental geochemistry and diet, a review[J]. Applied Geochemistry, 2015, 63: 282-302.
DOI URL |
[22] |
HOU X, HANSEN V, ALDAHAN A, et al. A review on speciation of iodine-129 in the environmental and biological samples[J]. Analytica Chimica Acta, 2009, 632(2): 181-196.
DOI URL |
[23] | YEAGER C M, AMACHI S, GRANDBOIS R, et al. Microbial transformation of iodine: from radioisotopes to iodine deficiency[J]. Advances in Applied Microbiology, 2017, 101: 83-136. |
[24] |
FUGE R, JOHNSON C C. The geochemistry of iodine: a review[J]. Environmental Geochemistry Health, 1986, 8(2): 31-54.
DOI URL |
[25] | GILFEDDER B, LAI S, PETRI M, et al. Iodine speciation in rain, snow and aerosols and possible transfer of organically bound iodine species from aerosol to droplet phases[J]. Atmospheric Chemistry and Physics, 2008, 8: 7977-8008. |
[26] | LI J, WANG Y, XIE X, et al. Hydrogeochemistry of high iodine groundwater: a case study at the Datong Basin, northern China[J]. Environmental Science Processes & Impacts, 2013, 15(4): 848-859. |
[27] | GILFEDDER B S, PETRI M, BIESTER H. Iodine speciation in rain and snow: implications for the atmospheric iodine sink[J]. Journal of Geophysical Research Atmospheres, 2007, 112(D7): D07301. |
[28] |
KODAMA S, TAKAHASHI Y, OKUMURA K, et al. Speciation of iodine in solid environmental samples by iodine K-edge XANES: application to soils and ferromanganese oxides[J]. Science of the Total Environment, 2006, 363(1/2/3): 275-284.
DOI URL |
[29] |
SHIMAMOTO Y S, TAKAHASHI Y, TERADA Y. Formation of organic iodine supplied as iodide in a soil-water system in Chiba, Japan[J]. Environmental Science & Technology, 2011, 45(6): 2086-2092.
DOI URL |
[30] |
KAPLAN D I, DENHAM M E, ZHANG S, et al. Radioiodine biogeochemistry and prevalence in groundwater[J]. Critical Reviews in Environmental Science and Technology, 2014, 44(20): 2287-2335.
DOI URL |
[31] |
TSUNOGAI S, SASE T. Formation of iodide-iodine in the ocean[J]. Deep Sea Research and Oceanographic Abstracts, 1969, 16(5): 489-496.
DOI URL |
[32] |
COUNCELL T B, LANDA E R, LOVLEY D R. Microbial reduction of iodate[J]. Water, Air, and Soil Pollution, 1997, 100(1/2): 99-106.
DOI URL |
[33] | LI J X, WANG Y T, XUE X B, et al. Mechanistic insights into iodine enrichment in groundwater during the transformation of iron minerals in aquifer sediments[J]. Science of the Total Environment, 2020, 745: 140922. |
[34] |
HOROWITZ A, SUFLITA J M, TIEDJE J M. Reductive dehalogenations of halobenzoates by anaerobic lake sediment microorganisms[J]. Applied and Environmental Microbiology, 1983, 45(5): 1459-1465.
DOI URL |
[35] |
OBA Y, FUTAGAMI T, AMACHI S. Enrichment of a microbial consortium capable of reductive deiodination of 2,4,6-triiodophenol[J]. Journal of Bioscience and Bioengineering, 2014, 117(3): 310-317.
DOI URL |
[36] |
AMACHI S, MURAMATSU Y, AKIYAMA Y, et al. Isolation of iodide-oxidizing bacteria from iodide-rich natural gas brines and seawaters[J]. Microbial Ecology, 2005, 49(4): 547-557.
DOI URL |
[37] |
WAKAI S, ITO K, IINO T, et al. Corrosion of iron by iodide-oxidizing bacteria isolated from brine in an iodine production facility[J]. Microbial Ecology, 2014, 68(3): 519-527.
DOI URL |
[38] |
ZHAO D, LIM C P, MIYANAGA K, et al. Iodine from bacterial iodide oxidization by Roseovarius spp. inhibits the growth of other bacteria[J]. Applied Microbiology and Biotechnology, 2013, 97(5): 2173-2182.
DOI URL |
[39] |
SEKI M, OIKAWA J, TAGUCHI T, et al. Laccase-catalyzed oxidation of iodide and formation of organically bound iodine in soils[J]. Environmental Science & Technology, 2013, 47(1): 390-397.
DOI URL |
[40] |
WATTS R J, FINN D D, CUTLER L M, et al. Enhanced stability of hydrogen peroxide in the presence of subsurface solids[J]. Journal of Contaminant Hydrology, 2007, 91(3/4): 312-326.
DOI URL |
[41] |
LI H P, YEAGER C M, BRINKMEYER R, et al. Bacterial production of organic acids enhances H2O2-dependent iodide oxidation[J]. Environmental Science & Technology, 2012, 46(9): 4837-4844.
DOI URL |
[42] |
FOX P M, DAVIS J A, LUTHER G W III. The kinetics of iodide oxidation by the manganese oxide mineral birnessite[J]. Geochimica et Cosmochimica Acta, 2009, 73(10): 2850-2861.
DOI URL |
[43] |
ALLARD S, VON GUNTEN U, SAHLI E, et al. Oxidation of iodide and iodine on birnessite (δ-MnO2) in the pH range 4-8[J]. Water Research, 2009, 43(14): 3417-3426.
