江汉盆地大型富锂卤水矿床成因与资源勘查进展:综述

doi:10.13745/j.esf.sf.2021.8.11

地学前缘 ›› 2022, Vol. 29 ›› Issue (1): 107-123.DOI: 10.13745/j.esf.sf.2021.8.11

• 稀有金属矿床成矿过程及勘查进展 • 上一篇下一篇

江汉盆地大型富锂卤水矿床成因与资源勘查进展:综述

余小灿¹(), 刘成林¹^,²^,^*(), 王春连¹, 徐海明¹, 赵艳军¹, 黄华³, 李瑞琴¹

1.中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室, 北京 100037
2.中国地质大学(武汉), 湖北武汉 430074
3.中国石油化工股份有限公司江汉油田分公司, 湖北武汉430223

收稿日期:2020-06-02 修回日期:2020-12-18 出版日期:2022-01-25 发布日期:2022-02-22
通讯作者: 刘成林
作者简介:余小灿(1988—),男,博士后,主要从事地下卤水型钾、锂矿床与地球化学研究。E-mail: xiaocany1988@163.com
基金资助:
中央级公益性科研院所基本科研业务费项目(YYWF201607);中央级公益性科研院所基本科研业务费项目(KY1603);中央级公益性科研院所基本科研业务费项目(K1415);国家自然科学基金项目(42002106);国家重点基础研究发展计划“973”项目(2011CB403007)

Genesis of lithium brine deposits in the Jianghan Basin and progress in resource exploration: A review

YU Xiaocan¹(), LIU Chenglin¹^,²^,^*(), WANG Chunlian¹, XU Haiming¹, ZHAO Yanjun¹, HUANG Hua³, LI Ruiqin¹

1. MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China
2. China University of Geosciences (Wuhan), Wuhan 430074, China
3. SINOPEC Jianghan Oilfield Company, Wuhan 430223, China

Received:2020-06-02 Revised:2020-12-18 Online:2022-01-25 Published:2022-02-22
Contact: LIU Chenglin

摘要/Abstract

摘要：

古近纪时期,华南江汉盆地的潜江凹陷和江陵凹陷发育盐湖,沉积了巨厚的蒸发岩,并形成和储藏了富锂、钾、铷、铯、溴、碘等元素的卤水资源,这些元素含量达到工业品位或综合利用品位;富锂卤水属于深层地下卤水型锂矿资源,镁锂比值低,是非常优质的锂资源。本文总结了江汉盆地大地构造特征、火成岩及古气候背景,论述了古盐湖沉积岩相特征、富锂卤水水化学、分布及储层特征、卤水中锂的来源与富集机理、卤水型锂矿成矿模式以及富锂卤水勘查与开采技术进展,提出了卤水开发利用中存在的问题和解决途径。江汉盆地富锂卤水成因包括:古盐湖锂可能主要来自高温水岩反应产生的富锂热液流体的补给;在干旱的气候下,古湖水不断蒸发浓缩,导致卤水中锂浓缩富集;在盐湖演化末期,逐渐埋藏的盐类晶间富锂卤水被转移至裂隙、砂岩及玄武岩储层中储集;在较高的地热背景值下,埋藏卤水与储层岩石可能发生水岩反应,进一步促进了卤水中锂的富集。江汉盆地深层卤水初步勘查显示,氯化锂资源量已达到大型工业规模,展示了巨大的资源潜力。此外,卤水锂开采技术已基本形成,建议进一步加强富锂卤水的绿色开发技术研究,制定相关勘查开发规范。

关键词: 富锂卤水, 古近纪, 古盐湖, 卤水锂提取技术, 江汉盆地

Abstract:

