地学前缘 ›› 2015, Vol. 22 ›› Issue (3): 205-214.DOI: 10.13745/j.esf.2015.03.018

• 中国中部盆地构造演化与油气 • 上一篇    下一篇

鄂尔多斯盆地北部延安组白色砂岩形成的稳定同位素示踪及其地质意义

吴柏林, 魏安军, 刘池洋, 宋子升, 胡亮, 王丹, 寸小妮, 孙莉, 罗晶晶   

  1. 西北大学 大陆动力学国家重点实验室; 西北大学 地质学系, 陕西 西安 710069
  • 收稿日期:2014-06-09 修回日期:2014-08-05 出版日期:2015-05-15 发布日期:2015-05-15
  • 作者简介:吴柏林(1967—),男,博士,教授,博士生导师,研究方向为矿产普查与勘探。E-mail:wbailin@126.com
  • 基金资助:

    国家自然科学基金项目(41173060);国家重点基础研究发展计划“973”项目(2015CB453000);中国地质调查局项目(12120114009201,1212011220799);西北大学大陆动力学国家重点实验室科学技术部专项

Stable isotope tracing on the formation of white sandstone in Yanan Group, northern Ordos Basin, and its geological significance.

 TUN  Bai-Lin, WEI  An-Jun, LIU  Che-Xiang, SONG  Zi-Sheng, HU  Liang, WANG  Dan, CUN  Xiao-Ni, SUN  Chi, LUO  Jing-Jing   

  • Received:2014-06-09 Revised:2014-08-05 Online:2015-05-15 Published:2015-05-15

摘要:

鄂尔多斯盆地东北部延安组顶部存在大规模的白色砂岩,形成当地的大型高岭土矿床。该白色砂岩与东胜—杭锦旗一带发现的大型砂岩铀矿含矿层位直罗组相邻相近;研究表明白色化与铀矿的富集保存、控矿砂岩的绿色蚀变、碳酸盐化等空间关系密切,成因相似,均与盆地中部上古生界天然气向北运移耗散所导致的低温气水热液流体中烃类还原的流岩作用有关。文中重点从稳定同位素示踪白色砂岩形成的地球化学成因机制和过程,同时也指示了本区存在天然气耗散的动力学背景。高岭石氢氧同位素揭示白色化砂岩形成的高岭土矿床成因以低温热液作用为主,与东胜铀矿形成的低温热液作用为同一性质及事件;高岭石硅同位素与铀矿石中铀矿物铀石的硅同位素数据相近,而与成岩作用黏土的硅同位素特征相去甚远,进一步证明了白色砂岩与铀矿化是在同一低温热液事件作用下的产物。碳氧同位素说明白色砂岩形成的流体与有机质来源有关,结合东胜砂岩铀矿有机地球化学及本区天然气耗散地质事件的背景,认为该有机质来源于向北耗散的上古生界天然气。方解石包裹体氢氧同位素特征表明,流体中水的性质和来源为大气降水。系统总结和综合以上认识认为,本区白色砂岩的形成过程是,中部上古生界低温天然气向北运移耗散至浅部延安组—直罗组,与地下水一起构成低温“天然气水”混合热液,该低温热液的烃类还原作用同时导致了本区延安组顶部白色砂岩的形成以及直罗组下部东胜铀矿的富集保存、砂岩的绿色化和碳酸盐化等蚀变现象,从而形成本区东胜超大型铀矿及大型高岭土矿床和相关的烃类还原蚀变现象,构成现今多种能源及相关资源同盆共存、共荣的局面。

关键词: 白色砂岩, 稳定同位素, 示踪, 天然气耗散, 烃类还原, 砂岩铀矿, 低温热液

Abstract:

There are a mass of white sandstone in the top of Yanan Formation in northeastern Ordos Basin which formed the local large kaolin deposit, and its bearing horizons were similar and adjacent to Zhiluo Formation in DongshengHangjinqi Area. Studies have shown that the whitening was closely related to uranium enrichment and reservation, green alteration of the orecontrolling sandstone, carbonation and so forth. These phenomena were related to the flowrock effect which was caused by the upper Paleozoic natural gas migrating northward. This paper mainly talks about the formation process and geochemical genesis mechanism of the white sandstone through the stable isotope tracing. The paper also indicates that there existed a natural gas dissipation dynamics background in this area, and that the hydrogen and oxygen isotopes of the kaolinite revealed that the formation of kaolin deposit was based on low temperature hydrothermal event, with the same properties and events as Dongsheng uranium deposit. The silicon isotopes of the kaolinite were similar to the uranium silicon isotope data, but far different from the clay silicon isotope data, which further evidenced that the white sandstone and uranium mineralization were the products of the same low temperature hydrothermal events. Carbon and oxygen isotopes showed that the white sandstone formation fluid was associated with organic matter source. Combined with organic geochemistry of Dongsheng sandstone type of uranium deposits and local geological background events of natural gas dissipation, it is suggested that the organic matters came from the natural gas dissipation northward in the Upper Palaeozoic. The characteristics of hydrogen and oxygen isotope of calcite inclusion indicated that the water of the fluid was atmospheric precipitation. In summary, the forming processes of white sandstone in the study area were as follows: the microthermal natural gas in the Upper Palaeozoic migrated from the central part northward to the shallow YananZhiluo Formations; this microthermal natural gas along with the underground water made up the microthermal mixed hydrothermal “natural gaswater”; the reduction effect of hydrocarbons in the microthermal liquid also led to the alterations, causing the formation of white sandstone in the top of Yanan Group and the Dongsheng uranium deposit in Zhiluo Formation, causing the greenization of the sandstone, the carbonatization and so on. These alterations formed the Dongsheng super large uranium deposit, super large kaolin deposit and hydrocarbon alteration. These all brought about the situation that multienergy sources and ores coexisted in the same basin with common prosperity.

Key words: white sandstone, stable isotope, tracing, the natural gas dissipation, reduction of the hydrocarbons, sandstone type uranium deposit, epithermal

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