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    2008, Volume 15 Issue 5
    02 May 2008
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    Ecological geochemistry: from a geochemical survey to an applied theory.
    XI Xiao-Huan
    2008, 15(5): 1-8. 
    Abstract ( 2276 )   PDF (1247KB) ( 1005 )  

     On the basis of multipurpose regional geochemical survey, ecological geochemistry is a complex project composed of ecogeochemical assessment, ecogeochemical evaluation, ecogeochemical warning and ecogeochemical remediation. This paper systematically summarizes the achievements in the research of ecogeochemistry in China for recent years. Progress in regional ecogeochemical assessment has been presented, including the research on river ecosystem in Yangzi regions, farm land ecosystem in Shanxi, urban ecosystem in Beijing, and those lakemarsh ecosystems in Poyang Lake, Dongting Lake and Tai Lake. The methods of calculation of soil carbon reserves, soil baseline and background values, and the grading of soil pollution have been discussed on a regional scale. Further steps of the research on ecogeochemistry have also been proposed in this article, as well as the depicting of the future of ecogeochemistry.

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    A new round of global geochemical mapping: opportunity and challenge to China
    CHENG Hang-Xin YANG Zhong-Fang XI Xiao-Huan DIAO Chuan-Dong
    2008, 15(5): 9-22. 
    Abstract ( 2252 )   PDF (2373KB) ( 874 )  

    Since the projects of “International Geochemical Mapping (IGCP259)” and

    “Global Geochemical Baseline (IGCP360)” were met with approval by UNESCO in 1988, decisive

    contributions of working out the methodological guidance and the technical standard of

    global geochemical mapping have been made by China and Europe.  Though demonstrations have

    been made by China and Europe through carrying out the projects of “Environmental

    Monitoring Network and Dynamic Geochemical Mapping” and “FOREG geochemical baseline

    mapping”, respectively, the expectation of acquiring a general picture of global

    geochemistry in 10 years has not yet been realized. Geochemists from China and Norway are

    now deliberating, through International Association of Hydrological Sciences/International

    Commission on Continental Erosion (IAHS/ICCE), about a major international cooperative

    project on “Global Geochemical Mapping and SedimentBound Flux of Major World Rivers”, on

    carrying out a new round global geochemical mapping, and planning to start working first on

    the Arctic region under the project of the Year of Polar (IPY317). The practical plan for

    the Global Geochemical Mapping is based on the “Draft of Sampling Plan of Floodplain

    sediments” for the Global Geochemical Mapping suggested by China and the “Draft of

    Sampling Plan of Overbank Sediments in Deltas” suggested by Norway, thereby further

    strengthening the advantages of Chinese methodology in geochemical mapping. After analyzing

    the opportunities and challenges to China, this article suggests that the competent

    authorities of science and technology should take the initiative of supporting the new round

    global geochemical mapping.

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    An example of ecogeochemical assessment for agroecosystems: a study of Cd in Chengdu economic region
    YANG Zhong-Fang HOU Jing-Xie TU Chao CHEN Jia-Wei JIA Hua-Ji HUANG Yong LI Kuo
    2008, 15(5): 23-35. 
    Abstract ( 1808 )   PDF (1764KB) ( 871 )  

    Chengdu economic region is selected as an example for ecogeochemical assessment

    of agroecosystem for Cd 58 samples of dry and wet atmospheric deposition, 86 of chemical

    fertilizers, 121 of irrigation water and 276 of plants were collected Concentrations of Cd

    and other elements in those samples were analyzed and fluxes of input and output for the

    agroecosystem were calculated The results indicated that Cd was more concentrated in the

    surface soil than in the deep one and Cd concentrations in some rice samples exceeded the

    standards for the pollution free agricultural products The flux of Cd inputting to the

    agroecosystem is averaged to 1776 g/(hm2·a), accounting for 8520% of the total input

    flux Water Downward infiltrating (234 g/(hm2·a)) and crop harvesting (187 g/(hm2·a))

    are the two maximal Cd outputs The average increasing rate of Cd content in soil resulted

    from sources outside of the agroecosystem is 0006 mg/(kg·a) It was forecasted that the

    area of the third class soil would increase by 23 times under the condition of constant

    input and output fluxes of Cd The rate of acidification is 0106 a-1 and the contribution

    of chemical fertilization for soil acidification is 8962%, preponderating over that of

    acid rain The study of ecogeochemical alarming indicated that though 95% of rice

    production was safe at present, however, 70% of safe soil would degenerate to ecumenical

    one, and the area of soil in alarm would increase from 4% to 27%

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    Study of  distribution of geochemical speciation of cadmium and factors controlling the distribution in paddy soil profiles, Chengdu Plain, Southwest China.
    HOU Jing-Xie YANG Zhong-Fang YANG Xiao-Yan YANG Yan LAI Mu-Shou
    2008, 15(5): 36-46. 
    Abstract ( 1759 )   PDF (1429KB) ( 1033 )  

    For understanding geochemical behaviors of cadmium (Cd), it is essential to study

    the factors that affect the transport of different geochemical species of cadmium in the

    pedogenetic process. We focus on the distribution features of cadmium species in paddy soil

    profiles in Chengdu agroecosystems in Sichuan Province, in order to discuss the factors

    controlling geochemical behaviors of cadmium species, and to assess the ecological safety.

    It is known that Cd background values of paddy soils in Minjiang River and Tuojiang River

    catchments are 0147 mg·kg-1 and 0215 mg·kg-1, respectively. The inputs of Cd Ion

    exchange species and Cd carbonate species into cultivated soils dominate the total Cd

    increments, and these cadmium species have limited ability to transfer along the profiles.

    The total Cd, pH, total organic carbon (TOC) and clay minerals contents have significant

    influence on the transferring of Cd species. The bioavailability index of cadmium for

    cultivated paddy soil is very high; it ranges between 059 and 065, which suggests that

    the cultivated soils have posed high risk on plant safety.

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    Environmental Health Risk Assessment of heavy metals in argoecosystems of Deyang district, Sichuan Province.
    JIN Li-Xin HOU Jing-Xie YANG Zhong-Fang BAO Yu-Han LI Zhong-Hui XU Zhou CHEN De-You
    2008, 15(5): 47-56. 
    Abstract ( 1817 )   PDF (1129KB) ( 1086 )  

    Environmental Health Risk Assessment is an important method for quantitatively

    describing the relationship between the pollution and the human health. This paper adopts

    the theories and the models for Health Risk Assessment recommended by the U.S. Environmental

    Protection Agency. We calculate the heavy metals intake risk through inhalation, foods,

    drinking water and skins. The results suggest that the noncarcinogenic risk index is more

    than 1, which  implies that they are the health risk for the residents in Deyang. The health

    risk for people in Mianzhu and Jingyang is very high; the noncarcinogenic risk index for

    these two areas are 776 and 4.36, respectively. Foods are a dominative factor for risk in

    comparison to other ways. Although the results have some uncertainties, they are important

    for the risk management in the study areas.

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    The distribution rule of soil carbon in Dongting lake district and its response to the global climate change.
    ZHANG Jian-Xin GENG Xu-Dong LU Jiang LV Huan-Zhe
    2008, 15(5): 57-66. 
    Abstract ( 1936 )   PDF (1505KB) ( 772 )  

    It is important to research on the distribution rule of the regional soil carbon

    pool for the study of global change, soil fertility and ecosystem function appraisal. The

    domestic and foreign scientists do the research by using models and the second soil survey

    data for lack of longterm actual material. This article studies several factors affecting

    soil carbon distribution by using ecologicalgeochemistry investigation data in Dongting

    lake district. The study revealed that the regional soil carbon quantity is in the high

    intermediate level of our country, and that the geological landform is the most important

    factor  affecting the distribution of soil inorganic carbon quantity, and the soil type is

    also an influential factor. The soil erosion has little effect on TOC in the surface layer.

    The utilization of land by forestation, and the prevention and control of soil dives

    nurtures are advantageous to the soil carbon storage. The temporalspatial distribution

    rules of the deposition of TOC and so on indicate that the regional environmental variation

    is the response to the global environmental variation. This research provided a basis for

    the study of regional land utilization, soil carbon fixation and global environment

    variation.

