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    2018, Volume 25 Issue 5
    15 September 2018
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    Detrital zircon U-Pb ages of the Sijizhuang glacial diamictites of the Hutuo Group in Wutai Shan, Shanxi Province and implication for the Great Oxidation Event
    CHEN Weiyu,CHEN Yanjing,LI Qiugen,LI Jianrong,LI Kaiyue,SHU Sunping,CHEN Xi,TONG Zida
    2018, 25(5): 1-18. 
    DOI: 10.13745/j.esf.sf.2018.4.12

    Abstract ( 513 )   PDF (16871KB) ( 545 )  
    The metamorphosed diamictite in the Sijizhuang Formation of the Hutuo group in Shanxi Province shows the characteristics of a polymictic origin. They are barely sorted, poorly rounded, and with striated and faceted clasts and dropstone structures, suggesting a glaciomarine environment during the Paleoproterozoic glaciation in the North China Craton. Our research show that the U-Pb ages of detrital zircons from different lithofacies sediments of the Sijizhuang Formation peaked at around 2.5 Ga. The youngest zircons from two diamictite samples from the lower portion of the Sijizhuang Formation yielded the youngest concordant ages of 2440±40 and 2400±23 Ma, respectively, and sandstone from the upper layer of the Sijizhuang Formation yielded a youngest concordant age of 2121±22 Ma. Thus the detrital zircon U-Pb ages  constrain the glaciation in Wutai Shan to be between 2.4 and 2.1 Ga, i.e., the time of  the HGE (Huronian Glaciation Event). However, the youngest zircon age of 2.1 Ga suggests that the glaciation in North China Craton did not end until 2.1 Ga. The Sijizhuang Formation was not deposited from mountain glacier but on a continental margin. The Dashiling Formation above the Sijizhuang Formation was deposited during 2.12 to 2.08 Ga, showing positive carbonate carbon isotopic excursion that coincided with the global positive carbon isotopic excursion event (LJE: Lomagundi-Jatuli Event). The record of red beds in the Qingshicun Formation occurred about 2.08 Ga, coinciding with the beginning of global evolution of red beds. Thus, the Hutuo Group in the North China Craton records a complete sequence of the Great Oxidation Event.
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     Carbon isotope compositions and geochemical characteristics of the Zhangshe graphite deposit of the Jingshan Group, Jiaobei.
    LI Kaiyue,CHEN Yanjing,SHE Zhenbing,TANG Haoshu,CHEN Weiyu
    2018, 25(5): 19-33. 
    DOI: 10.13745/j.esf.sf.2018.4.11

    Abstract ( 294 )   PDF (7600KB) ( 406 )  
    Graphite deposits in China are widely distributed in ore-bearing khondalite series around the North China Craton. The massive accumulation of graphite deposits from multiple sources has significant implications for the palaeoenvironment. Here, our compilation of previously published isotopic ages for the Jingshan Group suggests a depositional age of 2.11.9 Ga. We also report new geochemical data, including major elemental and C/O isotope data, and Raman characteristic frequencies for graphite ore and related rocks from the Douya Formation, Jingshan Group in the Zhangshe mining area. The δ13Cgrap values of 8 gneiss samples ranged from -18.6‰-21.7‰, with an average of -20.7‰±0.8‰. The δ13Cgrap values for two diopside marbles were -16.3‰ and -19.3‰, respectively. All the δ13Cgrap values were slightly lower than the average (-26‰±7‰) for the worlds organic matter. The δ13Ccarb and δ18Ocarb values of four diopside marbles were -8.9‰0.2‰ and 12.5‰16.6‰, respectively. Raman microspectroscopy of graphites showed that the highest rock temperature reached 700800 ℃. The above mentioned geochemical characteristics indicate the carbon source of graphite mainly came from organic matter that subsequently mixed with inorganic carbon (homogenization) to yield heavier carbon isotopes. And high temperature metamorphism and fluid influence likely contributed to carbon homogenization. The occurrence of large amounts of graphite deposits in the Paleoproterozoic, accompanied by stromatolite expansion, accumulation of phosphorite deposits and perturbation of marine carbon cycles, suggests a flourishing of marine microbial life and high rates of biological productivity and carbon burial during this period.
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    The 1.331.30 Ga mafic large igneous province and REE-Nb metallogenic event in the northern North China Craton.
    ZHANG Shuanhong,ZHAO Yue
    2018, 25(5): 34-50. 
    DOI: 10.13745/j.esf.sf.2018.4.7

    Abstract ( 366 )   PDF (7777KB) ( 583 )  
    The Yanliao rift zone in the northern North China Craton is associated with the emplacement of large volumes of diabase sills within the Mesoproterozoic Xiamaling, Wumishan, Gaoyuzhuang and Tieling formations. In this study, detailed field investigation and geological cross-section measurements show that the sills are distributed over an area of >1.2×105 km2  with cumulative thickness of 50 to >1800 m. A tabulation of 18 published baddeleyite 207Pb/206Pb ages of diabase emplaced into different lithospheric layers, including the Xiamaling, Wumishan, Gaoyuzhuang and Tieling formations, shows that sill emplacement occurred between 1.33 and 1.30 Ga with a peak age of ca. 1.32 Ga. The Yanliao diabase sills exhibit similar geochemical features of tholeiitic composition with intraplate characteristics. Given its vast areal and volumetric extents and relatively short duration of emplacement, along with the intraplate setting, the diabase sill province of the Yanliao area constitutes a mid-Mesoproterozoic large igneous province (LIP) in the North China Craton, which we named here the Yanliao LIP. Emplacement of the Yanliao LIP was accompanied by pre-magmatic uplift that started at about 1.35 to 1.34 Ga, as indicated by the disconformity between the Changlongshan and Xiamaling formations. Among the globally known LIPs, the Yanliao LIP of the northern North China Craton bears clear similarities to the 13.2 Ga DerimGaliwinku LIP of the North Australian Craton in terms of age, occurrence, petrographical assemblage and geochemical compositions. Moreover, compositions and ages of the late Paleo-Mesoproterozoic stratigraphic units in two cratons are also very similar,  as exemplified by the top stratigraphic horizons that are intruded by the diabase sills and are both dominated by black shales (Xiamaling Formation in Yanliao area and Velkerri Formation of Roper Group in Northern Austarlia). These similarities indicate the two cratons were connected (or close neighbors at least) during the mid-Mesoproterozoic period, and the Yanliao and DerimGaliwinku LIPs are the fragments of the same LIP. Field investigations and zircon Th-Pb dating show that the REE-Nb-rich carbonatites in the Bayan Obo deposit occur mainly as sills emplaced at ca. 1.30 Ga. Zircon morphology and analyses of trace elemental composition and mineral inclusion demonstrate that crystallization of the 1.30 Ga carbonatite sills in the Bayan Obo deposit was accompanied by large-scale REE-Nb mineralization. Therefore, the Bayan Obo carbonatites and REE-Nb deposit are thought to be spatially and temporally linked with the 1.331.30 Ga Yanliao LIP in the northern North China Craton, and their formations were likely related to the continental rifting and breakup of the North China Craton from the Columbia (Nuna) supercontinent.
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    Geochemical characteristics and petrogenesis of Devonian magmatic rocks in the Kalatag district, eastern Tianshan, NW China.
    CHEN Lei,WANG Jingbin,DENG Xiaohua,WU Xiangbin,ZOU Haiyang,SUN Yan,XU Jun,ZHANG Wendong
    2018, 25(5): 51-68. 
    DOI: 10.13745/j.esf.sf.2018.4.14

