Earth Science Frontiers ›› 2022, Vol. 29 ›› Issue (1): 231-244.DOI: 10.13745/j.esf.sf.2021.8.1
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YANG Xiaoyong1(), SUN Chao1, CAO Jingya1, SHI Jianbin2
Received:
2020-11-05
Revised:
2021-05-31
Online:
2022-01-25
Published:
2022-02-22
CLC Number:
YANG Xiaoyong, SUN Chao, CAO Jingya, SHI Jianbin. High purity quartz: Research progress and perspective review[J]. Earth Science Frontiers, 2022, 29(1): 231-244.
Fig.2 BSE photos of submicron and nano inclusions. Adapted from [39]. (a) Submicron anatase (ilm), rutile (rt) and mica (m) inclusions in blue quartz from Llano rhyolite; (b) Rutile inclusions in the submicron and nanoscale metre grade (white punctate or needle-like) included in the Broken Hill blue quartz.
Fig.3 Fluid inclusions in quartz. a-d—Typical fluid inclusions in quartz from the Guposhan granite in Guangxi; e-g—Typical fluid inclusions in quartz from Zhangjinzhuang quartz sand, Northern Jiangsu Province. Photographic scales as shown in picture g.
Fig.4 Microphotographs and Roman spectra of representative mineral inclusions in quartz. a—Apatite inclusions contained in quartz from the Guposhan granite in Guangxi; b—Calcite inclusions in quartz from Zhangjinzhuang quartz sand, Northern Jiangsu; c—Microplagioclase inclusion in quartz from Zhangjinzhuang quartz sand, Northern Jiangsu province; d—Rutile inclusions in quartz from Zhangjinzhuang quartz sand, Northern Jiangsu Province.
Fig.5 Quality classification (according to total impurities) and price range of quartz, and minimum size of quartz deposit required for mining. Modified after [25].
Fig.7 Abundance range (grey bars) and average abundance (upper line) of elements in natural quartz, and the suggested maximum abundance of elements in high purity quartz (middle line) and in IOTA standard quartz (lower line). Modified after [27].
等级 | | | 脉石矿物种类 | 包裹体特征 | 晶格杂质 | |
---|---|---|---|---|---|---|
a | >99.9 | >5 | 0种 | 气液相 | 已破坏 | 纯净 |
b | 99.5~99.9 | 2~5 | 1种 | 占主要 | 稀疏分布 | 星染状类质同象 |
c | 99.0~99.5 | 0.2~2 | 2种 | 部分 | 密集分布 | 杂质出溶现象 |
d | <99.0 | <0.2 | >3种 | 固相矿物占主要部分 | 明显石英环带结构 |
Table 1 Assessment indexes for high purity quartz raw materials. Modified after [28].
等级 | | | 脉石矿物种类 | 包裹体特征 | 晶格杂质 | |
---|---|---|---|---|---|---|
a | >99.9 | >5 | 0种 | 气液相 | 已破坏 | 纯净 |
b | 99.5~99.9 | 2~5 | 1种 | 占主要 | 稀疏分布 | 星染状类质同象 |
c | 99.0~99.5 | 0.2~2 | 2种 | 部分 | 密集分布 | 杂质出溶现象 |
d | <99.0 | <0.2 | >3种 | 固相矿物占主要部分 | 明显石英环带结构 |
石英成因 | 石英类型 | 属性 | 首选应用领域 |
---|---|---|---|
岩浆/岩浆后成因 | 白岗岩石英 | 化学纯 | 高纯石英材料、光学、高温灯管、半导体、太阳能级Si |
伟晶岩 | 化学纯,晶体高度有序 | 光学和压电石英 | |
热液石英 | 石英合成、半导体、太阳能级Si、Si合金、玻璃 | ||
变质成因 | 石英岩 | SiO2含量可达>98% | 难熔材料、Si材料、Si合金 |
变质石英脉 | 化学纯 | 石英合成 | |
沉积成因 | 石英砂 | 化学纯 | 玻璃和铸造工业、方石英、石英粉、Si玻璃、SiC |
石英砾石 | 化学纯 | Si材料、Si合金、建筑工业 | |
沉积石英岩 | 化学纯,隐晶质SiO2 | 难熔材料 |
Table 2 Properties and preferred applications of quartz raw materials of different origins. Modified after [30].
石英成因 | 石英类型 | 属性 | 首选应用领域 |
---|---|---|---|
岩浆/岩浆后成因 | 白岗岩石英 | 化学纯 | 高纯石英材料、光学、高温灯管、半导体、太阳能级Si |
伟晶岩 | 化学纯,晶体高度有序 | 光学和压电石英 | |
热液石英 | 石英合成、半导体、太阳能级Si、Si合金、玻璃 | ||
变质成因 | 石英岩 | SiO2含量可达>98% | 难熔材料、Si材料、Si合金 |
变质石英脉 | 化学纯 | 石英合成 | |
沉积成因 | 石英砂 | 化学纯 | 玻璃和铸造工业、方石英、石英粉、Si玻璃、SiC |
石英砾石 | 化学纯 | Si材料、Si合金、建筑工业 | |
沉积石英岩 | 化学纯,隐晶质SiO2 | 难熔材料 |
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