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    Factors affecting the geochemical behavior of heavy metal elements Pb and Cd in soil.
    TU Chao YANG Zhong-Fang ZHONG Jian CHENG Xin-Ban
    2008, 15(5): 67-73. 
    Abstract ( 1841 )   PDF (916KB) ( 1046 )  

    In this paper,we have studied the relationship of lead and cadmium to the organic

    matter, clay content and pH in the paddy soil in the Dongting lake region, Hunan Province

    It shows that the content of organic matter has a distinct relationship to cadmium or lead

    in soilThe increase in organic matter in soil may obviously lower the content of cadmium

    or lead in ionic and exchangeable formAlso, the increase in clay content in soil may

    slightly increase the proportion of the content of cadmium and lead in ionic exchangeable

    form to the total content of Pb and CdThe lead or cadmium that is adsorbed in the clay

    surface may enter into the frond more easily, and would endanger the ecosystemThe soil

    acidification may increase the content of cadmium in ionic exchangeable form, which has a

    distinct relationship to the pH in soil, and directly results in the increase in cadmium

    content in crop, thus it is a good way to avoid ecosystem damage by preventing soil

    acidificationThe proportion of the content of lead in ionic exchangeable form to the total

    content of lead is distinctly related to the pH in soil; keeping soil pH in a range of less

    acidity to alkalescence is a better way to prevent soil acidification or basification in the

    heavily leadpolluted areaIt is concluded that the soil organic matter and soil pH are

    the most important factors controlling the geochemical behavior of heavy metals

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    Geochemical characteristics and fluxes of elements in rain water and soil leaching water in the Chengdu economic region
    LIU Dong-Cheng YANG Zhong-Fang JIA Hua-Ji HOU Jing-Xie TU Chao
    2008, 15(5): 74-81. 
    Abstract ( 1802 )   PDF (986KB) ( 802 )  

     In this paper, we have studied the element contents in rain water and soil

    leaching water, the output and input flux of farmland tilth and its influencing factors in

    the Chengdu economic region The results show that the rain water in the study area

    contains a lot of acidic material such as SO2-4, NO-3, etc, and SO2-4>NO-3>Cl- by

    concentration The concentrations of Ca2+ and NH+4 are the highest, and NH+4>Ca2+>

    K+>Na+>Mg2+ in the rain water The pH of the rain water and the difference between anion

    and cation molar concentration are significantly correlated By concentration,

    Pb>As>Cd>Se>Hg in the rain water and Pb>As>Se>Cd>Hg in leaching water in different areas; as

    a result, the element of Cd, Pb, Se, Hg, etc are accumulated in tilth layer, and As was

    carried out from tilth layer into the underground by leaching The Cd flux in the soil from

    the rain water is more than that from leaching; the leaching flux of As is 545 to 1316

    times higher than the flux from the rain water in some parts of the area The leaching

    ratio of tilth elements is related to soil texture and pH value.

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    Geochemical characteristics of DDT and HCH in agricultural soil in the suburb of Beijing.
    LIU Chen CHEN Jia-Wei YANG Zhong-Fang
    2008, 15(5): 82-89. 
    Abstract ( 2208 )   PDF (1028KB) ( 1108 )  

    Beijing is the political, economical and cultural center of China with a huge

    population. As the rapid development of society and economy, a great many of environmental

    problems come about. The organochlorine pesticide is a kind of persistent organic

    pollutants, and nowadays more attention is paid to its pollution to the environment. Because

    the quality of soil is closely related to the human health, it is very important and

    meaningful to do research on the residues of organochlorine pesticide in agricultural soil

    in the suburb of Beijing. In this paper, the distributional characteristics of the DDTs and

    HCHs residues were analyzed in both surface and deep soil samples. The risks of DDTs and

    HCHs residues were also discussed, and it could provide a reference for evaluation of

    environmental geochemistry. The DDTs and HCHs were detected in 9 surface soil and 8 deep

    soil samples at different levels. The DDTs residues were at a low level with the ∑DDTs

    ranging from 0 to 29240 μg/kg, while the contents of ∑HCHs varied from 069 μg/kg to

    2662 μg/kg. Few DDT isomers were detected in the deep soil samples. The contents of DDTs

    were decreased with the increase in the depth of soil profile. In one sample the four

    isomers of DDT  were found in the first layer, and in the others only p,p′DDE was

    detected. The HCHs were found in all the layers at different levels. The contents of HCHs

    were not increased obviously as the depth of soil profile increased. The concentrations of

    DDTs in most samples reached the first level of the national standard quality of soil

    environment (GB 1561895). And the contents of HCHs were also lower than the standard.

    According to the concentration and distribution of different isomers, we concluded that

    there was no new input of pollution in this area.

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    Distinguishing origins of elements in environmental geochemistry of Baiyangdian billabong of Hebei province,
    ZHANG Xiu-Zhi GUO Hai-Quan LI Hong-Liang LI Jian-Hua
    2008, 15(5): 90-96. 
    Abstract ( 1818 )   PDF (1042KB) ( 814 )  

     The Baiyangdian billabong of Hebei province is a large natural plain billabong,

    in which multivariable geochemical anomalies,especially Cu,Pb,Zn,Cd,were detected in both

    topsoils and deepsoils. This study distinguished the characteristics and origins of the

    Cu,Pb,Zn,Cd anomalies in topsoils and deepsoils by the method of geochemical

    characteristics, the method of reference elements and the method of multivariate

    statistics. The result indicates that the anomalies presenting in deepsoils were related to

    the specific geochemical deposition environment that resulted mainly from natural

    processes;however,the geochemical anomalies presenting in topsoils have typical

    characteristics of dualistic superposition, and mainly resulted from anthropogenic

    activities.

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     A preliminary study of soil pollution assessment model based on SVM—a case example from Changsha, Zhuzhou and Xiangtan districts, Hunan Province.
    TUN Jian-Gong WANG Guan-Jin DAI Da-Gen HOU Mu-Zhou
    2008, 15(5): 97-102. 
    Abstract ( 2381 )   PDF (832KB) ( 1291 )  

     Considering the fact that a very limited amount of data of soil pollution are

    available and the demand of the urban development, the authors try to develop a model of

    soil pollution using impact factors that affect the quality of soil environment for the

    assessment and prediction of the soil pollution. The study employs the support vector

    machine (SVM) method, a fairly new pattern recognition tool, the advantages of which are the

    good adaptation to the case of limited samples, the effective generalization ability and the

    higher accuracy. The 9 impact factors including GDP, the amount of waste water, gas and

    solid waste, population, rainfall, vegetation, etc. are chosen as the input variables of the

    model and the percentages of the concentrations of Cu, Pb, Zn, Cd, Co, Ni, Cr, and Mn in

    polluted soil are taken as the output variables. The SVM model was trained and tested on 879

    soil samples collected in 1986 and 2003, and 51 impact factor samples spanning 17 years. For

    optimizing and approximating the implicit performance function, we employed a Gauss kernel

    function and calculated the value kernel (γ), loss function insensibility (ε) and punish

    function parameters (C) by genetic algorithm methods; the corresponding values are 1.021,

    0.000416 and 1012, respectively. Eventually we thus obtained the SVMbased explicit

    performance functions of soil pollution with impact factors, and the model has shown its

    effectiveness.

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     Comparison between methods for interpolation of studying spatial distribution of elements: a case study of soil heavy metals in Tongling area, south China.
    YUAN Feng BAI Xiao-Yu ZHOU Chao-Fa LI Xiang-Ling ZHANG Xin CHEN Xin-Ren CHEN Yong-Ning
    2008, 15(5): 103-109. 
    Abstract ( 1699 )   PDF (918KB) ( 1338 )  

    Taking six kinds of elements of soil contamination including As, Cd, Cu, Pb, Tl

    and Zn in Tongling area as an example, we have made spatial interpolation for soil elements

    by using four types of representative interpolation methods, including inverse distance

    weighted, radial basis function, ordinary Kriging and multifractal interpolation, and have

    validated and appraised the resultsComparison is made between methods with optimized

    parameters337 soil samples in a total of 372 samples were used for interpolation, and the

    rest 35 samples not having been interpolated were used for validationThe results of

    comparison indicate that ordinary Kriging exhibits best effect in characterizing spatial

    distribution trend of soil elements, yet the optimized models and parameters of semi

    variogram are still pending further study; multifractal method is the best in characterizing

    local abnormality and contamination, whereas its function of reflecting the general texture

    of soil element distribution needs indepth study; inverse distance weighted and radial

    basis function interpolate less accurately for the spatial distribution of soil elements,

    but are easy to use and to select optimized parameters.

