Earth Science Frontiers ›› 2022, Vol. 29 ›› Issue (1): 14-28.DOI: 10.13745/j.esf.sf.2021.8.9
Previous Articles Next Articles
DENG Miao1(), WEI Chunwan1, XU Cheng1,2,*(
), SHI Aiguo1, LI Zuoqi1, FAN Chaoxi1, KUANG Guangxi1
Received:
2020-06-25
Revised:
2020-10-25
Online:
2022-01-25
Published:
2022-02-22
Contact:
XU Cheng
CLC Number:
DENG Miao, WEI Chunwan, XU Cheng, SHI Aiguo, LI Zuoqi, FAN Chaoxi, KUANG Guangxi. Rare earth mineralization in Bayan Obo super-large deposit: A review[J]. Earth Science Frontiers, 2022, 29(1): 14-28.
Fig.3 Chondrite-normalized REE patterns (a) and Y/Ho vs. La/Ho (b), (Ce/Nd)CN vs. ∑REE (c) and Y vs. Sr (d) diagrams for three types of apatite from H8 dolomite rock. Modified after [56].
[1] |
WENG Z H, JOWITT S M, MUDD G M, et al. A detailed assessment of global rare earth element resources: opportunities and challenges[J]. Economic Geology, 2015, 110(8):1925-1952.
DOI URL |
[2] |
SMITH M P, CAMPBELL L S, KYNICKY J. A review of the genesis of the world class Bayan Obo Fe-REE-Nb deposits, Inner Mongolia, China: multistage processes and outstanding questions[J]. Ore Geology Reviews, 2015, 64:459-476.
DOI URL |
[3] |
FAN H R, YANG K F, HU F F, et al. The giant Bayan Obo REE-Nb-Fe deposit, China: controversy and ore genesis[J]. Geoscience Frontiers, 2016, 7(3):335-344.
DOI URL |
[4] |
YANG X Y, LAI X D, PIRAJNO F, et al. Genesis of the Bayan Obo Fe-REE-Nb formation in Inner Mongolia, North China Craton: a perspective review[J]. Precambrian Research, 2017, 288:39-71.
DOI URL |
[5] | CHAO E C T, BACK J M, MINKIN J A, et al. The sedimentary carbonate-hosted giant Bayan Obo REE-Fe-Nb ore deposit of Inner Mongolia, China: a cornerstone example for giant polymetallic ore deposits of hydrothermal origin[R]. US Geological Survey Bulletin, 1997. |
[6] |
CAMPBELL L S. Discussion on Le Bas. et al. (1997) ‘Oxygen, carbon and strontium isotope study of the carbonatitic dolomite host of the Bayan Obo Fe-Nb-REE deposit, Inner Mongolia, China’, Mineralogical Magazine, 61, 531-41[J]. Mineralogical Magazine, 1999, 63(6):927-931.
DOI URL |
[7] | ARTZ Z J, FRIEHAUF K C, XIAO R. Comparison of banded ores in the main/east, west and south orebodies of the giant Bayan Obo REE district, Inner Mongolia, China[C]. Geological Society of America Annual Meeting in Salt Lake City, 2005. |
[8] |
LE BAS M J, KELLERE J, TAO K J, et al. Carbonatite dykes at Bayan Obo, Inner Mongolia, China[J]. Mineralogy and Petrology, 1992, 46(3):195-228.
DOI URL |
[9] |
LE BAS M J, SPIRO B, YANG X M. Oxygen, carbon and strontium isotope study of the carbonatitic dolomite host of the Bayan Obo Fe-Nb-REE deposit, Inner Mongolia, northern China[J]. Mineralogical Magazine, 1997, 61(407):531-541.
DOI URL |
[10] | 倪培, RANKIN A H, 周进. 白云鄂博地区碳酸岩墙及岩墙旁侧石英岩中的包裹体研究[J]. 岩石学报, 2003, 19(2):297-306. |
[11] |
YUAN Z X, BAI G, WU C Y, et al. Geological features and genesis of the Bayan Obo REE ore deposit, Inner Mongolia, China[J]. Applied Geochemistry, 1992, 7(5):429-442.