During the Paleogene, saline lakes developed in the Qianjiang and Jiangling Sags, Jianghan Basin, where thick evaporites later deposited to produce rich brine resources that contain industrial or general commercial grade Li, K, Rb, Cs, Br, and I elements. The Li-rich brines, belonging to deep underground lithium brine deposits, are a high-quality lithium resource, with low Mg/Li ratios. In this paper, the geotectonic feature, igneous rock and paleoclimatic background associated with the Jianghan Basin are summarized; the sedimentary facies of ancient salt lakes, the hydrochemistry, distribution and characteristics of lithium brine reservoirs, also the source and enrichment mechanism of lithium in brines, the formation model of lithium brine deposits, and progress in lithium brine exploration and mining technology are introduced; and the problems and solutions in the development and utilization of brines are discussed. The genesis of lithium brines in the Jianghan Basin is as follows: lithium, likely, comes mainly from the replenishment of Li-rich hydrothermal fluids produced by water-rock interaction at high temperature. In an arid climate, saline lake continues to evaporate and concentrate, leading to lithium enrichment in brines. At the end of salt lake evolution, the gradually buried intercrystalline Li-rich brines in saline minerals migrated to fractures, sandstone and basalt reservoirs for storage, where brine-reservoir rock interaction in geothermal environment further promotes lithium enrichment. Preliminary surveys of deep brines in the Jianghan Basin predicted large industrial scale LiCl resources in the basin with great resources potential. As lithium brine mining technology is maturing, researches on green technology development should be strengthened, and relevant exploration and development standards should be established.

Key words: lithium-rich brine, Paleogene, ancient salt lake, lithium brine extraction technology, Jianghan Basin

中图分类号:

余小灿, 刘成林, 王春连, 徐海明, 赵艳军, 黄华, 李瑞琴. 江汉盆地大型富锂卤水矿床成因与资源勘查进展:综述[J]. 地学前缘, 2022, 29(1): 107-123.

YU Xiaocan, LIU Chenglin, WANG Chunlian, XU Haiming, ZHAO Yanjun, HUANG Hua, LI Ruiqin. Genesis of lithium brine deposits in the Jianghan Basin and progress in resource exploration: A review[J]. Earth Science Frontiers, 2022, 29(1): 107-123.

图/表 12

图1 江汉盆地地质简图及周缘构造单元 (据文献[26]修改) T3—上三叠统沉积物;J2—中侏罗统沉积物;K1—下白垩统沉积物;K2—上白垩统沉积物; E—古近系沉积物;F1—信阳—舒城断裂(商丹缝合带在大别造山带北缘的延伸部分);F2—襄广断裂(勉略缝合带在大别山南缘的延伸部分);NDC—北大别山核部变质杂岩体;UHP—超高压变质带;HP—高压变质带。

Fig.1 Simplified geological map of the Jianghan Basin showing the surrounding tectonic units. Modified after [26].

图2 江汉盆地沉积充填及地层柱状图 (据文献[30]修改)

Fig.2 Basin filling evolution and stratigraphic column of the Jianghan Basin. Modified after [30].

图3 江汉盆地火山岩分布图 (据文献[54]修改)

Fig.3 Distribution of volcanic rocks in the Jianghan Basin. Modified after [54].

表1 江陵凹陷深层富锂卤水化学组成

Table 1 Chemical compositions of deep Li rich brines from the Jiangling Depression

图4 江汉盆地富锂卤水Li和K含量与矿化度相关性

Fig.4 Relationship between Li (a, c) or K (b, d) content and TDS in Li-rich brines from the Jianghan Basin

表2 潜江凹陷深层富锂卤水化学组成

Table 2 Chemical composition of deep Li- rich brines in Qianjiang Depression

图5 江汉盆地古近纪沉积岩相图 (据文献[57,61-62]修改) a—江陵凹陷沙市组下段;b—江陵凹陷沙市组上段;c—江陵凹陷新沟嘴组下段;d—潜江凹陷潜江组。

Fig.5 Paleogene sedimentary facies map of the Jianghan Basin. Modified after [57,61-62].

图6 江汉盆地富锂卤水储层岩性特征 a、b—江陵凹陷泥岩裂隙储层,岗钾1井岩心;c—江陵凹陷砂岩储层,岗钾2井岩心;d—江陵凹陷玄武岩储层,八岭山地区玄武岩露头;e、f—潜江凹陷砂岩储层,分别为泽5井和广29井岩心。

Fig.6 Lithofacies of Li-rich brine reservoir in the Jianghan Basin

图7 江汉盆地砂岩、火山岩厚度变化特征 (据文献[31,61]) a—江陵凹陷沙市组至新沟嘴组下段砂岩等厚图[31];b—江陵凹陷火山岩等厚图[31];c—潜江凹陷潜江组砂岩等厚图[61]。

Fig.7 Isopach maps of sandstones (a, c) and volcanic rocks (b) in the Jianghan Basin. Modified after [31,61].