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     Micronutrients in soils, crops, and livestock.
    Umesh C.Gupta Wu Kening Liang Siyuan
    2008, 15(5): 110-125. 
    Abstract ( 1646 )   PDF (457KB) ( 1543 )  

     Micronutrient concentrations are generally higher in the surface soil and decrease with soil depth. In spite of the high concentration of most micronutrients in soils, only a small fraction is available to plants. Micronutrients, also known as trace elements, are required in microquantities but their lack can cause serious crop production and animal health problems.Crops vary considerably in their response to various micronutrients. Brassicas and legumes are highly responsive to molybdenum (Mo) and boron (B), whereas corn and other cereals are more responsive to zinc (Zn) and copper (Cu). Micronutrient deficiencies are more common in humid temperate regions, as well as in humid tropical regions, because of intense leaching associated with high precipitation. Soil pH is one of the most important factors affecting the availability of micronutrients to plants. With increasing pH, the availability of these nutrients is reduced with the exception of Mo whose availability increases as soil pH increases. In most plant species, leaves contain higher amounts of nutrients than other plant parts. Therefore, whenever possible, leaves should be sampled to characterize the micronutrient status of crops. Deficiency symptoms for most micronutrients appear on the younger leaves at the top of the plant, whereas toxicity symptoms generally appear on the older leaves of plants.As summarized by Deckers and Steinnes, micronutrient deficiencies are widespread in developing countries, which have much poorer soil resources than the fertile soils of Europe and North America. Many of these areas lie in the humid tropics with extremely infertile, highly weathered, and/or highly leached soils, which are intensely deficient in nutrients. The rest of such soils are in the semiarid and areas adjacent to the latter, where alkaline and calcareous soil conditions severely limit the availability of micronutrients to plants.Frequently, the Cu, iron (Fe), manganese (Mn), Zn, and selenium (Se) levels in forages, which are sufficient for optimum crop yields, are not adequate to meet the needs of livestock. Selenium is a trace mineral, which is not required by plants, and maximum forage yields can be obtained on soils with very low amounts of soil Se. However, if animals are fed feed crops and forages with low Se, they could suffer from serious muscular disorders and other diseases. White muscle disease caused by Se deficiency is the most common disorder and is found in calves and lambs. Sufficiency levels of micronutrients for crops have been discussed in relation to the animal requirement.

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    Regional ecogeochemical assessment of mercury in soils in Beijing.
    CHENG Hang-Xin PENG An-Min DIAO Chuan-Dong YANG Ke NIE Hai-Feng LIU Fei HUANG Hong-Ku ?
    2008, 15(5): 126-146. 
    Abstract ( 2121 )   PDF (2912KB) ( 716 )  

    Mercury enrichments or anomalies in soils in urban and town areas are a general phenomenon in China, and investigation on source, transport cycle and fate of Hg in soil is essential for evaluating environmental risks. Soil Hg may be derived from natural and/or anthropogenic sources and may be deposited by wet or dry processes. Emitted Hg may be also derived from the reemission of Hg that was previously deposited to the soil from the atmosphere. It is important to understand the relative magnitude of emission, deposition, and reemission of Hg associated with ecosystem of cities with soil Hg anomalies because for these cities being the center districts of human activity, the aggravated Hg pollution would result in serious dangers to environment and human health. The major focus of this paper is to discuss soilair Hg exchange process, occurrence forms of mercury for high concentration Hg soils in Beijing, China. This information is important for developing ecogeochemical mass balances, assessing the effectiveness of regulatory controls of Hg emission from coal combustion.  Data collected from field and laboratory are presented. An extension measurement of mercury in soil covered 1044 km2 with a density of 1 sample/km2 were carried out within the Beijing area; 19 samples of dry and wet deposition, and 20 samples of airborne particles (PM10 and PM2.5) with a relatively uniform distribution using a grid design based on 7 km×7 km were collected. 131 atmospheric mercury samples and soil gas mercury samples in mercury enrichments area and 66 samples in mercury background area were sampled. Results indicate that the average content of Hg is 0.410±0.403 mg/kg in soil, 0.194±0.058 mg/kg in dry and wet precipitation, 3.13±2.35 ng/m3 in atmosphere, 559.65±1177.36 ng/m3 in soil gas, 0.59±0.26 ng/m3 and 0.67±0.49 ng/m3 in PM10 and in PM2.5, respectively. Hg emission from coal combustion has been significantly reduced to 1836 kg in 2006 compared with the emission of 8830 kg in 1999, because the Beijing government in 2000 issued a regulation on changing from coal combustion to natural gas combustion. Consequently, average Hg concentration in atmosphere has been obviously declined from 8.324.7 ng/m3 in 1998 to 3.13 ng/m3 in 2006, and Hg content in airborne particles has been diminished from 1.18 ng/m3 in 2003 to 0.59 ng/m3 in PM10 and 0.67 ng/m3 in PM2.5 in 2006, respectively. It means that the regulatory measures adopted by the Beijing government since 2000 to change the combustion mode from coal combustion to natural gas combustion has been successful in reducing Hg emission. Quantities of cinnabar minerals, metallic and glassy spherical particles characterized by high temperature melting were found in high concentration Hg in soil, which indicated that large ash and mercury emitted from coal combustion and metal smelting industry were deposited in soils in Beijing. Coupling spatial distribution patterns of S, Hg, pH with that of cinnabar minerals showed that the contents of S, Hg and pH in soil are key controlling factors for forming cinnabar minerals. The formation of soil gas Hg is not as well understood as the formation of cinnabar minerals in soil; whether the Hg released from soil was an original component of the soil (geogenic) or the reemission of Hg previously precipitated from the atmosphere is not known. But a good linear relationship for soil gas Hg versus atmospheric Hg was confirmed (n=131,R=0.267,p<0.01), which indicated that the sources of soil gas Hg may be the more significant contributors of mercury to the atmosphere than previously realized. The area average emission rate of mercury calculated for soil in the Beijing area is 102.42 ng/(m2·h), and the total Hg flux emitted to atmosphere from soil is 936.70 kg in 2005, which were obtained based on the linear relationship between the total Hg in soil and mercury flux of emission; while 1387 kg Hg was precipitated by the way of dry and wet precipitating processes. A prediction on mercury content in soil, mercury flux of emission from soil and precipitated flux of dry and wet precipitation in Beijing in 2050 has been made, and a scenario of soil environmental quality of mercury in Beijing in 2050 was outlined, which are based on the major objective of reducing 10% of total quantities of pollutant (including Hg) of the previous year, as indicated in Chinas 11th 5year plan.

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    Distributional characteristics of heavy metal elements in atmospheric particulate matter and their impact on land quality in Liaoning province.
    TU Chao CHENG Xin-Ban YANG Zhong-Fang DUAN Hong-Fei ZHANG Bing-Bing YANG Xiao-Bei
    2008, 15(5): 146-154. 
    Abstract ( 1821 )   PDF (1003KB) ( 956 )  

    Atmospheric particulate matter is one of the important common indicators for air quality assessment. Recent years, many researchers have studied the hot issues of atmospheric particulate matter pollution. In this paper,we selected the cities of Shenyang, Jinzhou and Huludao in Liaoning province to study the distributional characteristics of heavy metal elements in atmospheric particulate matter(TSP,PM10,PM2.5). It shows that the content of lead or zinc in the respirable particulate matter is the highest one, and the contents of copper, manganese, arsenic, chrome and cadmium are the higher ones. This perhaps results from coal combustion, oil combustion and other industrial sources of pollution. Furthermore, we have studied the impact of atmospheric particulate matter on land quality. It was concluded that the content of heavy metal element in atmospheric particulate matter has a significant correlation with the corresponding element content in soil, and the influence of atmospheric particulate matter on land quality is obvious. We suggest that the administration should pay much attention to monitoring the contents of heavy metal elements in atmospheric particulate matter to reduce their influence on land quality.