DOI URL |
[12] |
YANG X M, YANG X Y, ZHENG Y F, et al. A rare earth element-rich carbonatite dyke at Bayan Obo, Inner Mongolia, North China[J]. Mineralogy and Petrology, 2003, 78(1/2):93-110.
DOI URL |
[13] |
CAMPBELL L S, HENDERSON P. Apatite paragenesis in the Bayan Obo REE-Nb-Fe ore deposit, Inner Mongolia, China[J]. Lithos, 1997, 42(1/2):89-103.
DOI URL |
[14] |
CHAO E C T, BACK J M, MINKIN J A, et al. Host-rock controlled epigenetic, hydrothermal metasomatic origin of the Bayan Obo REE-Fe-Nb ore deposit, Inner Mongolia, PRC[J]. Applied Geochemistry, 1992, 7(5):443-458.
DOI URL |
[15] |
WANG J W, TATSUMOTO M, LI X B, et al. A precise 232Th-208Pb chronology of fine-grained monazite: age of the Bayan Obo REE-Fe-Nb ore deposit, China[J]. Geochimica et Cosmochimica Acta, 1994, 58(15):3155-3169.
DOI URL |
[16] |
YANG X Y, SUN W D, ZHANG Y X, et al. Geochemical constraints on the genesis of the Bayan Obo Fe-Nb-REE deposit in Inner Mongolia, China[J]. Geochimica et Cosmochimica Acta, 2009, 73(5):1417-1435.
DOI URL |
[17] | 王中刚, 李绍柄, 苏贤泽. 沉积变质-热液交代型稀土、 铁矿床的成因特征[J]. 地球化学, 1973, 2(1):5-11. |
[18] | 周煜双. 试论白云鄂博铁矿的沉积: 热液交代变质成因[J]. 内蒙古科技与经济, 2006(5):58-59. |
[19] | 袁忠信, 白鸽, 张宗清. 白云鄂博矿床赋矿岩石的自交代现象及其意义[J]. 岩石矿物学杂志, 2004, 23(1):19-25. |
[20] | 张宗清, 袁忠信, 唐索寒. 白云鄂博矿床年龄和地球化学[M]. 北京: 地质出版社, 2003. |
[21] | 秦朝建, 裘愉卓, 周国富, 等. 白云鄂博矿床碳酸岩墙/脉和赋矿白云岩中流体包裹体研究[J]. 岩石学报, 2007, 23(1):161-168. |
[22] |
LE BAS M J, YANG X M, TAYLOR R N, et al. New evidence from a calcite-dolomite carbonatite dyke for the magmatic origin of the massive Bayan Obo ore-bearing dolomite marble, Inner Mongolia, China[J]. Mineralogy and Petrology, 2007, 90(3/4):223-248.
DOI URL |
[23] |
YANG K F, FAN H R, SANTOSH M, et al. Mesoproterozoic carbonatitic magmatism in the Bayan Obo deposit, Inner Mongolia, North China: constraints for the mechanism of super accumulation of rare earth elements[J]. Ore Geology Reviews, 2011, 40(1):122-131.
DOI URL |
[24] |
DREW L J, MENG Q R, SUN W J. The Bayan Obo iron-rare-earth-niobium deposits, Inner Mongolia, China[J]. Lithos, 1990, 26(1/2):43-65.
DOI URL |
[25] | 周振玲, 李功元, 宋同云, 等. 内蒙古白云鄂博白云石碳酸岩的地质特征及其成因探讨[J]. 地质论评, 1980, 26(1):35-42, 92. |
[26] |
FAN H R, XIE Y H, WANG Y K, et al. REE daughter minerals trapped in fluids inclusions in the giant Bayan Obo REE-Nb-Fe deposit, Inner Mongolia, China[J]. International Geology Review, 2004, 46:638-645.