图8 裂谷盆地钾、锂成矿示意图 (据文献[9]修改)

Fig.8 Model describing the potassium and lithium mineralization pathways in a rift basin. Modified after [9].

图9 江陵凹陷卤水综合利用原则工艺路线 (据文献[80]修改)

Fig.9 Principle process route of comprehensive utilization of brine in Jiangling Depression. Modified after [80].

图10 江陵凹陷卤水沉淀法提锂工艺 (据文献[80]修改)

Fig.10 Lithium production extraction process by precipitation from brine in Jiangling Depression. Modified after [80].

参考文献 86

[1]	GIL-ALANA L A, MONGE M. Lithium: production and estimated consumption. Evidence of persistence[J]. Resources Policy, 2019, 60:198-202. DOI URL
[2]	KESLER S E, GRUBER P W, MEDINA P A, et al. Global lithium resources: relative importance of pegmatite, brine and other deposits[J]. Ore Geology Reviews, 2012, 48:55-69. DOI URL
[3]	王秋舒, 元春华, 许虹. 全球锂矿资源分布与潜力分析[J]. 中国矿业, 2015, 24(2):10-17.
[4]	CHRISTMANN P, GLOAGUEN E, LABBÉ J F, et al. Global lithium resources and sustainability issues[M]// Lithium process chemistry. Amsterdam: Elsevier, 2015: 1-40.
[5]	李建康, 刘喜方, 王登红. 中国锂矿成矿规律概要[J]. 地质学报, 2014, 88(12):2269-2283.
[6]	LI R Q, LIU C L, JIAO P C, et al. The tempo-spatial characteristics and forming mechanism of lithium-rich brines in China[J]. China Geology, 2018, 1(1):72-83. DOI URL
[7]	HE M Y, LUO C G, YANG H J, et al. Sources and a proposal for comprehensive exploitation of lithium brine deposits in the Qaidam Basin on the northern Tibetan Plateau, China: evidence from Li isotopes[J]. Ore Geology Reviews, 2020, 117:103277. DOI URL
[8]	潘源敦, 刘成林, 徐海明. 湖北江陵凹陷深层高温富钾卤水特征及其成因探讨[J]. 化工矿产地质, 2011, 33(2):65-72.
[9]	刘成林. 大陆裂谷盆地钾盐矿床特征与成矿作用[J]. 地球学报, 2013, 34(5):515-527.
[10]	马黎春, 黄华, 张连元, 等. 湖北潜江凹陷古近系深层富钾卤水矿床特征及成因[J]. 地质学报, 2015, 89(11):2114-2121.
[11]	黄华, 张士万, 张连元. 潜江凹陷潜江组深层卤水矿产特征与资源评价[J]. 盐湖研究, 2015, 23(2):34-43.
[12]	刘成林, 余小灿, 赵艳军, 等. 华南陆块液体钾、锂资源的区域成矿背景与成矿作用初探[J]. 矿床地质, 2016, 35(6):1119-1143.
[13]	周敏娟, 胡立, 黄小年, 等. 江西省泰和县梅岗含锂卤水矿成矿地质特征及开发利用前景[J]. 现代矿业, 2017, 33(11):61-64, 82.
[14]	王春连, 刘丽红, 李强, 等. 江西吉泰盆地卤水型锂钾矿物源区岩石地球化学特征及成因分析[J]. 岩石矿物学杂志, 2020, 39(1):65-84.
[15]	舒良树. 华南构造演化的基本特征[J]. 地质通报, 2012, 31(7):1035-1053.
[16]	XIA G Q, YI H S, ZHAO X X, et al. A late Mesozoic high plateau in Eastern China: evidence from basalt vesicular paleoaltimetry[J]. Chinese Science Bulletin, 2012, 57(21):2767-2777. DOI URL
[17]	ZHANG L M, WANG C S, CAO K, et al. High elevation of Jiaolai Basin during the Late Cretaceous: implication for the coastal mountains along the East Asian margin[J]. Earth and Planetary Science Letters, 2016, 456:112-123. DOI URL