    Abstract ( 176 )   PDF (6312KB) ( 367 )  
    We conducted  petrologic investigation and performed major and trace elemental and Sr-Nd isotopic analysis on magmatic rocks from the Kalatag district, eastern Tianshan in order to understand the petrogenesis and geodynamic setting of Devonian magmatic rocks. The results show that Devonian magmatic rocks were mainly composed of intermediate-basic rocks including gabbro, diorite, quartz diorite, monzonite and andesite. Gabbro was calc-alkaline to tholeiitic with high Al2O3 content (18.96%19.06%) and Mg# value (57.2869.37), yielding A/CNK value of 0.730.88. Diorite, quartz diorite, monzonite and andesite were calc-alkaline to high-K calc-alkaline with high Al2O3 contents (15.02%17.43%) and Mg# values (53.6772.91), and A/CNK values of 0.731.17. Sr-Nd isotopic analysis yielded positive εNd(t) values ranging from 5.36 to 7.72 with low initial 87Sr/86Sr ratios of 0.70311 to 0.70518. Devonian magmatic rocks were enriched in large ion lithophile elements (Rb, Ba and K) while depleted in high field strength elements (Ta, Nb and Ti). These geochemical characteristics indicate that Devonian magmatic rocks were derived from the same magma chamber with an enriched mantle wedge metasomatized by subduction slab fluid and emplaced in an island arc setting during the northward subduction of the Kanggur Ocean.
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    A study of the occurrences of gold and silver in the massive sulfide deposit in the Kalatag region, NW China
    LI Yao,DENG Xiaohua,WU Yanshuang,YUE Suwei,LIN Zhenwen,YANG Liya,CHEN Xi,XU Jun
    2018, 25(5): 69-82. 
    DOI: 10.13745/j.esf.sf.2018.4.16

    Abstract ( 289 )   PDF (16471KB) ( 253 )  
    The Kalatag region in eastern Tianshan, NW China contains a number of economically important Cu deposits, including the HonghaiHuangtupo VMS-type Cu-Zn deposit hosted in the volcanicsedimentary rocks of the Late Ordovician to Early Silurian Daliugou Formation. The characteristic dualistic structure of the Cu-Zn deposit features  concordant massive sulfide and discordant vein-type ores in the footwall strata. The massive auriferous sulfide ores consist of pyritechalcopyrite, pyritechalcopyritesphalerite, pyritesphaleritechalcopyrite and sphalerite. Based on detailed mineragraphic analysis of various kinds of auriferous sulfide ores, and combined with scanning electron microscope and energy dispersive spectrometer hyphenated techniques (SEM/EDS), we clarified that the principle ore minerals are pyrite, chalcopyrite and sphalerite, while tetrahedrite, galena and pyrrhotite occur in minor quantities; gangue minerals are mainly quartz, sericite and barite with lesser chlorite, plagioclase and carbonate. Mineralization of the Honghai deposit can be divided into three periods: VMS mineralization, hydrothermal overlapping and supergene periods. The VMS mineralization period can be further subdivided into pyrite, sphaleritechalcopyrite-tetrahedritegalena and quartzbarite stages. Four grains of natural gold and silver metallic mineral were found in this deposit for the first time, their very different chemical contents inferred that the hydrothermal environment went through a transformation from intermediateacid to alkalescent, which benefited Au and Ag transport. Au and Ag were activated and re-enriched through metasomatism of minerals formed in the VMS mineralization period, by the late alkalescent hydrothermal solution. Through metasomatism, Au and Ag mineralization occurred not only in the intermediatehypothermal sphaleritechalcopyrite stage of the late VMS mineralization period, but also in the intermediatehyperthermal pyrite stage of the early VMS mineralization as well as the whole hydrothermal overlapping periods. In all mineral assemblages, except the four mineral grains, Au and Ag could not be observed under the electron microscope, which may illustrate that Au and Ag in this deposit mainly occur as constituents of the crystal lattice of host minerals.
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    Fluid inclusions and zircon U-Pb age characteristics and their significance for the Xiaoyuzan gold deposit in Western Tianshan
    YU Jie,LI Nuo,ZHANG Bo,SHU Sunping,CHEN Yanjing
    2018, 25(5): 83-95. 
    DOI: 10.13745/j.esf.sf.2018.4.15