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     Pollution characteristics of polycyclic aromatic hydrocarbons in the topsoil of Taiyuan city,
    LIU Fei LIU Ying-Han WANG Jian-Wu NIE Hai-Feng FU Shan DIAO Chuan-Dong YANG Ke
    2008, 15(5): 155-160. 
    Abstract ( 1800 )   PDF (814KB) ( 807 )  

    Polycyclic aromatic hydrocarbons (PAHs) were quantified in 15 topsoils from Taiyuan CityConcentrations of ∑PAHs in topsoils ranged from 098 to 2623 μg/g with an average of 865 μg/g, and the spatial distribution of ∑PAHs declined from north to southThe abundance of the heavier PAHs was more than that of the low molecular weight PAHsBy contrasting Taiyuan with other cities, the pollution of PAHs in Taiyuan City was extremely serious and the primary source of soil PAHs was the coal combustionThe industry distribution, the energy structure and the location of Taiyuan City were the reasons of heavily pollution of PAHs

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    Concentrations and sources of heavy metal in atmospheric dustfall in the Nanjing city, East China.
    HUANG Shun-Sheng HUA Meng JIN Xiang TUN Xin-Min LIAO Qi-Lin SHU Bai-Mo BO Yong-Min
    2008, 15(5): 161-166. 
    Abstract ( 1855 )   PDF (693KB) ( 4693 )  

     Seventeen atmospheric dustfall samples were collected successively from December 2006 to December 2007 in Nanjing, China. All dustfall samples were analyzed for concentrations of As, Cd, Cr, Cu,  Hg, Mn, Mo, Ni, Pb, Se and Zn. The results indicated that, compared with the background values of soil in Nanjing area, atmospheric dustfalls have elevated metal concentrations as a whole, except those of Cr, Fe and Mn. Correlation coefficient analysis and principal component analysis (PCA) were performed and three main sources were identified: (1)As, Cu, Pb, Hg and Se are mainly derived from coal combustion and traffic exhaust; (2)Cd, Ni, Mo and Zn are possibly related to petrochemicals, and Mo is also originated from industrial sources and soil particles (natural source). The samples near to the petrochemical park have relatively high concentrations in these elements, which further confirms the source identification; (3)Cr and Mn are mainly derived from soil particles. Based on concentration analysis and correlation analysis, Fe was selected as the reference element to calculate the heavy metal enrichment factors (EFs), which in turn further validates the source identification. Naturally derived Cr and Mn show the lowest enrichment relative to the background values. Nevertheless, anthropogenically enhanced Cd, Pb, Se and Zn show maximum enrichments. Therefore, EFs give an insight of the level of human influence on atmospheric dustfalls.

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    Reconstruction of the regional soil pollution history by heavy metals in Taihu lake drainage area: taking Pb and Cd as examples.
    CHENG Hang-Xin DIAO Chuan-Dong PENG An-Min JIA Wei-Lan LIU Yang-Han YANG Ke NIE Hai-Feng
    2008, 15(5): 167-178. 
    Abstract ( 2196 )   PDF (1502KB) ( 984 )  

     The Taihu Lake located at the lower reaches of Yangtze River is a shallow large lake The Cd and Pb pollution history of sediments of the Taihu Lake and the soils of its intake areas has been reconstructed based on 137Cs and 210Pb depositional dating at 4 sections representing different depositional environments The results show that the Cd and Pb concentrations in the lake sediments were roughly equal to that of background level in the intake areas before 1980; while since then the concentrations have become considerably higher, which is just basically corresponding to the industrialization progress there It is thus inferred that the industrialization has been the main reason for the increase in Cd and Pb concentrations in the lake sediments The accumulated amounts of Cd and Pb in the lake sediments have been 146 t and 25980 t respectively since 1900, among them 40 t and 6777 t were due to the intake from Tiaoxi river, 36 t and 6023 t from Yili river, and 71 t and 13179 t from other rivers (say Tiao river, Ge river and the Grand Canal), respectively It is seen that the above mentioned other rivers have been the main sources for the accumulated Cd and Pb in the Taihu Lake The peak period of the accumulation was 8090s of the last century The outputs of Cd and Pb from the Grand Canal have been 2826 t and 3419 t since 1980, respectively; while the total outputs of Cd and Pb from the basin of Tiao river have been 1370 t and 1585 t, among them 890 t of Cd and 610 t of Pb have been due to human activities, corresponding to 6496 % and 3847 % of the total outputs of Cd and Pb respectively The total outputs of Cd and Pb from the basin of Yili river have been 1009 t and 1063 t since 1980, respectively, among them 696 t of Cd and 500 t of Pb have been due to human activities, corresponding to 6868 % and 4708 % of the total outputs of Cd and Pb respectively It shows that the accumulation of Cd due to human activity has been over that of natural denudation in the Taihu Lake drainage area The key measures for improving the environmental quality of the lake sediments should be to decrease the total discharge of Cd and Pb from industrialization progress and to control the outputs of Cd and Pb from the Grand Canal

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    A methodology of  tracking sources of  cadmium anomalies  and their quantitative estimation in the Yangtze River basin
    DIAO Chuan-Dong CHEN Fu-Rong CHEN Xin-Ren DIAO He-Cang JIA Wei-Lan NIE Hai-Feng KONG Mu
    2008, 15(5): 179-193. 
    Abstract ( 1921 )   PDF (1809KB) ( 928 )  

    The cadmium anomalies are spreading along almost the whole Yangtze River basinThis is the major ecological environmental issue discovered by the Multipurpose Geochemical Investigation that is being carried out in ChinaBy taking the Anhui section of the Yangtze River basin as its object, a systematical study on methodology of the source tracking and quantitative estimation of the Cd anomalies has been made in the paperBy determining contents of elements in suspended matters in the Anhui section of the trunk stream and main tributaries of the Yangtze River, it is shown that the suspended matters are the main carriers of heavy metals for long distance migrations; the concentration of Cd in the suspended matters is much higher than those of other heavy metals, this may be the main reason for forming the Cd anomalies spreading along the whole Yangtze River basin; and the tributaries of the Yangtze River have significant influences on the variations of heavy metal contents in the suspended matters in its trunk streamThe quantitative computation of output flow of heavy metals for the trunk stream and main tributaries for the Anhui section of the Yangtze River shows that the largest output flow of heavy metals is from the Qiupu River, with roughly 445 t of Cd deposited in soils along either bank of the Anhui section of the Yangtze RiverResults of source tracking of Cd anomalies along the Shunan River by detailed survey of suspended matters, soil survey on a scale of 1∶50 000 and rock survey indicate that endogenetic mineral deposits, especially PbZn deposits, are the largest suppliers of Cd in the suspended mattersWith techniques of layer sampling of sediments on alluvial beds and isotopic agedetermination, we have primarily reconstructed the geochemical history of sedimentation of Cd and other heavy metals and of their pollutions, and have made the prediction and early warning of evolution of anomalies of Cd and other heavy metals

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    Major ion chemistry in the Yangtze River.
    JIA Hua-Ji YANG Zhong-Fang WANG E-Beng JI Jun-Feng LI Wen-Meng YUAN Xu-Yin
    2008, 15(5): 194-202. 
    Abstract ( 3099 )   PDF (1098KB) ( 961 )  

     36 water samples were collected in the main Yangtze River channel and 40 in its tributaries. Concentrations of Ca2+,Mg2+,Na+,K+,HCO-3,SO2-4,Cl-and SiO2 in the water samples were determined. It was found that the chemistry of the Yangtze River is dominated by the weathering of carbonates and evaporites with high K+, Na+, Cl- and SO2-4 concentrations in the upstream of the Yangtze River, i.e. Tuotuohe, Tongtianhe and Jinshajiang, and Ca2+ and HCO-3 dominating the cations and anions in the middle and lower stream of the Yangtze River; All the major ions in Yangtze River water, especially Na+,K+,SO2-4 and Cl-, have increased significantly compared with data acquired from 1950s to 1990; Dongting Lake and Poyang Lake are the first two ion sources of the main Yangtze River channel. Besides the two lakes, the Minjiang River is the first source for Na+, K+, Ca2+, Mg2+, F- and HCO-3, and the Jialing River is the first source for SO2-4 and dissolved SiO2; the Yangtze River is the biggest source of Mg2+, SO2-4 and Cl- for the ocean, and its fluxes for Ca2+ and HCO-3 is next to the Amazon River.