[18]	童崇光. 中国东部裂谷系盆地的石油地质特征[J]. 石油学报, 1980, 1(4):19-26.
[19]	GILDER S A, KELLER G R, LUO M, et al. Eastern Asia and the Western Pacific timing and spatial distribution of rifting in China[J]. Tectonophysics, 1991, 197(2/3/4):225-243. DOI URL
[20]	任纪舜, 杨巍然. 中国东部岩石圈结构与构造岩浆演化[M]. 北京: 原子能出版社, 1998.
[21]	华仁民, 毛景文. 试论中国东部中生代成矿大爆发[J]. 矿床地质, 1999, 18(4):300-307.
[22]	LI X H. Cretaceous magmatism and lithospheric extension in Southeast China[J]. Journal of Asian Earth Sciences, 2000, 18(3):293-305. DOI URL
[23]	REN J Y, TAMAKI K, LI S T, et al. Late Mesozoic and Cenozoic rifting and its dynamic setting in Eastern China and adjacent areas[J]. Tectonophysics, 2002, 344(3/4):175-205. DOI URL
[24]	毛景文, 谢桂青, 李晓峰, 等. 华南地区中生代大规模成矿作用与岩石圈多阶段伸展[J]. 地学前缘, 2004, 11(1):45-55.
[25]	ZHAI M G, FAN Q C, ZHANG H F, et al. Lower crustal processes leading to Mesozoic lithospheric thinning beneath eastern North China: underplating, replacement and delamination[J]. Lithos, 2007, 96(1/2):36-54. DOI URL
[26]	刘少峰, 张国伟. 大别造山带周缘盆地发育及其对碰撞造山过程的指示[J]. 科学通报, 2013, 58(1):1-26.
[27]	LIU S F, STEEL R, ZHANG G W. Mesozoic sedimentary basin development and tectonic implication, northern Yangtze Block, Eastern China: record of continent-continent collision[J]. Journal of Asian Earth Sciences, 2005, 25(1):9-27. DOI URL
[28]	刘少峰, 王平, 胡明卿, 等. 中、上扬子北部盆-山系统演化与动力学机制[J]. 地学前缘, 2010, 17(3):14-26.
[29]	戴世昭, 方志雄. 江汉断陷盐湖盆地石油地质特征及其勘探[J]. 江汉石油科技, 1994, 4(2):1-7.
[30]	王必金, 林畅松, 陈莹, 等. 江汉盆地幕式构造运动及其演化特征[J]. 石油地球物理勘探, 2006, 41(2):226-230.
[31]	王春连, 黄华, 王九一, 等. 江陵凹陷富钾锂卤水矿田地质特征及成藏模式研究[J]. 地质学报, 2018, 92(8):1630-1646.
[32]	吴必豪, 渠洁瑜, 王弭力, 等. 湖北Q凹陷第三纪含盐系Br、 Rb、 B、 Li的地球化学研究[J]. 矿床地质, 1983, 2(1):76-86.
[33]	方志雄. 潜江凹陷隐蔽油藏成藏主控因素及勘探方向[J]. 石油与天然气地质, 2006, 27(6):804-812.
[34]	张水山, 张三元, 周红艳, 等. 潜江凹陷蚌湖向斜周缘岩性油藏识别技术及效果[J]. 岩性油气藏, 2014, 26(5):86-90.
[35]	江新胜, 潘忠习. 中国白垩纪沙漠及气候[M]. 北京: 地质出版社, 2005.
[36]	SCHERER C M S, GOLDBERG K. Palaeowind patterns during the late Jurassic-early Cretaceous in Gondwana: evidence from aeolian cross-strata of the Botucatu Formation, Brazil[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2007, 250(1/2/3/4):89-100. DOI URL
[37]	HASEGAWA H, TADA R, JIANG X, et al. Drastic shrinking of the Hadley circulation during the mid-Cretaceous Supergreenhouse[J]. Climate of the Past, 2012, 8(4):1323-1337. DOI URL
[38]	CHUMAKOV N M, ZHARKOV M A, HERMAN A B, et al. Climatic belts of the mid-Cretaceous time[J]. Stratigraphy and Geological Correlation, 1995, 3(3):42-63.