DOI URL |
[27] | 刘铁庚. 碳酸盐岩石成因类型的判别分析和白云鄂博“白云岩”的成因讨论[J]. 沉积学报, 1990, 8(3):93-102. |
[28] | 张培善, 杨克捷, 杨主明, 等. 中国稀土矿物学[M]. 北京: 科学出版社, 1998. |
[29] | 杨学明, 杨晓勇. 白云鄂博REE-Nb-Fe矿床成因的氧、 碳和锶同位素及微量元素地球化学证据[J]. 地球物理学报, 1998, 41(增刊1):216-227. |
[30] | 杨学明, 杨晓勇, 陈天虎, 等. 白云鄂博富稀土碳酸岩的地球化学特征[J]. 中国稀土学报, 1999, 17(4):289-295. |
[31] | 高计元, 王一先, 裘愉卓, 等. 白云鄂博矿床含矿白云岩的成因探讨[J]. 沉积学报, 1999, 17(增刊1):675-680. |
[32] | 涂光炽. 试论非常规超大型矿床物质组成、 地质背景、 形成机制的某些独特性: 初谈非常规超大型矿床[J]. 中国科学: D辑, 1998, 28(增刊2):1-6. |
[33] | 侯宗林. 白云鄂博铁-铌-稀土矿床基本地质特征、 成矿作用和成矿模式[J]. 地质与勘探, 1989, 25(7):1-5, 22. |
[34] | 章雨旭, 彭阳, 杨晓勇. 白云鄂博矿床赋矿微晶丘的论证[J]. 矿床地质, 1998, 17(增刊):691-696. |
[35] | 章雨旭, 吕洪波, 张绮玲, 等. 微晶丘成因新认识[J]. 地球科学进展, 2005, 20(6):693-700. |
[36] | 乔秀夫, 高林志, 彭阳, 等. 内蒙古腮林忽洞群综合地层和白云鄂博矿床赋矿微晶丘[J]. 地质学报, 1997, 71(3):202-211, 290. |
[37] | 姚德, 张丽洁, WILTSHIRE J, 等. 中国内蒙古白云鄂博Fe-Nb-REE矿床地质特征与陨石撞击成因[J]. 海洋地质与第四纪地质, 1998, 18(4):87-96. |
[38] | 中国科学院地球化学研究. 白云鄂博矿床地球化学[M]. 北京: 科学出版社, 1988: 437-468. |
[39] | 任英忱, 张英臣, 张宗清. 白云鄂博稀土超大型矿床的成矿时代及其主要地质热事件[J]. 地球学报, 1994, 21(1/2):95-101. |
[40] | 曹荣龙, 朱寿华, 王俊文. 白云鄂博铁-稀土矿床的物质来源和成因理论问题[J]. 中国科学: B辑, 1994, 24(12):1298-1307. |
[41] |
LING M X, LIU Y L, WILLIAMS I S, et al. Formation of the world’s largest REE deposit through protracted fluxing of carbonatite by subduction-derived fluids[J]. Scientific Reports, 2013, 3:1776.
DOI URL |
[42] | 刘玉龙, 陈江峰, 李惠民, 等. 白云鄂博矿床白云石型矿石中独居石单颗粒U-Th-Pb-Sm-Nd定年[J]. 岩石学报, 2005, 21(3):881-888. |
[43] | 范宏瑞, 胡芳芳, 陈福坤, 等. 白云鄂博超大型REE-Nb-Fe矿区碳酸岩墙的侵位年龄: 兼答Le Bas博士的质疑[J]. 岩石学报, 2006, 22(2):519-520. |
[44] | 章雨旭, 江少卿, 张绮玲, 等. 论内蒙古白云鄂博群和白云鄂博超大型稀土-铌-铁矿床成矿的年代[J]. 中国地质, 2008, 35(6):1129-1137. |
[45] | CAMPBELL L S, COMPSTON W, SIRCOMBE K N, et al. Zircon from the East Orebody of the Bayan Obo Fe-Nb-REE deposit, China, and SHRIMP ages for carbonatite-related magmatism and REE mineralization events[J]. Contributions to Mineralogy and Petrology, 2014, 168(2):1-23. |
[46] |
ZHU X K, SUN J, PAN C X. Sm-Nd isotopic constraints on rare-earth mineralization in the Bayan Obo ore deposit, Inner Mongolia, China[J]. Ore Geology Reviews, 2015, 64:543-553.