    Abstract ( 228 )   PDF (12060KB) ( 337 )  
    Xiaoyuzan gold deposit is an epithermal deposit in the Yeliemodun basin in Western Tianshan, Xinjiang Province. The ore bodies are hosted by volcanic rocks of the Late Paleozoic Dahalajunshan Formation and mainly consist of altered tuff and quartz veins. The hydrothermal alterations include intense silicification, beresitization, illitization and propylitization. The ore-forming process can be divided into three stages: quartzpyrite, quartzchalcedonypyrite and quartzcarbonatepyrite. Hydrothermal quartz from the three stages contains only aqueous fluid inclusions of liquid-rich, vapor-rich and pure liquid types, respectively. Fluid inclusions in the three stages were homogenized in temperatures of 130190, 115161 and 110138 ℃, respectively, with salinities of 0.188.0, 0.703.4 and 0.183.4 wt.% NaCl equivalent, respectively. Homogenization temperatures decreased from early to late stages implying the presence of fluid boiling. LA-ICP-MS U-Pb dating of zircons from tuff breccia yielded an Early Carboniferous age (weighted average) of 353.8±1.8 Ma, while the ore bodies were covered by the Aqialehe Formation constraining the age of deposit between 353.8±1.8 Ma and Visean age. The positive zircon εHf(t) values (4.18.4) and young two-stage Hf model ages (TDM2, 8221095 Ma) suggest a minor juvenile continental crustal involvement. Based on geological evidence including geological and fluid inclusion characteristics and mineralization age of the deposit, we propose that the Xiaoyuzan gold deposit is an LS type epithermal deposit formed in the Early Carboniferous.
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    Geochemistry, geochronology and oxygen fugacity of volcanic and intrusive rocks from the Laoshankou Fe-Cu-Au deposit in the northern margin of East Junggar, NW China.
    LIANG Pei,CHEN Huayong,WU Chao,LIU Zhenjiang
    2018, 25(5): 96-118. 
    DOI: 10.13745/j.esf.sf.2018.4.2

    Abstract ( 227 )   PDF (19356KB) ( 394 )  
    The Laoshankou deposit is an important Fe-Cu-Au deposit in the northern margin of the East Junggar, NW China. LA-ICP-MS U-Pb dating of zircon constrains the timing of crystallization of Ordovician basaltic andesite (~449 Ma), Ordovician andesite (~447 Ma), Devonian volcanic rocks (393376 Ma), monzodiorite (~379 Ma), biotite diorites (~379 Ma), quartz syenites (~376 Ma), fine-grained diorite (~370 Ma), alkali granite (~330 Ma) and coarse-grained diorite porphyry (~310 Ma). Zircon dating indicates three periods of magmatism in Laoshankou: 450440 Ma, ~390370 Ma and 330310 Ma. The magmatism for the first two periods occurred in a subduction-related island arc setting; the magmatism for the last one occurred in a post-collision or inplate extensive setting. Pre-, syn- and post-mineralization volcanic and intrusive rocks are divided based on the Fe-Cu-Au mineralization timing. Syn-mineralization intrusions in Laoshankou have relatively high (Eu/Eu*)N, (Ce/Ce*)N and CeIV/CeIII values of 0.130.86, 1.14445.92 and 33.341165.04, respectively, indicating Fe-Cu-Au mineralization was associated with high oxygen fugacity magmatism.
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    Zircon U-Pb age, geochemistry and Hf isotopes of the causative porphyry from the Bilihe porphyry gold deposit, Inner Mongolia.
    ZHU Xuefeng,CHEN Yanjing,WANG Pin,ZHANG Cheng,CAI Yunlong,DENG Ke,XU Qiangwei,LI Kaiyue
    2018, 25(5): 119-134. 
    DOI: 10.13745/j.esf.sf.2018.4.18

    Abstract ( 264 )   PDF (5826KB) ( 414 )  
    The Bilihe gold deposit, located in the Bainaimiao arc along the northern margin of the North China Craton (NCC), is considered a porphyry mineralization system. This study is focused on the LA-ICP-MS U-Pb geochronology and Lu-Hf isotopic composition of zircons from the causative granodiorite. The results show that geochemical features, such as peraluminous high-K calc-alkaline characteristics, SiO2 content (61.3%64.4%), ratios of K2O/Na2O (0.520.87) and A/CNK (0.820.95), enrichment of LILEs (eg. Rb, U, Th) and LREEs, depletion of HFSEs (eg. Nb, Ta, Ti) and HREEs, and negative Eu anomalies (δEu=0.501.03), indicate the Bilihe granodiorite is similar to typical arc-related granitoids. Also, two granodiorite samples (zk086-53 and zkI005-105) had similar zircon ages and Lu-Hf isotopic characteristics, with weighted mean 206Pb/238U ages of 268.1±1.8 Ma (MSWD=1.17, 1σ) and 267.7±4.1 Ma (MSWD=1.06, 1σ), respectively,  εHf(t) values of 3.28.7 and -0.68.3, respectively, and TDM2 ages of 1085737 Ma and 1330762 Ma, respectively, suggesting that the Bilihe causative granodiorite likely formed during the EarlyMiddle Permian, from the underplating magma of partially molten juvenile crust mixed with partially molten ancient basement rocks in a continental arc setting.
    Key words: Central Asian orogenic belt; Solonker zone; Bilihe gold deposit; zircon U-Pb ages; Lu-Hf isotopes
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    Geological characteristics and ore minerals of the Taldybulak Levoberezhny gold deposit, Kyrgyzstan.
    XI Wei,XIA Xiaohong,WU Yanshuang,YE Tian,LI Nuo
    2018, 25(5): 135-150. 
    DOI: 10.13745/j.esf.sf.2018.4.9