[39]	陈丕基. 晚白垩世中国东南沿岸山系与中南地区的沙漠和盐湖化[J]. 地层学杂志, 1997, 21(3):203-213.
[40]	RODRÍGUEZ-LÓPEZ J P, CLEMMENSEN L B, LANCASTER N, et al. Archean to recent aeolian sand systems and their sedimentary record: current understanding and future prospects[J]. Sedimentology, 2014, 61(6):1487-1534. DOI URL
[41]	YANG Y T. An unrecognized major collision of the Okhotomorsk Block with East Asia during the Late Cretaceous: constraints on the plate reorganization of the Northwest Pacific[J]. Earth-Science Reviews, 2013, 126:96-115. DOI URL
[42]	CHEN P J. Paleoenvironmental changes during the Cretaceous in eastern China[J]. Developments in Palaeontology and Stratigraphy, 2000, 17:81-90.
[43]	吴萍, 杨振强. 中南区白垩纪至早第三纪岩相古地理概要[J]. 地质论评, 1980, 26(1):25-29.
[44]	叶芝萍. 东南油气区第三纪古气候[J]. 石油学报, 1992, 13(2):143-149.
[45]	王大宁, 赵英娘. 江汉盆地晚白垩世—早第三纪早期孢粉组合特征及其地层意义[C]//地层古生物论文集(第九辑), 1980(2):121-171.
[46]	万重芳. 江汉盆地早第三纪古气候、古生态和古环境分析[J]. 江汉石油科技, 1991, 1(2):8-15.
[47]	陈波, 张昌民, 韩定坤, 等. 干旱气候条件下陆相高分辨层序地层特征研究: 以江汉盆地西南缘晚白垩世渔洋组为例[J]. 沉积学报, 2007, 25(1):21-28.
[48]	王春连, 刘成林, 胡海兵, 等. 江汉盆地江陵凹陷南缘古新统沙市组四段含盐岩系沉积特征及其沉积环境意义[J]. 古地理学报, 2012, 14(2):165-175.
[49]	王春连, 刘成林, 徐海明, 等. 江陵凹陷古新世盐湖沉积碳酸盐碳氧同位素组成及其环境意义[J]. 地球学报, 2013, 34(5):567-576.
[50]	WANG C L, LIU C L, WANG J Y, et al. Palynology and stratigraphy of the thick evaporate-bearing Shashi Formation in Jiangling Depression, Jianghan Basin of South China, and its paleoclimate change[J]. China Geology, 2020, 3(2):283-291.
[51]	关德范. 新华夏系第二沉降带油、气形成的地质条件[J]. 大庆石油学院学报, 1977, 1(2):7-21.
[52]	刘若新. 中国新生代火山岩年代学与地球化学[M]. 北京: 地震出版社, 1992.
[53]	徐义刚, 樊祺诚. 中国东部新生代火山岩研究回顾与展望[J]. 矿物岩石地球化学通报, 2015, 34(4):682-689, 673.
[54]	徐论勋, 阎春德, 俞惠隆, 等. 江汉盆地下第三系火山岩年代[J]. 石油与天然气地质, 1995, 16(2):132-137.
[55]	YU X C, LIU C L, WANG C L, et al. Origin of geothermal waters from the Upper Cretaceous to Lower Eocene strata of the Jiangling Basin, South China: constraints by multi-isotopic tracers and water-rock interactions[J]. Applied Geochemistry, 2020, 124:104810. DOI URL
[56]	于升松. 湖北江汉盆地潜江凹陷深层地下卤水水文地球化学研究[J]. 盐湖研究, 1994, 2(1):6-17.
[57]	沈均均, 陈波, 王春连, 等. 江陵凹陷古近系沙市组含膏盐岩系沉积特征研究[J]. 地球学报, 2014, 35(4):425-433.
[58]	YU X C, WANG C L, LIU C L, et al. Sedimentary characteristics and depositional model of a Paleocene—Eocene salt lake in the Jiangling Depression, China[J]. Chinese Journal of Oceanology and Limnology, 2015, 33(6):1426-1435. DOI URL
[59]	YU X C, LIU C L, WANG C L, et al. Sedimentary characteristics and palaeoclimatic significance of glauberite in Paleocene lacustrine deposits of the Jiangling Depression, central China[J]. Geosciences Journal, 2018, 22(3):407-422. DOI URL