DOI URL |
[47] |
SONG W L, XU C, SMITH M P, et al. Genesis of the world’s largest rare earth element deposit, Bayan Obo, China: protracted mineralization evolution over ~1 b.y.[J]. Geology, 2018, 46(4):323-326.
DOI URL |
[48] |
YANG K F, FAN H R, PIRAJNO F, et al. The Bayan Obo (China) giant REE accumulation conundrum elucidated by intense magmatic differentiation of carbonatite[J]. Geology, 2019, 47(12):1198-1202.
DOI URL |
[49] |
CHEN W, LIU H Y, LU J, et al. The formation of the ore-bearing dolomite marble from the giant Bayan Obo REE-Nb-Fe deposit, Inner Mongolia: insights from micron-scale geochemical data[J]. Mineralium Deposita, 2020, 55(1):131-146.
DOI URL |
[50] | 王楫, 李双庆, 王保良, 等. 狼山:白云鄂博裂谷系[M]. 北京: 北京大学出版社, 1992. |
[51] | 白鸽, 袁忠信. 白云鄂博矿床地质特征和成因论证[M]. 北京: 地质出版社, 1996. |
[52] | 白鸽, 袁忠信. 白云鄂博矿床成因分析[G]//中国地质科学院矿床地质研究所文集. 北京: 中国地质学会, 1983: 5-21. |
[53] |
LAI X D, YANG X Y, SANTOSH M, et al. New data of the Bayan Obo Fe-REE-Nb deposit, Inner Mongolia: implications for ore genesis[J]. Precambrian Research, 2015, 263:108-122.
DOI URL |
[54] |
SMITH M P, HENDERSON P, CAMPBELL L S. Fractionation of the REE during hydrothermal processes: constraints from the Bayan Obo Fe-REE-Nb deposit, Inner Mongolia, China[J]. Geochimica et Cosmochimica Acta, 2000, 64(18):3141-3160.
DOI URL |
[55] |
LIU S, FAN H R, YANG K F, et al. Fenitization in the giant Bayan Obo REE-Nb-Fe deposit: implication for REE mineralization[J]. Ore Geology Reviews, 2018, 94:290-309.
DOI URL |
[56] |
DENG M, XU C, SONG W L, et al. REE mineralization in the Bayan Obo deposit, China: evidence from mineral paragenesis[J]. Ore Geology Reviews, 2017, 91:100-109.
DOI URL |
[57] |
WILLIAMS-JONES A E, MIGDISOV A A, SAMSON I M. Hydrothermal mobilisation of the rare earth elements: a tale of “ceria” and “yttria”[J]. Elements, 2012, 8(5):355-360.
DOI URL |
[58] |
CHAKHMOURADIAN A R, WALL F. Rare earth elements: Minerals, mines, magnets (and more)[J]. Elements, 2012, 8(5):333-340.
DOI URL |
[59] |
XIE Y L, LI Y X, HOU Z Q, et al. A model for carbonatite hosted REE mineralisation: the Mianning-Dechang REE belt, Western Sichuan Province, China[J]. Ore Geology Reviews, 2015, 70:595-612.
DOI URL |
[60] |
REN Y S, YANG X Y, WANG S S, et al. Mineralogical and geochemical study of apatite and dolomite from the Bayan Obo giant Fe-REE-Nb deposit in Inner Mongolia: new evidences for genesis[J]. Ore Geology Reviews, 2019, 109:381-406.
DOI URL |
[61] |
ZHANG S H, ZHAO Y, LIU Y S. A precise zircon Th-Pb age of carbonatite sills from the world’s largest Bayan Obo deposit: implications for timing and genesis of REE-Nb mineralization[J]. Precambrian Research, 2017, 291:202-219.