    Abstract ( 547 )   PDF (10282KB) ( 483 )  
    The Taldybulak Levoberezhny deposit (130 t@6.9 g/t) is the third largest gold deposit in northern Tienshan, Kyrgyz. Since its discovery in 1963, no detailed mineralogical studies has been done, especially on ore minerals in the deposit. The ore genesis is still under debate over the proposed origins including porphyry, orogenic or multi-stage overprint. In this contribution, through detailed field survey and petrographic observation, we discovered that gold mineralization was mainly controlled by both shear zones and later intrusion with ore bodies parallel to the strata. The ores can be divided into at least five types according to texture and composition: dissemination-stockwork (hosted in intrusions such as monzogranite), quartz-tourmaline-sulfide, massive ores, dissemination (hosted in altered metamorphic rocks) and calcite-sulfide vein types. Related hydrothermal alterations are dominated by silicic, sericite, tourmaline and calcite alterations with minor chlorite and epidote alterations or argillation. Electron microprobe analysis (EMPA) revealed both visible and invisible gold in the ores. The visible gold includes electrum (Au: 67.90%80.86%; Ag: 14.24%30.76%) and silver-bearing native gold (Au: 88.95%; Ag: 8.09%), and occur as micro-mineral inclusions enclosed in pyrite or distributed along pyrite boundaries or fractures, while the invisible gold resides in pyrite or chalcopyrite containing 0.16%0.33% Au. Pyrite from different types of ores display variable morphology, texture and composition. In the dissemination-stockwork ores hosted in monzogranite, pyrite generally occurs as medium-coarse sized (301300 μm, mostly >200 μm) subhedral to euhedral cubic grains;  it may contain native gold, electrum or silicate inclusions, with little or no cracks; commonly, moderate amounts of As (0.03%1.72%, averaging 0.66%), Co (0.06%0.19%, averaging 0.13%) and Te (0.03%0.06%, averaging 0.04%), with moderate As/S, Fe/S and Co/As ratios and limited Cu, Pb, Zn and Ag are present. In the quartz-tourmaline-sulfide ores, the medium-coarse sized (302000 μm) subhedral to anhedral pyrite are often fractured and replaced by minerals such as chalcopyrite or galena; some grains may also contain electrum or silicate as inclusions; and it is generally embedded with high concentrations of As (0.05%2.05%, averaging 0.97%) and Co (0.05%0.34%, averaging 0.15%), and has high As/S and Fe/S but low Co/As ratios. In the massive ores, pyrite also has the subhedral to anhedral texture, although grain sizes vary greatly from 30300 μm to 2503300 μm; the pyrite composition is characterized by high contents of As (0.05%2.20%, averaging 1.21%) and Te (0.04%0.09%, averaging 0.06%), high ratios of As/S and Fe/S, but low ratio of Co/As. In the disseminated ores hosted by altered metamorphic rocks, pyrite grains are medium sized (mainly 50200 μm) with subhedral to anhedral texture, and contain some inclusions (e.g. sulfide, silicate, native gold or electrum) or fractures; their compositions vary greatly, although as a whole the Co content (0.08%1.04%, averaging 0.35%) and Co/As ratio are high, but no Te, Cu and Zn. In calcitesulfide veins, pyrite occurs as medium-coarse sized (40480 μm) subhedralanhedral grains, and may contain silicate inclusions; it is typified by ultra low As (0.04%0.08%, averaging 0.06%) and Co (0.04%0.20%, average 0.10%) contents and As/S and Fe/S ratios, but high Co/As ratio; it does not contain any detectable Zn. Based on pyrite ore-controlling structures, mineralization types, wallrock alterations, and variable structural chemical features, we propose that the Taldybulak Levoberezhny gold deposit may be formed by multi-stage superimposed mineralization.
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    Study of fluid inclusions and ore genetic type of the Changlingzi deposit, Keshiketeng County, Inner Mongolia
    XU Qiangwei,WANG Pin,ZHONG Jun,WANG Chengming,ZHENG Yi,FANG Jing
    2018, 25(5): 151-166. 
    DOI: 10.13745/j.esf.yx.2018-3-40

    Abstract ( 210 )   PDF (5920KB) ( 326 )  
    The Changlingzi Pb-Zn deposit in Keshiketeng County, Inner Mongolia, China, was recently discovered in the southern Great Hinggan Range. Ore bodies occur as veins in the Early Permian Dashizhai Formation with skarn alteration. The Early Permian Dashizhai Formation consists of marine intermediate-acid volcanic rocks and spilites interbeded with sandstones and slates. Based on the mineral assemblages and crosscutting relations of vein lets, the mineralization process can be divided into four stages (from early to late): the dry skarn stage, wet skarnmagnetite stage, quartzsulfide stage and quartzcarbonate stage characterized by the mineral assemblages of garnet±diopside±wollastonite, quartz+epidote+tourmaline+magnetite, quartz+pyrite±pyrrhotite±chalcopyrite±galena±sphalerite, and quartz±calcite, respectively. Two types of fluid inclusions (FIs), including aqueous (W-type) and daughter mineral-bearing polyphase (S-type) fluid inclusions, occur in the Changlingzi deposit. And the W-type can be subdivided into the liquid-rich (WL-type) and vapor-rich (WV-type) types. The diopside grains contain S- and WL-type FIs. The epidote and quartz grains of the wet skarnmagnetite stage contain WL-, WV- and S-type FIs. Quartzes of the quartzsulfide stage include all types of FIs. Only WL-type FIs are present in the quartzcarbonate stage quartz±calcite veins. FIs in the diopside were homogenized at 387524 ℃, with salinities ranging from 10.7 to 52 wt.%(NaCleqv.). FIs of the wet skarnmagnetite, quartzsulfides and quartzcarbonate stages attained homogenization temperatures of 312533 ℃, 182329 ℃, 124199 ℃ and salinities of 11.360, 4.738 and  3.122.4 wt.%(NaCleqv.), respectively. The above characteristics of ore geology and ore-forming fluids indicated that the Changlingzi Pb-Zn deposit is a typical skarn-type deposit. The ore-forming fluids experienced an evolutionary transformation from the high-temperature, high-salinity magmatic fluids of the skarn stage to the low-temperature, low-salinity meteoric waters of the quartzcarbonate stage. The occurrence of ebullition in the quartzsulfide stage was recognized as an important mechanism for ore-metals precipitation.
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    Mineralogical characteristics and ore-forming physicochemical conditions of the Sankuanggou skarn Fe-Cu deposit, Heilongjiang Province.
    DENG Ke,CHEN Yanjing,ZHANG Cheng,XU Qiangwei,ZHU Xuefeng
    2018, 25(5): 167-182. 
    DOI: 10.13745/j.esf.sf.2018.4.4