[60]	WANG C L, LIU C L, YU X C, et al. The extremely hot and dry climatic events and potash enrichment in salt lakes of the Jiangling Depression, Jianghan Basin[J]. Acta Geologica Sinica, 2016, 90(2):769-770. DOI URL
[61]	胡辉. 江汉盆地潜江凹陷岩性油藏形成条件及分布规律研究[J]. 地质力学学报, 2005, 11(1):67-73.
[62]	沈均均, 陈波, 王春连, 等. 江汉盆地江陵凹陷古近系新沟咀组含膏盐岩系沉积特征及控制因素[J]. 古地理学报, 2015, 17(2):265-274.
[63]	范传军. 江汉盐湖盆地潜江组沉积控制因素与岩性油藏[J]. 江汉石油职工大学学报, 2006, 19(6):25-28.
[64]	蔡芃睿, 王春连, 刘成林, 等. 运用扫描电镜和压汞法研究江汉盆地古新统—白垩系砂岩储层孔喉结构及定量参数特征[J]. 岩矿测试, 2017, 36(2):146-155.
[65]	戴世昭. 江汉盐湖盆地石油地质[M]. 北京: 石油工业出版社, 1997.
[66]	王芳, 赵新生, 田继军. 江汉盆地潜江凹陷岩性油藏规律研究[J]. 西部探矿工程, 2011, 23(11):53-57, 60.
[67]	黄华, 张士万, 张连元, 等. 潜江凹陷潜江组砂岩卤水矿床测井识别方法研究[J]. 化工矿产地质, 2013, 35(2):65-71.
[68]	BRADLEY D, MUNK L, JOCHENS H, et al. A preliminary deposit model for lithium brines[J]. USGS Professional Paper, 2013, 1006:1-6.
[69]	MUNK L A, HYNEK S A, BRADLEY D C, et al. Lithium brines: a global perspective[J]. Reviews in Economic Geology, 2016, 18:339-365.
[70]	WANG L C, LIU C L, WANG C L, et al. Lithium isotope evidence for the source of potassium-rich brine solutes in the Jiangling depression of central China[J]. Acta Geologica Sinica, 2017, 91(1):363-364. DOI URL
[71]	余小灿. 华南陆块中新生代蒸发岩盆地火山作用对富钾锂卤水成因约束: 以江陵凹陷为例[D]. 北京: 中国地质大学(北京), 2019:83-94.
[72]	渠洁瑜, 吴必豪, 李际明. 地下卤水成因类型的统计分析: 以潜江凹陷为例[J]. 工程勘察, 1984, 12(1):65-70.
[73]	付路路, 刘成林, 王青春, 等. 湖北潜江凹陷北部古近系孔隙卤水矿床特征及成因[J]. 盐湖研究, 2018, 26(1):15-24.
[74]	吴必豪, 祁佐明, 王弭力, 等. 湖北Q盆地含盐系地球化学的研究[J]. 地质学报, 1980, 54(4):324-334.
[75]	江汉油田地质志编写组. 中国石油地质志(卷9): 江汉油田[M]. 北京: 石油工业出版社, 1991:1-488.
[76]	张士万, 黄华, 张连元, 等. 深井卤水资源勘探与评价报告[R]. 武汉: 中国石油化工股份有限公司江汉油田分公司, 2014:135-154.
[77]	赵艳军, 王春连, 余小灿, 等. 湖北省沙洋县地下卤水调查评价成果报告[R]. 北京: 中国地质科学院矿产资源研究所, 2016:1-50.
[78]	刘成林, 徐海明, 王春连, 等. 江陵凹陷中南部深层卤水氯化钾资源量评价报告[R]. 北京: 中国地质科学院矿产资源研究所, 2013:1-83.
[79]	郑春辉, 董殿权, 刘亦凡. 卤水锂资源及其开发进展[J]. 化工技术与开发, 2006, 35(12):1-4, 31.
[80]	刘成林, 徐海明, 王春连, 等. 江陵凹陷富钾卤水勘查与研究阶段性总结报告[R]. 北京: 中国地质科学院矿产资源研究所, 2011:154-201.
[81]	谭秀民, 张秀峰, 张利珍. 江陵凹陷深层卤水提碘工艺研究[J]. 盐业与化工, 2012, 41(12):20-21, 23.
[82]	谭秀民, 张秀峰, 张利珍. 江陵凹陷深层卤水提溴工艺研究[J]. 无机盐工业, 2013, 45(5):13-14, 37.
[83]	孟素青, 李瑞琴, 丁建跃, 等. 萃取法(t-BAMBP)提取卤水中铷、铯及其影响因素分析[J]. 中国井矿盐, 2013, 44(6):12-14.
[84]	陈侠, 郑颖贺, 胡宇飞, 等. 混合醇萃取深层地下卤水中硼的实验研究[J]. 无机盐工业, 2015, 47(9):35-37.
[85]	陈侠, 陈洁, 苗淑兰, 等. 江陵地下卤水富集锂的变化规律研究[J]. 无机盐工业, 2019, 51(7):51-54.
[86]	张秀峰, 谭秀民, 张利珍, 等. 从江陵凹陷富钾地下卤水中提取硼酸[J]. 无机盐工业, 2015, 47(5):21-23.