DOI URL |
[62] | 张宗清, 唐索寒, 王进辉, 等. 白云鄂博稀土矿床形成年龄的新数据[J]. 地球学报, 1994, 15(增刊1):85-94. |
[63] |
HU F F, FAN H R, LIU S, et al. Samarium-neodymium and rubidium-strontium isotopic dating of veined REE mineralization for the Bayan Obo REE-Nb-Fe deposit, Northern China[J]. Resource Geology, 2009, 59(4):407-414.
DOI URL |
[64] |
LIU Y L, YANG G, CHEN J F, et al. Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit[J]. Chinese Science Bulletin, 2004, 49(24):2627-2631.
DOI URL |
[65] | 杨奎锋, 范宏瑞, 胡芳芳, 等. 白云鄂博巨型REE-Nb-Fe矿区夕卡岩化时代: 单颗粒金云母Rb-Sr法定年[J]. 岩石学报, 2007, 23(5):1018-1022. |
[66] |
SUN J, ZHU X K, CHEN Y L, et al. Iron isotopic constraints on the genesis of Bayan Obo ore deposit, Inner Mongolia, China[J]. Precambrian Research, 2013, 235:88-106.
DOI URL |
[67] | 孙剑, 房楠, 李世珍, 等. 白云鄂博矿床成因的Mg同位素制约[J]. 岩石学报, 2012, 28(9):2890-2902. |
[68] |
TAYLOR H P, FRECHEN J, DEGENS E T. Oxygen and carbon isotope studies of carbonatites from the Laacher See District, West Germany and the Alnö District, Sweden[J]. Geochimica et Cosmochimica Acta, 1967, 31(3):407-430.
DOI URL |
[69] |
VEIZER J, CLAYTON R N, HINTON R W. Geochemistry of Precambrian carbonates: IV. Early Paleoproterozoic (2.25±0.25 Ga) seawater[J]. Geochimica et Cosmochimica Acta, 1992, 56(3):875-885.
DOI URL |
[70] |
TENG F Z, LI W Y, KE S, et al. Magnesium isotopic composition of the Earth and chondrites[J]. Geochimica et Cosmochimica Acta, 2010, 74(14):4150-4166.
DOI URL |
[71] |
HUANG K J, SHEN B, LANG X G, et al. Magnesium isotopic compositions of the Mesoproterozoic dolostones: implications for Mg isotopic systematics of marine carbonates[J]. Geochimica et Cosmochimica Acta, 2015, 164:333-351.
DOI URL |
[72] |
LAI X D, YANG X Y. Geochemical characteristics of the Bayan Obo giant REE-Nb-Fe deposit: constraints on its genesis[J]. Journal of South American Earth Sciences, 2013, 41:99-112.
DOI URL |
[73] |
ZINDLER A, HART S. Chemical geodynamics[J]. Annual Review of Earth and Planetary Sciences, 1986, 14(1):493-571.
DOI URL |
[74] |
BELL K, TILTON G R. Nd, Pb and Sr isotopic compositions of East African carbonatites: evidence for mantle mixing and plume inhomogeneity[J]. Journal of Petrology, 2001, 42(10):1927-1945.
DOI URL |
[75] | 李龙, 郑永飞, 周建波. 中国大陆地壳铅同位素演化的动力学模型[J]. 岩石学报, 2001, 17(1):61-68. |
[76] |
SMITH M P. Metasomatic silicate chemistry at the Bayan Obo Fe-REE-Nb deposit, Inner Mongolia, China: contrasting chemistry and evolution of fenitising and mineralising fluids[J]. Lithos, 2007, 93(1/2):126-148.
DOI URL |
[77] |
ANDRADE F R D, MÖLLER P, LÜDERS V, et al. Hydrothermal rare earth elements mineralization in the Barra do Itapirapuã carbonatite, southern Brazil: behaviour of selected trace elements and stable isotopes (C, O)[J]. Chemical Geology, 1999, 155(1-2):91-113.