    Abstract ( 241 )   PDF (14304KB) ( 496 )  
    The Sankuanggou skarn Fe-Cu deposit is located in the Duobaoshan metallogenic belt of the northern Greater Khingan Range, Heilongjiang Province. The ore bodies occur in the garnet skarns of the contact zones between the Yanshanian granodiorite and the Ordovician Duobaoshan Formation marble. As indicated by mineral assemblage and interaction, the hydrothermal ore-forming process included the prograde skarn, retrograde skarn and quartzsulfide stages. Iron oxides and copper sulfides were mainly formed in the retrograde skarn and quartzsulfide stages, respectively. Electron microprobe analysis showed that garnets are made of andradite and grossularite; pyroxenes consist of diopside and hedenbergite; amphiboles belong to calciferous amphibole; chlorites are trioctahedral Fe-chlorite; and the mineral assemblage in the Sankuanggou Fe-Cu deposit is a typical calcareous skarn system. Garnets present as early coarse-grained grossularite (Grt-Ia) and andradite (Grt-Ib), and late fine-grained andradite veins (Grt-Ⅱ). Skarns formed under high temperature and weak acidic and oxidizing conditions. Retrograde skarnization led to  decreased temperature and higher pH resulting in magnetite and specularite deposit, while chalcopyrite and other sulfides precipitated due to decreased oxygen fugacity and temperature following retrograde skarnization.
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    LA-ICP-MS cassiterite and zircon U-Pb ages of the Weilasituo tin-polymetallic deposit in the southern Great Xing an Range and their geological significance
    LIU Ruilin,WU Guang,LI Tiegang,CHEN Gongzheng,WU Liwen,ZHANG Peichun,ZHANG Tong,JIANG Biao,LIU Wenyuan
    2018, 25(5): 183-201. 
    DOI: 10.13745/j.esf.sf.2018.4.1

    Abstract ( 424 )   PDF (14908KB) ( 393 )  
    The Weilasituo tin-polymetallic deposit, located in Hexigten Banner of Inner Mongolia, is a newly discovered large tin deposit associated with tungsten, zinc, copper, molybdenum, rubidium, niobium and tantalum the west slope of the southern Great Xingan Range. Three types of mineralization developed in the deposit: the deep section altered granite-type orebody is dominated by Sn and associated with Zn, Rb, Nb; the middle section cryptoexplosive breccia-type orebody is mainly of Sn with Cu and Zn; and the shallow section comprises quartz vein-type Sn, W, Zn, Cu, and Mo ore bodies. The quartz vein-type ore bodies are the most economically valuable ores, they are hosted within the NNE-trending shattered fault zones of the Paleoproterozoic Baoyintu Group and Middle Variscan quartz diorite, whereas the altered granite- and cryptoexplosive breccia-type ore bodies are usually low grade ores. A cassiterite sample from the quartz vein-type Sn ore of the Weilasituo deposit was selected for LA-ICP-MS dating, which yielded a 206Pb/207Pb238U/207Pb isochron age of 136.0±6.1 Ma (MSWD=0.94) and a 207Pb/206Pb238U/206Pb concordant age of 132.3±5.4 Ma (MSWD=2.8). The result suggested that the Weilasituo Sn-polymetallic mineralization took place during the Early Cretaceous. A zircon sample from the Beidashan granite was also selected for LA-ICP-MS dating, and the result of a weighted mean 206Pb/238U age of 140±2 Ma (MSWD=0.10) indicated the ore causative intrusion also formed during the Early Cretaceous. The Weilasituo tin-polymetallic deposit belongs to a granite-related magmatic-hydrothermal deposit. Our dating results, together with previous researchers rock- and ore-forming ages of other Sn-polymetallic deposits in the southern Great Xingan Range, demonstrated that almost all Sn-polymetallic deposits formed during 140135 Ma, which suggests that the Early Cretaceous is the peak era for the formation of the Sn-polymetallic deposits in the southern Great Xingan Range.
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    Fluid inclusion study and isotope characteristics of the Daolundaba copper-polymetallic deposit in the southern Great Xing an Range
    CHEN Gongzheng,WU Guang,WU Wenheng,ZHANG Tong,LI Tiegang,LIU Ruilin,WU Liwen,ZHANG Peichun,JIANG Biao,WANG Zhili
    2018, 25(5): 202-221. 
    DOI: 10.13745/j.esf.sf.2018.4.10

    Abstract ( 432 )   PDF (16470KB) ( 419 )  
    The Daolundaba deposit in the southern Great Xingan Range, Inner Mongolia is a medium-sized copperwolframtinsilver deposit. Ore bodies are hosted in faulted and shattered zones and host rocks are mainly the Permian sandstone and slate with minor amounts of Variscan biotite granite. The mineralization process can be divided into four stages: quartzfluoritemuscovitetourmalinecassiteritewolframite (stage Ⅰ), quartzfluoritewolframitechalcopyritearsenopyritepyrrhotite (stage Ⅱ), quartzfluoritechalcopyritepyritepyrrhotitesilver-bearing mineral (stage Ⅲ), and calcitefluoritepyrite (stage Ⅳ) stages. In this study, three types of fluid inclusions (FIs) have been distinguished in quartz, fluorite, and calcite veins including liquid-rich (WL type), gas-rich (WG type), and daughter mineral-bearing (S type) inclusions. The FIs in both stages Ⅰ and Ⅱ were  of WL-, WG-, and S-types, with homogenization temperatures and salinities varying from 309 to 389 ℃ and from 6.2 to 46.3 wt.% NaCleqv. in stage Ⅰ, respectively, and from 242 to 339 ℃ and from 5.3 to 41.4 wt.% NaCleqv. in stage Ⅱ, respectively. The FIs in stage Ⅲ contained mainly WL- and S-types, with  homogenization temperatures and salinities ranging from 153 to 268 ℃ and from 3.5 to 35.4 wt.% NaCleqv., respectively. Only WL-type FIs occurred in stage Ⅳ, and the homogenization temperatures and salinities varied from 114 to 188 ℃ and from 2.1 to 7.6 wt.% NaCleqv., respectively. In general, the ore-forming fluids of stages Ⅰ/Ⅱ, Ⅲ and Ⅳ were characterized by moderatehigh temperature/high salinity, moderatelow temperature/high salinity and low temperature/low salinity fluids, respectively. The δ18OH2O and δD values of the ore-forming fluids were between  -10.0‰ and 7.2‰, -127‰ and -81‰, respectively, demonstrating that, from the early to late stages, the ore-forming fluids of the Daolundaba deposit gradually evolved from magmatic fluids to mixtures of meteoric and magmatic waters. The δ34S values ranged from -7.4‰ to -1.2‰, indicating S came primarily from deep magma. The Pb isotopic composition (μ values 9.39.7) also indicated that Pb was mainly derived from the magma formed by partial melting of orogenic material. Thus, both S and Pb isotopic data suggest that the ore-forming materials originated mainly from magma. Overall, our study shows that the multi-stage boiling and mixing of the ore-forming magmatic fluids with meteoric water were the dominant mechanism for ore deposition.
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    Geological characteristics and ore genesis of the Chachaxiangka U-Th-Nb-REE deposit in the northeastern Qaidam Basin: a new mineralization type related to albitite.
    2018, 25(5): 222-237. 
    DOI: 10.13745/j.esf.sf.2018.4.17