江汉盆地大型富锂卤水矿床成因与资源勘查进展:综述

Genesis of lithium brine deposits in the Jianghan Basin and progress in resource exploration: A review

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 86

相关文章 7

编辑推荐

Metrics

本文评价

[1]	王彤, 朱筱敏, 董艳蕾, 杨道庆, 苏彬, 谈明轩, 刘宇, 伍炜, 张亚雄. 陆相坳陷湖盆沉积对深时古气候的响应信号: 以准噶尔盆地西北缘安集海河组为例[J]. 地学前缘, 2021, 28(1): 60-76.
[2]	李国彪, 王天洋, 李新发, 牛晓路, 张文苑, 谢丹, 李阅薇, 姚又嘉, 李琪, 马雪嵩, 李兴鹏, 修迪, 韩子晨, 赵胜楠, 韩屹, 薛嵩, 任荣, 贾志霞. 西藏特提斯喜马拉雅海相白垩纪—古近纪生物地层与重大地质事件研究进展[J]. 地学前缘, 2020, 27(6): 144-164.
[3]	席党鹏, 唐自华, 王雪娇, 覃祚焕, 曹文心, 江湉, 吴宝旭, 栗源浩, 张赢月, 姜文彬, KAMRAN Muhammad, 方小敏, 万晓樵. 塔里木盆地西部白垩纪—古近纪海相地层框架及对重大地质事件的记录[J]. 地学前缘, 2020, 27(6): 165-198.
[4]	雷华蕊，姜在兴，周红科. 早古近纪极热时期古气候演化分析：以东营凹陷为例[J]. 地学前缘, 2018, 25(4): 176-184.
[5]	胡修棉，李娟，安慰，王建刚. 藏南白垩纪—古近纪岩石地层厘定与构造地层划分[J]. 地学前缘, 2017, 24(1): 174-194.
[6]	丁守卓, 罗金海, 程佳孝, 韩奎, 王师迪, 尤佳. 西秦岭伯阳石英正长斑岩的地球化学、年代学及其地质意义[J]. 地学前缘, 2015, 22(4): 247-254.
[7]	李增学，张功成，李莹，刘海燕，吕大炜，沈怀磊，尚鲁宁. 中国海域区古近纪含煤盆地与煤系分布研究[J]. 地学前缘, 2012, 19(4): 314-326.