DOI URL |
[78] | 谢玉玲, 曲云伟, 杨占峰, 等. 白云鄂博铁、 铌、 稀土矿床: 研究进展、 存在问题和新认识[J]. 矿床地质, 2019, 38(5):983-1003. |
[79] |
ZHANG S H, ZHAO Y, YE H, et al. Origin and evolution of the Bainaimiao arc belt: implications for crustal growth in the southern Central Asian orogenic belt[J]. Geological Society of America Bulletin, 2014, 126(9/10):1275-1300.
DOI URL |
[80] | 范宏瑞, 胡芳芳, 杨奎锋, 等. 内蒙古白云鄂博地区晚古生代闪长质-花岗质岩石年代学框架及其地质意义[J]. 岩石学报, 2009, 25(11):2933-2938. |
[81] |
LING M X, ZHANG H, LI H, et al. The Permian-Triassic granitoids in Bayan Obo, North China Craton: a geochemical and geochronological study[J]. Lithos, 2014, 190/191:430-439.
DOI URL |
[82] | EINAUDI M T, MEINERT L D, NEWBERRY R J. Skarm deposit[M]//SKINNER B J. Economic Geology Seventy-fifth Anniversary Volume(1905-1980). EI Paso: The Economic Geology Publishing Company, 1981: 317-391. |
[83] | MEINERT L D. Application of skarn deposit zonation models to mineral exploration[J]. Exploration and Mining Geology, 1997, 6(2):185-208. |
[84] |
LIU S, FAN H R, GROVES D I, et al. Multiphase carbonatite-related magmatic and metasomatic processes in the genesis of the ore-hosting dolomite in the giant Bayan Obo REE-Nb-Fe deposit[J]. Lithos, 2020, 354/355:105359.
DOI URL |
[1] | XU Zhihao, YAN Guoying, YANG Zongfeng, WANG Zhaojing, SHEN Junfeng, ZHANG Mengmeng, LI Peipei, XU Kexin. Typomorphic characteristics of magnetite and prediction of deep iron-rich orebody in the Bayan Obo ore deposit [J]. Earth Science Frontiers, 2023, 30(2): 426-439. |
[2] | CHEN Shizhong, ZHOU Yan, XING Guangfu, XU Mincheng, FAN Feipeng, XI Wanwan, ZHU Xiaoting, GUO Weimin. Relationship between the large scale fenitization and REE mineralization on the border between Zhejiang and Fujian provinces: A review of recent research progress [J]. Earth Science Frontiers, 2023, 30(2): 415-425. |
[3] | SHEN Junfeng, YAN Guoying, ZHANG Mengmeng, WANG Zhaojing, XU Kexin, MENG Wenxiang. REE enrichment process in the Bayan Obo Fe-REE-Nb deposit: Genetic and mineralogical evidence [J]. Earth Science Frontiers, 2023, 30(2): 370-383. |
[4] | WEN Ligang,ZENG Pusheng,ZHAN Xiuchun,FAN Chenzi,SUN Dongyang,WANG Guang,YUAN Jihai,FEI Xiaojie. The Yinachang deposit in central Yunnan Province, Southwest China: A “Bayan Obo-type” Fe-Cu-REE deposit. [J]. Earth Science Frontiers, 2018, 25(6): 308-329. |
[5] | . Geological characteristics and ore genesis of the Chachaxiangka U-Th-Nb-REE deposit in the northeastern Qaidam Basin: a new mineralization type related to albitite. [J]. Earth Science Frontiers, 2018, 25(5): 222-237. |
[6] | LI Tongfei,XIA Qinglin,WANG Xinqing,LIU Yue,CHANG Liheng,LENG Shuai. Metallogenic geological characteristics and mineral resource potential analysis of rare earth element resources in China. [J]. Earth Science Frontiers, 2018, 25(3): 95-106. |
[7] | CHAO Hui-Xia, SU Sheng-Rui, YANG Xin-Ke. Research on the geological characteristics of the Miaoya REE deposit, Hubei Province. [J]. Earth Science Frontiers, 2016, 23(4): 102-108. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||