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     The Cd geochemical province in the source area of the Yangtze River and the output fluxes of Cd for its major water systems
    CHENG Hang-Xin LIU Yang-Han NIE Hai-Feng SUN Ze-Hun FU Qi-Hong DIAO Juan XIE Li-Juan
    2008, 15(5): 203-211. 
    Abstract ( 2563 )   PDF (964KB) ( 807 )  

     The results of the multipurpose geochemical investigation in China, which is still in progress, show that Cd geochemical anomalies are spreading through the whole Yangtze River valley Reasonably, the origin of the anomalies and Cd output fluxes for the major tributaries of Yangtze River have become key points of scientific studiesThe water system in the source area of Yangtze River includes Tongtian River as well as tributaries of Togton River, Qumar River, Gar Qu, Bi Qu, Dam Qu, Kouqian Qu and Nyaqa Qu The geochemical mapping has been performed with dense sampling of stream sediments at 1 sample/km2, and a giant CdPbAs geochemical province and a Cd province have been outlined in the basins of Togton RiverGar Qu and the Za QuNyaga Qu  respectively, whereas for the rest of the area just show normal background of Cd, Pb and AsIt has been found out through the study that the contents of Cd, Pb and As in the rocks in the Togton RiverGar Qu geochemical province of Cd, Pb and As are significantly higher than those in soils and stream sediment, showing that a large amount of Cd, Pb and As were released to water bodies during the forming of soils and stream sediments by weathering The contents of Cd, Pb and As in the raw water of the trunk stream of Tongtian River are 0144, 1762 and 259 μg/L, respectively; while they are 0187, 1998 and 233 μg/L for the raw water of Togton River and 0144,637 and 233 μg/L for the raw water of Nyaga Qu, respectively They are almost one order higher than those for the rest of tributaries, indicating that the contents of Cd, Pb and As have been controlled by geological processBased on calculations, the year outputs of Cd, Pb and As from the Togton River to Tongtian River are 0155, 1647 and 193 t, respectively, while they are 0015, 077 and 035 t from Qumar River to Tongtian River, 0095, 1031 and 272 t from Gar QuBi Qu to Tongtian River and 248, 2907 and 423 t from Tongtian River to Jinsha River, respectively All these show that the Cd geochemical province in the source area of Yangtze River is an important material source of Cd geochemical anomalies along Yangtze River Analytical results of the raw water and the filtered water (by using 045 μm filtering film) indicate that the migrations of Cd and Pb in the water body in the source area of Yangtze River have been mainly in the form of suspended substances, whereas for As it has been in the form of soluble substances

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    Bioavailable phosphorus in sediments in the rivers to the west of the   Taihu lake  and their trophic level, East China
    YUAN Xu-Yin LI Bing HU Wei-Wei CHEN Ying
    2008, 15(5): 212-218. 
    Abstract ( 1407 )   PDF (964KB) ( 714 )  

    The fractions and distribution of bioavailable phosphorus in river sediments were studied in order to identify the trophic level of inflow rivers to the west of Taihu LakeThe nutritive elements in sediments show higher contents in the northern rivers and lower in the southern riversThe contents of bioavailable phosphorus decrease in following order: algal available phosphorus (AAP)>OlsenP(OLP)>water soluble phosphorus(WSP)>readily desorbed phosphorus(RDP)The trophic level increases with the proportion of AAP to total phosphorusThe correlations between AAP and nutritional components show different characteristics for sediments from different regionsAAP is well associated with TN and TP in the northern rivers and with TOM in the middle and southern riversThe bioavailable phosphorus is evidently influenced by pollution sources, and its high content is corresponding to the severe algal bloomIn comparison with river sediments, the lake sediments have higher values of BAP/TP and AAP/TP, which suggests that phosphorus in lake sediments is readily absorbed by hydrophyte

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    The evolution of Cd in sediment of Dongting lake area and its significance based on ARIMA model
    ZHANG Jian-Xin LU Jiang GENG Xu-Dong
    2008, 15(5): 219-226. 
    Abstract ( 2068 )   PDF (1267KB) ( 923 )  

     Based on the study of chronology and geochemistry of Cd in sediments of the Dongting lake area, we have established an ARIMA model of Cd and Cd/Ca in Quaternary and Holocene period respectively, and discussed Cd evolutionary regularity according to the fitted value and predicted value of the model The results revealed that the Cd evolution has remarkable periodicity of ecogeochemistry cycles, and is correlated with the climate change of alternative cold and warm Cd/Ca is changed with climate, from which the evolutionary history of regional ecogeochemistry can be inferred The changes of Cd and Cd/Ca are basically simultaneous, which showed that the change of Cd is mainly a natural evolution Cd in sediments will rise in the next 30 years and then tend to decrease From the regularity of ecogeochemistry indexes and global environment variation, it is concluded that the natural environment is the dominant factor affecting the Cd deposition

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    Influence of dissolved oxygen in overlying water on releasing/absorption of phosphorus from sediments from Suzhou river, east China.
    FENG Hai-Yan LI Wen-Xia YANG Zhong-Fang RUAN Xiao-Gong
    2008, 15(5): 227-234. 
    Abstract ( 1449 )   PDF (1103KB) ( 794 )  

     The influence of different levels of dissolved oxygen (anaerobic, aerobic and natural) in overlying water on the release or absorption of phosphorus from sediment was studied under static state in laboratory without outer input. Through the experiment, we conclude that phosphorus is apt to release from sediment under anaerobic condition (DO<05 mg/L); on the other hand, maintaining higher level of DO (DO>50 mg/L) in water is essential for controlling the release of phosphorus from sediment. Therefore, we should control the quantity of oxygen consumers and increase the level of dissolved oxygen to improve the water quality and to reduce the phosphorus release from sediment.

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    The effective factor of phosphorous release from soil in WaterFluctuationZone of the Three Gorges Reservoir.
    MA Li-Min TANG Yan-Ping TENG Yan-Hang DIAO Jian-Fu
    2008, 15(5): 235-241. 
    Abstract ( 1468 )   PDF (902KB) ( 936 )  

     According to the WaterFluctuationZone (WFZ)s alternately waterlogged and drained environment, we have carried out the experiment for controlling phosphorous release at both laboratory and insitu flooding conditions at Wanzhou with purple alluvial soil of the WFZ at the Three Gorges Reservoir. This study focused on the environmental effective factor of phosphorous release from soil in the WFZ in periodic inundatingdraining environment. Results showed that there was evident change between each phosphorous fraction in concentration during first 510 days, and then the trend became stable. TP of soil decreased, and there was phosphorous release from soil. After several inundatingdraining processes, the OlsenP of soil decreased after each inundating process and increased after each draining process. There was 167% lower of OlsenP at last draining process than that at the beginning. OlsenP of the soil increased from 2053 mg·kg-1 to 4323 mg·kg-1, with a 1106% increase, when the inundating depth increased to 40 m. Phosphorous concentration of overlying water exerted an influence on phosphorous release. Time required to reach adsorption equilibrium was much shorter when phosphorous concentration in overlying water was low (<2 mg/L) than that when phosphorous concentration in overlying water was high (>2 mg/L). It took six weeks to get balance when phosphorous concentration in overlying water was low (<2 mg/L). After adding HgCl2, Phosphorous concentration in overlying water was not changed in first 10 days, and then there was an evident decrease compared to that not adding HgCl2, with 0048 mg/L lower. In addition, the content of OlsenP of soil with plants was higher than that of soil without plantfor soils with Cynodon dactylon and Ficus tikoua  by 215% and 127%.