    Abstract ( 213 )   PDF (5425KB) ( 402 )  
     The Chachaxiangka deposit in Qinghai Province is located in the eastern segment of the QaidamAltun UHPM complex in the northeastern Qaidam basin. It is the first albite aplite vein related U-Th-Nb-REE deposit recognized in China. Mineralization can be divided into two types: vein and disseminated veinlet types. Vein type mineralization is entirely hosted in albite aplite, while disseminated veinlet type refers to disseminated veinlets produced in greenschist wall rock. Three mineralization stages have been delineated according to detailed mineralogical analyses, i.e. magmatic, hydrothermal main mineralization and post-ore stages. The magmatic stage is characterized by the “droplet” U-Th-Nb mineral (uraninite, uranothorite, thorite, viggezzite, etc.) inclusions hosted in the albite grains. The main hydrothermal mineralization stage is mainly the REE mineralization stage, accompanied by Nb and Th mineralization. The major ore minerals include allanite, bastnaesite, thorite, Nb-titanite, zircon, etc., closely intergrown with low-temperature gangue minerals such as apatite, calcite, chlorite and quartz. The post-ore stage marks the termination of the mineralization system and is represented by the widespread calcite quartz stockworks. Based on our comprehensive analyses of mineralogical, major and trace elemental compositions, we suggest that the albitite vein is magmatic-hydrothermal in origin and derived from the partial melting of the REE- and Nb-rich metasomatized mantle source. Although phase separation between silicate and carbonate/phosphate melts could take place in the magmatic stage, immiscibility between silicate melt and chloride-dominated fluids is still the most important mechanism for REE mineralization and cause of Nb-Th re-mobilization and enrichment. The red color of albitite aplite vein is a useful prospecting mark in the field, and more mineralization can be expected in the deeply buried or peripheral areas of the deposit according to the metallogenic model of similar U-Th-Nb-REE mineralization systems.
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    The origin and significance of the differences in petrogenesis and mineralization of porphyry gold, copper and molybdenum deposits
    SHU Sunping,LI Qiugen,LIU Shuwen,CHEN Yanjing
    2018, 25(5): 237-250. 
    DOI: 10.13745/j.esf.yx.2018-4-8

    Abstract ( 279 )   PDF (1826KB) ( 669 )  
    In this paper, we compare the similarities and differences among porphyry Au, Cu, and Mo deposits in tectonic setting, whole rock geochemical characteristics due to ore-causative intrusion, and in temperature, pressure and salinity of exsolved fluid and related alteration. To expound these differences, we reviewed metal geochemistry and magma/fluid source and evolution, which explained the collected whole rock geochemical data and p-T-X of exsolved fluid. The differences in geochemical behavior, especially sulfophile affinities of Au, Cu and Mo, control the elements distribution, transport and enrichment in the magmas. And various magmatism in different tectonic settings control the distribution of ore metals. Factors, such as magma source region, fractional crystallization during ascent, and intra-chamber magma evolution in the middle and upper crust, shape the magmas geochemical characteristics which affect the pressure and temperature of emplacement to cause fluid exsolution at various p-T-X. The contents of LILEs (Rb, Sr, Ba) and SiO2 in magmatic rocks can be used to determine mineralization types in general: porphyry Mo deposits prefer high Rb content; Ba is enriched in porphyry Mo-Cu deposits; and Sr content will be the highest in porphyry Cu-Au deposits. Compared to subduction setting, LILE content in ore-causative magmatic rocks should be higher in post-subduction environment, where ore potential can be indicated initially from the textures (porphyry, weakly porphyry, heterogranular, equigranular, etc.) of intermediate to silicic rocks.
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    Occurrence state of gold in hydrothermal deposits and related research methods
    ZHANG Bo,LI Nuo,CHEN Yanjing
    2018, 25(5): 251-265. 
    DOI: 10.13745/j.esf.sf.2018.4.6

    Abstract ( 419 )   PDF (7297KB) ( 751 )  
    In this contribution, we review the occurrence state of gold in hydrothermal deposits and related analytical methods. The occurrence states of gold can be classified according to different criteria, but essentially they can be characterized as visible and invisible gold. The analytical methods include chemical phase analysis, physical identification, microbeam and spectroscopic analysis. At present, microbeam analysis techniques are widely used in SEM, EMPA, TEM, SIMS, SPM, LA-ICP-MS and so on, and these analytical methods can shed light on gold hydrothermal occurrence. Today we are still facing challenges in areas such as resolving the occurrence state of structural gold or valence state of Au in gold-bearing minerals, improving resolution and sensibility of microbeam analysis techniques, and overcoming obstacles in wave spectrum analysis. Improvements in microbeam analysis techniques and spectroscopic analysis will lead to more in-depth research on the occurrence state of gold.
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    Fluid inclusion characteristics and genesis of the Xingziyan stibnite deposit, Xinning, Hunan Province
    YU Pan,ZHENG Yi,WANG Yuejun,YU Pengpeng
    2018, 25(5): 266-276. 
    DOI: 10.13745/j.esf.sf.2018.4.3