DOI URL |
[44] |
BOWLEY H E, YOUNG S D, ANDER E L, et al. Iodine binding to humic acid[J]. Chemosphere, 2016, 157: 208-214.
DOI URL |
[45] |
SCHLEGEL M L, REILLER P, MERCIER-BION F, et al. Molecular environment of iodine in naturally iodinated humic substances: insight from X-ray absorption spectroscopy[J]. Geochimica et Cosmochimica Acta, 2006, 70(22): 5536-5551.
DOI URL |
[46] |
XU C, CHEN H M, SUGIYAMA Y, et al. Novel molecular-level evidence of iodine binding to natural organic matter from Fourier transform ion cyclotron resonance mass spectrometry[J]. Science of the Total Environment, 2013, 449: 244-252.
DOI URL |
[47] |
STEINBERG S M, SCHMETT G T, KIMBLE G, et al. Immobilization of fission iodine by reaction with insoluble natural organic matter[J]. Journal of Radioanalytical and Nuclear Chemistry, 2008, 277(1): 175-183.
DOI URL |
[48] |
STEINBERG S M, KIMBLE G M, SCHMETT G T, et al. Abiotic reaction of iodate with sphagnum peat and other natural organic matter[J]. Journal of Radioanalytical and Nuclear Chemistry, 2008, 277(1): 185-191.
DOI URL |
[49] | LUTHER G W, WU J, CULLEN J B. Redox chemistry of iodine in seawater: frontier molecular orbital theory considerations[M]// HUANG C P, O'MELIA C R, MORGAN J J. Aquatic chemistry:interfacial and interspecies processes. Washington DC: American Chemical Society, 1995: 135-155. |
[50] |
SHETAYA W H, YOUNG S D, WATTS M J, et al. Iodine dynamics in soils[J]. Geochimica et Cosmochimica Acta, 2012, 77: 457-473.
DOI URL |
[51] |
DAI J L, ZHANG M, HU Q H, et al. Adsorption and desorption of iodine by various Chinese soils: II. iodide and iodate[J]. Geoderma, 2009, 153(1/2): 130-135.
DOI URL |
[52] |
DAI J L, ZHANG M, ZHU Y G. Adsorption and desorption of iodine by various Chinese soils : I. iodate[J]. Environment International, 2004, 30(4): 525-530.
DOI URL |
[53] | LIN J X, DAI L P, WANG Y, et al. Quaternary marine transgressions in Eastern China[J]. Journal of Palaeogeography, 2012, 1(2): 105-125. |
[54] |
GONG H L, PAN Y, ZHENG L Q, et al. Long-term groundwater storage changes and land subsidence development in the North China Plain (1971-2015)[J]. Hydrogeology Journal, 2018, 26(5): 1417-1427.
DOI URL |
[55] | 石建省, 郭娇, 孙彦敏, 等. 京津冀德平原区深层水开采与地面沉降关系空间分析[J]. 地质论评, 2006, 52(6): 804-809. |
[56] | 朱菊艳, 郭海朋, 李文鹏, 等. 华北平原地面沉降与深层地下水开采关系[J]. 南水北调与水利科技, 2014, 12(3): 165-169. |
[57] |
XUE X, LI J, XIE X, et al. Impacts of sediment compaction on iodine enrichment in deep aquifers of the North China Plain[J]. Water Research, 2019, 159: 480-489.
DOI URL |
[58] | RODRíGUEZ-LADO L, SUN G F, BERG M, et al. Groundwater arsenic contamination throughout China[J]. Science, 2013, 341(6148): 866-868. |
[59] |
PODGORSKI J, BERG M. Global threat of arsenic in groundwater[J]. Science, 2020, 368(6493): 845-850.
DOI URL |
[60] |
CAO H L, XIE X J, WANG Y X, et al. Predicting geogenic groundwater fluoride contamination throughout China[J]. Journal of Environmental Sciences, 2022, 115: 140-148.
DOI URL |
[61] | LIU H X, LI J X, CAO H L, et al. Prediction modeling of geogenic iodine contaminated groundwater throughout China[J]. Journal of Environmental Management, 2022, 303: 114249. |
[62] |
ZHANG E Y, WANG Y Y, QIAN Y, et al. Iodine in groundwater of the North China Plain: spatial patterns and hydrogeochemical processes of enrichment[J]. Journal of Geochemical Exploration, 2013, 135: 40-53.
DOI URL |
[63] | 徐芬, 马腾, 石柳, 等. 内蒙古河套平原高碘地下水的水文地球化学特征[J]. 水文地质工程地质, 2012, 39(5): 8-15. |
[64] |
SHIMAMOTO Y S, TAKAHASHI Y. Superiority of K-edge XANES over LIII-edge XANES in the speciation of iodine in natural soils[J]. Analytical Sciences, 2008, 24(3): 405-409.
DOI URL |
[65] | HU Q H, MORAN J E, BLACKWOOD V. Geochemical cycling of iodine species in soils[M]// PREEDY V R, BURROW G N, WATSON R. Comprehensive handbook of iodine. Amsterdam: Elsevier, 2009: 93-105. |
[66] |
YANG Y J, PENG Y E, CHANG Q, et al. Selective identification of organic iodine compounds using liquid chromatography- high resolution mass spectrometry[J]. Analytical Chemistry, 2016, 88: 1275-1280.
DOI URL |
[67] |
SUFLITA J M, HOROWITZ A, SHELTON D R, et al. Dehalogenation: a novel pathway for the anaerobic biodegradation of haloaromatic compounds[J]. Science, 1982, 218(4577): 1115-1117.
DOI URL |
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