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     Residues and characteristics of organochlorine pesticides in surface water in the suburb of Beijing.
    CHEN Jia-Wei LIU Chen YANG Zhong-Fang WANG Ji-Yuan
    2008, 15(5): 242-247. 
    Abstract ( 1597 )   PDF (804KB) ( 814 )  

    The organochlorine pesticides (OCPs), such as DDT and HCH, have stable chemical properties and less biodegradability. As a kind of persistent organic pollutants, they have high risk to the environment and human health. Although DDT and HCH have been prohibited in China since 1983, they are still found in some soil and water nowadays. Water resource is very important in natural environment and essential for agriculture. Some past investigations showed that OCPs in some surface water in Beijing have been detected with different levels. In recent years, many measures have been taken to control the pollution and to monitor the environment, and more attention has been paid to the status of the surface water today. In this study, the water samples were collected in Wenyu river, Beiyun river, Yanqing, Fangshan, Changping, and Shunyi rivers in the suburb of Beijing and the residues and characteristics of DDT and HCH were studied. The results showed that the contents of DDTs and HCHs were ND1398 ng/L and 38714642 ng/L, respectively. According to the indicators of the ratio values of (DDD+DDE)/DDT and αHCH/γHCH, the source of pollution and its potential risk are also discussed in this article.

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    Geochemical migration model of heavy metallic elements in ecoenvironmental system of sulfidebearing metallic mines in South China—with specific discussion on Dabaoshan FeCupolymetallic mine, Guangdong Province
    ZHOU Yong-Zhang FU Shan-Meng ZHANG Cheng-Bo YANG Zhi-Jun YANG Xiao-Jiang DANG Zhi CHEN Bing-Hui
    2008, 15(5): 248-255. 
    Abstract ( 2645 )   PDF (1126KB) ( 981 )  

     The Dabaoshan Mine is a sulfidebearing type of FeCuPbZnMo polymetallic deposit in the famous South China metallic deposit belt.It is specifically typical in ecoenvironmental effects of sulfide mine and mining activities in warm and humid area, and is responsible for the presence of the “cancer village” at Shangbacun which is situated in the lower reaches of the mine.Some villagers have suspicious symptom of “ItaiItai disease”.Because of this, the mine attracted much attention of researchers in the field of environmental geochemistry of mines and mining, and the ecological and geochemical migration model of heavy metals was included among the hot topics of discussion.It is shown that there exist four important reaction interfaces, the tailings/water, the water/sediments, the soils/pore water and the soils/plant interface, in releasing and migration of heavy metal elements from mining tailings to destination ecological system, as exampled by element Zn.The tailings/water interface controls the releasing of heavy metals from main source of tailings.The water/sediments interface governs the equilibrium of precipitation and releasing of heavy metallic elements between water and sediments.The soils/pore water interface determines the bioavailability of the soils, while the soils/plant interface is responsible for the absorption and utilization of heavy metallic elements by living beings.The interaction of different media of the four reaction interfaces may be used to describe the geochemical migration model of heavy metallic elements, i.e., the path chain first exposing to the surface from the deposit ores, and then releasing, transporting, transforming and endresulting in surface environment.The migration of heavy metals from mining area makes heavy metals accumulate in areas neighboring the mine and in lower reaches of the mine, resulting in more and more ecological press.The heavy metals migrate to plants and animals through food chain and to human at last, and do harm to ecological safety and life health.The migration can be stopped or prevented through changing the environmental conditions of interfaces, which may help the treatment and prevention of environmental pollution of heavy metals.

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    Spatial variance and pollution analysis of soil heavy metals in Tongling mining area, South China.
    BAI Xiao-Yu YUAN Feng LI Xiang-Ling ZHOU Chao-Fa ZHANG Xin CHEN Xin-Ren CHEN Yong-Ning
    2008, 15(5): 256-263. 
    Abstract ( 2094 )   PDF (1135KB) ( 980 )  

     The paper interprets the spatial variance structure of As, Cd, Hg, Pb and Zn in soil in the Tongling mining area of China, makes spatial interpolation, and analyzes the pollution by using geostatistical method, expecting to provide insight into risk assessment of environmental pollution, soil remedy and decision making. The dataset of soil element contents is derived from project of “Multitarget Regional Geochemical Survey in Jianghuai Drainage Area in Anhui Province” by Anhui Institute of Geological Survey, China. With normalized datasets that are transformed by Johnson transformation, the variogram models are fitted, in which the As and Cd are spherical, Pb and Zn are pentaspherical, and Hg is exponential. The results show that the variograms of As, Cd, Pb and Zn exhibit anisotropy, which possibly is controlled by the distribution of ore deposits; Hg behaves strong nugget effect, which is influenced by smallscale factors, and the further study should increase the sample density. The As, Cd, Pb and Zn in soil in the Tongling mining area have high pollution hazard, especially the Cd; the Hg has low hazard. The pollution of As results from the copper deposits, the leadzinc deposits and limonite, and from their exploitation; the pollution of Cd is related to leadzinc deposits, the exploitation, and agricultural irrigation with waste water; the pollution of Pb and Zn are mostly ascribed to the leadzinc deposits and related exploitation.

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    THE CONCENTRATION OF PGE IN THE EARTHS CRUST WITH SPECIAL REFERENCE TO THE BUSHVELD COMPLEX
    Tony Naldrett Judith Kinnaird Allan Wilson Gordon Chunnett
    2008, 15(5): 264-297. 
    Abstract ( 1723 )   PDF (3449KB) ( 877 )  

    The Earths mantle is the principal reservoir from which platinumgroup element (PGE) concentrations in the crust are derived. The transfer of the PGE is accomplished by two main methods, first the development of mantle partial melts and their intrusion into the crust, and second the emplacement of mantle slabs in the subduction/collision zones. The first mechanism is far more important than the second. Once in the crust, a number of mechanisms serve to concentrate the PGE sufficiently and they can be exploited economically as the principal product, rather than as a byproduct. These include (i) the development of an NiCu sulfide liquid in a mafic intrusion, the concentration of this liquid, followed by cooling and fractional crystallization that results in a residual sulfide liquid highly enriched in Cu, Pt, and Pd; (ii) the formation of layers of very highPGE tenor sulfides at specific horizons within a layered intrusion, either with or without associated chromitite; (iii) the emplacement of magma carrying PGErich sulfide along the margins of layered intrusions; (iv) the delayed separation of immiscible sulfides until the late stages of the differentiation of a layered intrusion; (v) chromite crystallization without the development of sulfide immiscibility; (vi) hydrothermal redistribution and concentration of PGE from zones of low grade disseminated sulfide; (vii) secondary concentration of PGE along with chromite during recrystallization of UralAlaskan intrusions and the subsequent development of placer deposits during the weathering of these bodies; and (viii) the concentration of Pt during the formation of black shale deposits.The Bushveld Igneous Complex of South Africa hosts 75% of the worlds resources of Pt, 54% of Pd resources, and 82% of Rh resources, and contains examples of mineralization formed by processes (ii), (iii), (iv), (v), and (vi) listed a little earlier in the article. Of these, process (ii) accounts for 90% of the current economic reserves and resources, and type (iii) for 9%. The Merensky Reef (32% of total resources) is a PGEenriched horizon that contains 13 thin seams of chromite, and an average of 13 wt% sulfide, across the mining width. The sulfides are thought to have been the principal collectors for PGE. The Reef results from two or more influxes of hot, sulfidebearing, mafic magma that give rise to the horizon. The thickness of the ultramafic cumulates (mainly orthopyroxenite, although includes peridotite in some areas) as a result of these influxes and varies from 50 cm to several meters, although mining is usually focused on a zone that is rarely greater than 1 m in thickness. The genesis of the Reef is still debated, some arguing that the PGE have been concentrated from below by ascending hydrothermal fluids, and others arguing that they have been carried from above by sulfides settling from the magma, giving rise to the Merensky pyroxenites. What is clear is that the pyroxenite, norite, and anorthosite overlying the Reef are composed of minerals derived from two magma types, one rich in MgO (~12 wt%) and Cr and poor in Al2O3 (~12 wt%) and the other with the composition of a typical tholeiite. The UG2 chromitite accounts for 58% of the economic resources, and comprises of a chromitite seam 60 cm1 m thick (sometimes divided by an internal parting of pyroxenite) and 13 overlying thinner seams of chromite. The sulfide content of UG2 is significantly lower that that in the Merensky Reef, ranging from 0.5 to 1.5 wt%, although the sulfides are thought to have played a role in the concentration of at least some of the PGE. There are up to 13 chromitite horizons below that of the UG2, and all contain PGE, although the total PGE contents and the (Pt+Pd)/(Ru+Ir+Os) ratios are much lower than those of UG2. High 87Sr/86Sr ratios found within the pyroxenite “partings” within UG2 suggest that mixing with melted roof rocks may have played a role in causing both chromitite and sulfide to form. The Platreef is the main example of type (iii) mineralization and currently accounts for 9% of the total resources, although active exploration is occurring along this zone and this proportion will probably rise in the future. The Reef is much thicker than the Merensky Reef and UG2, and is currently mined open and cast over a thickness of about 50 m. The Platreef is zoned, ranging from an upper, orthopyroxene cumulate to a lower zone of pyroxenite, feldspathic pyroxenite, and norite that is interacted strongly with shale, iron formation, and dolomite sediments forming the immediate footwall. In this article, it is suggested that the Platreef is the consequence of several surges of magma that were responsible for different units, including the UG2 and Merensky Reef, within the main chamber of the Bushveld. These magmas were displaced and exited up the walls of the chamber in response to new influxes of magma entering the main chamber. Cylindrical, zoned pipes of ultramafic rock containing very high Pt grades cut cumulates in the lower part of the Bushveld complex, and were thought to be the consequence of hydrothermal remobilization. None are currently in production, and they constitute a historic PGE resource that never contributed significantly to the overall resources of the complex.