    Abstract ( 257 )   PDF (7297KB) ( 275 )  
    The Xingziyan stibnite deposit is located in the Central Hunan Basin (CHB), the middle section of the QinzhouHangzhou Joint Belt (QHJB). The stibnite ore bodies, controlled by NW-trending silicified fracture belt, are hosted in the pyrite-bearing carbonaceous and siliceous slate of the Cambrian Xiangnan Formation. In this study, we identified two ore-forming periods exhibiting three ore-forming stages. The sedimentary period typically presents rounded pyrite with recrystallized rims. And in the hydrothermal period, the early- and late-stage features presents stibnitequartz veins (wrapping around some host rock breccias) and stibnite-bearing calcite veins, respectively. The early-stage quartz and late-stage calcite in the hydrothermal period were selected to investigate fluid inclusions. Two types of widely developed fluid inclusion, H2O and CO2-H2O types, were identified under petrographic observation. The homogenization temperature and salinity of fluid inclusions ranged 113266 ℃ and 0.812.0 wt.% NaCleqv., respectively. Gaseous constituents in fluid inclusions were dominated by CO2 as identified by Laser Raman analysis. The characteristics of middle-to-low homogenization temperature, low salinity and high CO2 content indicate the ore-forming fluid may be of metamorphic origin. In consideration of the regional tectonic evolution, we conclude that the Xingziyan stibnite deposit, is an orogenic-type stibnite mineral system formed in the tectonic setting of the IndosinianYanshanian intracontinental strik-slip faulting.
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    Potassic syenite resource in China and reaction mechanism of potash salt processing by hydrothermal alkaline digestion
    MA Hongwen,YANG Jing,ZHANG Pan,LIU Changjiang,SU Shuangqing,YAO Wengui,LUO Zheng,LIU Meitang,YIN Congcong,CHEN Jian,
    2018, 25(5): 277-285. 
    DOI: 10.13745/j.esf.yx.2017-7-27

    Abstract ( 274 )   PDF (3085KB) ( 305 )  
    Due to shortage of salt lake resource, over 50% of potash salt consumption in China relies on import, seriously challenging Chinas agricultural development and grain production security. Syenites with K2O grade up to 8.5%15.4%, are rich potassium resource, possessing 20 times higher predictive reserve potential than that of salt lakes. In mineralogy, this syenite-type potassium resource is consisted of potassium minerals such as microcline, nepheline and muscovite; geographically, it mainly distributes in the “QinlingDabie syenite zone” and “YanliaoYinshan syenite zone”. In this work, phase equilibria in KAlSi3O8-NaOH/KOH/Ca(OH)2-H2O systems were simulated by electrolyte solution thermodynamic software OLI Analyzer 9.2, and tested on representative potassic syenite samples by hydrothermal alkaline decomposition experiments. As a result, leaching ratio of K2O reached as high as over 85.6%. The obtained sodium and potassium silicate alkaline solutions were suitable for preparing various types of potash salts or eco-potash fertilizers; accordingly, the alumina-silicate components were transferred into products of precipitated calcium silicate, Na-/K-zeolites, wollastonite and kaolin, etc. By virtue of its cleanliness, high efficiency, high resource utilization rate, and environmental compatibility, the hydrothermal alkaline digestive method provides excellent technological support for the green and sustainable development of a new potash salt industrial system in China.
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    Microbialites of Lower Ordovician in the Songzi area, Hubei Province
    XIAO Chuantao,ZHOU Siyu,XU Xinyue,YANG Aiying,WU Pengshan,HUANG Yunfei,DONG Man
    2018, 25(5): 286-297. 
    DOI: 10.13745/j.esf.sf.2018.4.5

    Abstract ( 233 )   PDF (15949KB) ( 227 )  
    The lower Ordovician microbialites in the Songzi area, Hubei Province are studied systematically for the first time. The microbialites are distributed in the Nanjinguan, Fenxiang and Honghuayuan formations of the Lower Ordovician in the study area. In this paper, microbial rocks are divided into two categories: in-situ and non-in-situ growth types. The former includes stromatolite and thrombolites, and the latter is mainly oncolite. According to geometric classification scheme, stromatolites in the study area are characterized as lamellar-, wavy-, columnar- and mound-shaped types; in addition, we discovered and named a new type, the double cone-shaped stromatolite. Likewise, the thrombolites are divided into three types: porphyritic, reticular and striped clotted types. Fossil record of drilling predation on mollusks Ecculiomphalus and traces of bioturbation were found in leopard porphyritic and striped thrombolites, both, we suggest, are bioturbated thrombolites. The discovery of bioturbated thrombolites filled a gap in domestic and international Ordovician research contributing new knowledge towards understanding of thrombolites genesis. Based on analysis of sedimentary characteristics, depositional environments and their distribution patterns are described for various types of microbiological rocks. And the relationship between microbialites evolution and resuscitation and radiation of metazoan during the early to middle Ordovician is discussed. We believe that the Ordovician microbialites are decreasing with time, and certain relationship exists between the decline of microbiological rocks and increase of metazoan abundance. We also believe that grazers not only chewed up the stromatolite-forming bacteria and algae microbes to cause continuing stromatolite reduction, but also destroyed the growth condition for stromatolites, resulting in bioturbation thrombolites with unique characteristics.
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    Regional differences of vegetation cover in the BeijingTianjin sandstorm source region from 2000 to 2015
    LI Qingxu,ZHANG Biao,WANG Shuang,XIE Gaodi
    2018, 25(5): 298-304. 
    DOI: 10.13745/j.esf.sf.2018.4.19