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    New advances in the study of the Earths deep interior—a glance of the American Geophysical Union Fall Meeting in 2007.
    DIAO Su-Chao JIN Zhen-Min
    2008, 15(5): 298-316. 
    Abstract ( 2000 )   PDF (2221KB) ( 1204 )  

    Recent progress in several aspects in the study on the Earths deep interior are discussed, with reference to the international conference on the American Geophysical Union (AGU) Fall Meeting in 2007.The scientific problems involved vary from the comprehensive testable predictions of geodynamic models to the equation of state theories and experiments, from mantle phase transitions and seismic discontinuities to mechanisms of deep earthquakes, from structure and dynamics of Earths core to volatiles and melts in the Earths interiorAll major fields in the study of Earths deep interior are under discussion.The conference suggests that: (1)The merge interdisciplinary is a major trend in the development of the Earths deep interior study; (2)International cooperation becomes a new highlight in the research of the Earths deep interior sciences; (3)Highly precise technique (modern supercomputers and clusters) is a new way of understanding the Earths deep interior sciences; Chinese geoscientists should pay more attention to the frontiers of Earths deep interior sciences, join the noted international conference and share the advanced knowledge.

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    Arsenicresistant denitrificator isolated from anaerobic activated sludge and its impact on the mobility of ferrihydriteadsorbed arsenic.
    GUO Hua-Meng CHEN Sai LIN Yan
    2008, 15(5): 317-323. 
    Abstract ( 1638 )   PDF (812KB) ( 1077 )  

     Anaerobic activated sludge was used to cultivate arsenicresistant denitrificator in laboratory. The acclimated bacteria were incubated with nutrient solution and Asadsorbing ferrihydrite in anaerobic condition to investigate the geochemical behavior of As adsorbed on ferrihydrite. The concentrations of Fe, Mn, NO-3and As species in suspensions were monitored during the incubation. The acclimation results show that the denitrificator in the anaerobic activated sludge can abide the As(V) in the solution, and its denitrification intensity was less affected by As when its concentration is less than 500 μg/L. In the batch incubation with addition of Asadsorbing ferrihydrite, the presence of arsenicresistant denitrificator caused an increase in concentrations of Fe and Mn, a decrease in concentrations of NO-3 and As, and a high ratio of As(III) to the total As. This indicates that both the reductive dissolution of ferrihydrite and the reductive desorption of As(V) occurred in the batches incubated with arsenicresistant denitrificator and Asadsorbing ferrihydrite. The decrease in As concentration was caused by the readsorption of the released As on the new adsorption sites of the partially dissolved ferrihydrite because of high ratio of ferrihydrite to the solution.

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    The current status and reclamation measures of the solid mine ecological environment in Beijing
    WU Xiong HAN Bing GUAN Qing-Hua ZHANG Shun-Feng GAO Meng-Xian HAN Yong-Qi CHEN Hong-Han
    2008, 15(5): 324-329. 
    Abstract ( 1622 )   PDF (921KB) ( 872 )  

     Solid mine operations surrounding the Beijing metropolitan area present difficult ecological and environmental issues and pose serious future challenges for the citys planning and development. We reviewed the vast body of research work on these issues, studied active mining operations and mine remediation projects in the area, and analyzed the impact on the ecological environment from solid mine resource utilization and exploitation. Based on these studies, we propose both general guidelines and specific measures for rehabilitating and protecting the ecological environment within the framework of relevant laws and regulations, taking into account local climate, soil, hydrology, and geology. It is important that the proposed guidelines and measures balance the need of environmental protection with that of efficient resource exploitation and utilization for the future economic development of the city. Experiences gained in addressing the environmental issues related to mining operations around Beijing may be valuable for other cities facing similar problems.

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    The diurnal pattern of soil water fluxes in subsurface zone and its  simulation analysis.
    CENG Yi-Jian MO Li SU Zhong-Bei Hirotaka Saito WANG Xu-Sheng CAO Wen-Bing
    2008, 15(5): 329-343. 
    Abstract ( 1824 )   PDF (1781KB) ( 1044 )  

    In desert and semidesert areas, vapor movement is often an important part of the total flux since it controls the partitioning of available energy into latent and sensible heat fluxes into the atmosphere. In addition, biological processes such as soil microbial activity and plant growth depend on the moisture and temperature status in the vadose zone, which are mainly influenced by the vapor movement. An experiment, in which the hourly measurements of water vapor flux in the vadose zone were reported, was conducted in a sandfilled bunker at a field site. It was found that the soil moisture reached the daily maximum value (5961  cm3/cm3 at 10 cm and 119131 cm3/cm3 at 30 cm) and minimum value (4445 cm3/cm3 at 10 cm and 104108 cm3/cm3 at 30 cm) at midday (12:0013:00 for 10 cm and 14:0015:00 for 30 cm) and before dawn (02:0003:00 for 10 cm and 04:0005:00 for 30 cm), respectively. The modified HYDRUS1D code, which refers to the coupled water, vapor and heat transport in soil, was used to develop a deeper understanding of the physical processes of soil water dynamics in this experiment. The numerical analyses provided insight into the diurnal movement of liquid water and water vapor driven by the gradients of pressure heads and temperatures in the subsurface zone. The simulated temperature and water content were in good agreement with the measured values. The spatialtemporal distribution of liquid water flux, of water vapor flux and of soil temperature showed a detailed diurnal pattern of soil water dynamics in relatively coarse sand.

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    The effect of groundwater level on the vegetation  from the mixture of distributions in Yinchuan plain, northwest China.
    SUN Xian-Chun JIN Xiao-Mei MO Li
    2008, 15(5): 344-348. 
    Abstract ( 1809 )   PDF (635KB) ( 868 )  

     The condition of natural ecoenvironment in Yinchuan plain located in the arid northwestern area is typical in China.MODIS NDVI is one of the important indexes that represent the condition of natural ecoenvironment,which is influenced by various factors. Groundwater is the most important one among the factors,but it is difficult to make full use of data concerning groundwater to establish a mathematical model and to draw a quantitative conclusion.Currently,the study on the mixture of distributions has received widespread attention,but the reliable estimation of the parameters in the mixture of distributions is quite difficult.A method, based on the relation between the mixture of distributions and the histogram of data, and using least squares to estimate the parameters, is introduced in this paper.The relation between groundwater and vegetation in Yinchuan Plain is discussed on the basis of the new method, using MODIS NDVI and groundwater monitoring data.The normal distribution of the effect of groundwater on vegetation in Yinchuan plain is founded.

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    Geological attributes and conditions of hydrocarbon accumulation of Cambrian folds in the southern Yingmaili swell,Tarim basin.
    ZHANG Chao-Jun WANG Chang-Xun LUO Xiu-Hu LIU Yun-Xiang ZHANG Jian-Liang JU Ke-Yuan
    2008, 15(5): 349-356. 
    Abstract ( 2383 )   PDF (1506KB) ( 1012 )  

     Traditionally,the Cambrian abnormal bodies in the southern Yingmaili swell were considered to be the reflections of MiddleCambrian salt tectonics. However, we found that there are multiple options to explain these large anomalous bodies. It is possible that the carbonate buildups exist in the main part of the folded structures and were thickened by the latter faults and formed large overlying composite folds. Faults and cracks are extremely developed inside the Cambrian folds and can greatly improve Cambrian dolomitite reservoir properties. They are very conducive to the oil and gas accumulation. The basement rifts can connect effectively with oil source, and the MiddleCambrian shale or mudstone can form good capping formations that are well closed. A comprehensive analysis on the southern Yingmaili area indicates that the Cambrian largescale fold structures possess favorable conditions for hydrocarbon accumulation and storage, and are favorable for forming large and mediumscale oil and gas fields. The Cambrian carbonatite buildup will be one of the new hydrocarbon exploration potential fields in the Tarim basin.

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    Study and application of carbon isotope fractionation during the reduction process from CO2 to CH4
    LI Jin HU Guo-Yi ZHANG Yang YANG Gui-Fang CUI Hui-Yang CAO Hong-Meng HU Xu-Long
    2008, 15(5): 357-363. 
    Abstract ( 2091 )   PDF (1092KB) ( 916 )  

     The CO2 reducted to CH4 pathway is important to biogas generation in the geological historyThe Quaternary biogenic gas fields in Qaidam Basin of China belongs to the CO2/H2 reduction biogenic gasAccording to the theory of H2/CO2 reduction, we have carried out the biosimulation experiments with different occurrences and different initial carbon isotope values of carbon sourcesThe experimental results indicated that there is a positive correlation between the δ13Cmethane values and the δ13C values of the substrate in products, and that,  in response to the existence of excessive substrate, the occurrence of substrate has its effect on the δ13Cmethane valuesThe δ13Cmethane values from free CO2 reducted to CH4 is relatively lower than that coming from HCO-3 and CO2-3 ionsBy applying to the Quaternary biogenic gas filed in the east of Qaidam Basin, the source and occurrences of the main substrate CO2 are discussed, and these have import reference value for evaluating the biogas resources and searching for favorable exploration ares

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    The control of tectonic thermal events on the concentration of high coalrank coalbed methane
    WANG Gong-Yan MO Tian-Feng LI Jing-Meng DIAO Qun
    2008, 15(5): 364-369. 
    Abstract ( 2089 )   PDF (903KB) ( 1584 )  

     China high coalrank coalbed methane basins have undergone multiphase of tectonic activity, which makes the high coalrank coalbed methane reservoirs of peculiar complexity. By the research on  the high coalrank coalbed methane reservoir of the Qinshui basin including the study of the coalbed thermal evolution level, the temperature and pressure of inclusion in calcite or quartz reef in coalbearing strata, the palaeogeothermal analysis of the fission track of apatite and zircon, the anogenic isotopic age, and the geothermal flux caused by magmatic activity, we have proved the existence of the tectonic thermal event. It is found from the experimental analysis of coal thermal decomposition that the high temperature and high pressure of the reservoir environment caused by the tectonic thermal event accelerates the hydrocarbon production in the coalbed, and raises the coal adsorptive capability, which make the gas content in the Qinshui basin 513 m3/t higher than that in the Black Warrior basin. Moreover, the change in temperature caused by the igneous intrusion is one of the reasons for the undersaturation of the gas content in the Qinshui basin, and the high temperature and high pressure of the reservoir environment improve the coal permeability. 

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     SAR monitoring of nowaday deformation in the eastern segment of the Altyn Tagh Fault
    DING Xian-Wen CHEN Han-Lin ZHANG Wei
    2008, 15(5): 370-375. 
    Abstract ( 1871 )   PDF (1052KB) ( 811 )  

    In recent years, the differential Interferometric Synthetic Aperture Radar (DInSAR) technique has been widely used in the earths surface deformation monitoring, including the displacements caused by earthquake, volcano activity, glacier movement, ground subsidence, active fault and landslides Compared with the conventional approaches (such as GPS monitoring), applying the DInSAR technique has many advantages in surface deformation monitoring Firstly, the SAR satellite works all the time, and it is not affected by climatic changes Secondly, the spatial resolution is high Thirdly, the images can cover a large area on the earth Finally, the continuous displacement information of the ground can be achieved In this paper, the DInSAR technique is used to study the tectonic deformation characteristics of the eastern segment of the Altyn Tagh Fault, which is an important crustal deformation boundary on the northeastern margin of the Tibetan Plateau To the north of this boundary, the surface deformation is weak and uniform, while to the south it is strong but not uniform From the western part to the eastern part of this area, the deformation intensity gradually decreases Between these two parts there is the western part of the North Qilianshan Fault, where the minimum deformation intensity is about 10 cm In addition, there exist two linear intensive deformation belts in the southern area One is in N65 W direction, which is in accordance with the direction of the secondary compressionshear plane of the Altyn Tagh strikeslip fault zone The other is in a roughly NW direction, which is consistent with the trend of the western part of the North Qilianshan Fault

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    The kinematic vorticity and strain rate of XiaotianMozitan fault and their tectonic significance
    WANG Yong-Sheng SHU Guang XIANG Bi-Wei WEI Xin
    2008, 15(5): 376-387. 
    Abstract ( 1670 )   PDF (1782KB) ( 788 )  

     As the boundary between the north Huaiyang unit and the North Dabie complex unit, the XiaotianMozitan fault is a very important exhumation channel Based on the detailed field survey, the estimation of temperature and pressure during the mylonitization, and the measurement of quartz Caxis fabrics, we calculate the kinematic vorticity numbers and strain rate during the synorogen mylonitization of the XiaotianMozitan fault The mylonites formed in the depth of 3040 km as indicated by the temperature and pressure of the deformation, which is more than the amount of denudation since the Cretaceous and suggests that the mylonitization was formed in the exhumation of the Dabie orogenic belts The kinematic vorticities are all more than 09, which indicates that the deformation was mainly the simple shear The XiaotianMozitan fault is a fault with shear sense of toptotheNW as shown by microstructures and quartz Caxis fabrics The strain rate of the synorogen mylonitization is about 10-10  s-1, which suggests that the exhumation rate is very high after the peak metamorphism in the Dabie orogenic belts

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     Analysis of heavy minerals in sediments of Jiuxi basin in north margin of the Tibet plateau in 4030 Ma and its tectonic implication
    DAN Bei WANG Cheng-Shan SHU Li-Dong CAO Ke YAN Bao-Nian HONG Man-Fu
    2008, 15(5): 388-398. 
    Abstract ( 2199 )   PDF (1455KB) ( 3738 )  

    The sediments in an orogen contain very rich tectonic information The Jiuxi basin, located in the triangular belt between Altyn Tagh Fault(ATF) and North Qilian Fault(NQF), was affected by strong active tectonics in the early Cenozoic; therefore, it was covered by mass sediments which could reflect the tectonic actions and uplift process nearby The assemblage, texture and sensitive index (ATi, GZi and ZTR) of the sedimental heavy minerals show regular variations in the Huoshaogou and Hongliuxia sections of Jiuxi basin in 4030 Ma The detailed study of the heavy mineral has revealed four different stages: ①the unstable mineral stage (Shanmacheng segment, 402379 Ma); ②the stable mineral stage (Qiaojia segment, 379353 Ma); ③the unstable mineral stage (Hongliuxia segment, 353334 Ma); ④the extra unstable mineral stage (Baiyanghe Formation, 33430 Ma) In addition, the detailed analysis of heavy mineral characteristics and sedimentary characteristics shows that there should be four different tectonic stages in the Jiuxi basin between 40 and 30 Ma: ①the strong tectonic stage (402379 Ma); ②the stable tectonic stage (379353 Ma); ③the thrusting and striking stage (353334 Ma); ④the strong thrusting stage (33430 Ma)

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