    Abstract ( 279 )   PDF (2258KB) ( 270 )  
     Vegetation status represents the overall condition of regional ecological environment, hence vegetation coverage is often used to measure the effectiveness of ecological protection and restoration projects. Although numerous studies have reported the overall changes of vegetation coverage in the BeijingTianjin sandstorm source region, few studies have investigated the regional differences over the years. In this paper, we  calculated the annual vegetation coverage from 2000 to 2015 in the BeijingTianjin sandstorm source region using MODIS data, emphasizing the regional variations of   vegetation cover in different subzones through statistical and GIS technology. The results indicated that, during the study period, the annual vegetation coverage in the region increased from 35% to 45% with an average annual growth rate of 0.4%. Although vegetation coverage in the eight subzones presented similar growth trend, remarkable differences existed in the vegetation status and growth speed. The annual vegetation growth rates in the Jinbei mountain-hill and Yanshan mountain-hill-water-source-protection subzones exceeded 0.6%, however, lower than 0.2% annual growth rates were observed in the Otindag sandy land and Desert grassland subzones. In addition, higher degree of vegetation primarily distributed in the sandstorm source regions of Beijing, Chengde and Tianjin with  Shuozhou and Zhangjiakou showing higher growth rates, whereas the rates were lower than 0.1% in Wulanchabu and Baotou. Approximately 51% BeijingTianjin sandstorm source region saw growth rate increasing in 2015 compared to 2000, while the remaining areas experienced decline in the mid and western districts. In conclusion, this study confirmed that significant vegetation improvement has been made in the BeijingTianjin sandstorm source region, however,  some areas remain poorly covered, therefore more efforts should be directed to these areas towards ecological restoration.
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    An overview of current status of copper pollution in soil and remediation efforts in China.
    WANG Meng,LI Shanshan,LI Xiaoyue,ZHAO Zhongqiu,CHEN Shibao
    2018, 25(5): 305-313. 
    DOI: 10.13745/j.esf.sf.2018.4.20

    Abstract ( 1442 )   PDF (638KB) ( 852 )  
    Copper (Cu) is an essential micronutrient of plants and animals, but excessive Cu can stunt plant and animal growth. With Chinas rapid industrial and agricultural developments in recent years, Cu contamination in soils has become one of the most serious issues of environmental pollution. Copper contamination not only reduces soil quality, but also disrupts homeostasis in  plants, soil microorganisms, soil enzyme activities, etc., and most importantly it threatens the quality and safety of agricultural products. Here, we first review the source and current status of Cu contamination in soil in China, and analyze the characteristics of Cu contamination and its harmfulness to the soil ecosystem. We then introduce Cu pollution prevention methods, and summarize the principle and applicability of and progress of research and development in each remediation technology used to remediate Cu contaminated soil. Finally, we discussion the problems in current soil remediation methods that deserve further study. Overall, we provide a comprehensive literature for future research and development in Cu contaminated soil remediation in China.
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    Effect of biofertilizers on the remediation of Cd-polluted soils in tobacco cultivating area
    LI Xiaoyue,DUAN Shuhui,ZHOU Zhicheng,LIU Yongjun,LI Shanshan,ZHAO Zhongqiu,WANG Meng,CHEN Shibao
    2018, 25(5): 314-322. 
    DOI: 10.13745/j.esf.sf.2018.4.21

    Abstract ( 246 )   PDF (3606KB) ( 294 )  
    The purpose of this study is to explore the influence of different biofertilizers on  the remediation of Cd-polluted soil and Cd uptake by tobacco cultivars. Three kinds of Cd-polluted clay soilsred, yellow and blue purple clay from tobacco planting areas, along with two kinds of tobacco plant, Y-87 and K-326, used as testing cultivars, were selected for this study. A pot experiment was carried out to evaluate the effects of different biofertilizers(DY, AMS and HMD) on the biomass of tobacco plant, Cd distribution in tobacco plants, and Cd bioavailability and microbial diversity in soils. The results indicated that (1) Biomass of tobacco leaves increased significantly by applying three kinds of biofertilizers, with HMD being the most effective one. (2) Biofertilizer can significantly reduce soil and tobacco plant Cd contents compared to controls. Specifically, for the above three kinds of soils with the three biofertilizers used at 1.5% (mass fraction), tobacco leaf Cd(%) was reduced by 17.2%63.9%, 20.4%58.3% and 18.9%48.3%, respectively, and soil DTPA-Cd contents were decreased by 13.8%17.3%, 17.2%22.8% and 12.8%16.2%, respectively. At 3.0% (mass fraction), reduction of tobacco leaf Cd reached 20.3%59%, 31.3%66.6% and 25.2%56.1%, respectively, and soil DTPA-Cd contents were decreased by 15.5%28.2%, 19.6%26.6% and 13.8%17.3%, respectively. Among the different biofertilizers, HMD was the most effective, followed by DY and AMS. (3) Application of biofertilizers not only increased soil microbial diversity and population but also optimized the soil environment for tobacco growth. In general, DY and HMD can be used in the field since they have better effect on increasing tobacco yield while simultaneously reducing Cd uptake and translocation in tobacco plants.
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    Microplate tectonics theory: insights from microblocks in the global oceans and continental margins
    LI Sanzhong,SUO Yanhui,LIU Bo,LIU Yongjiang,LI Xiyao,ZHAO Shujuan,ZHU Junjiang,WANG Guangzeng,ZHANG Guowei
    2018, 25(5): 323-356. 
    DOI: 10.13745/j.esf.sf.2018.7.1

    Abstract ( 686 )   PDF (9033KB) ( 1483 )  
    Any plate has a growth process from small to large. Microblocks or microplates are sometimes the precursors of large plates. The origin, growth, aborting, extinction and residual processes of microblocks are of great significance for the study of plate tectonics. Microblock can be classified as micro-continental, micro-oceanic and micro-mantle block according to its composition. In this paper, the characteristics of microblocks in the Pacific, Indian and Atlantic oceans are summarized according to five environments of the mid-ocean ridge, subduction system, deep-sea intraplate, extensional rifting and collisional orogenic systems. We first propose a genetic classification of micro-blocks as the detachment-, rifting-, transform-, propagation-, ridge jumping-, subduction-, accretion-, collision- and delamination-induced micro-mantle blocks. We then discuss the different types of micro-block boundaries systematically. These micro-block boundaries include active or inactive detachment fault, subduction zone, mid-ocean ridge, transform fault, fracture zone, lithosphere-scale fault, pseudo-fault, intra-oceanic collisional zone, overlapping spreading center, non-transform offset, ridge offset and others. The key research of boundary formation is the stability analysis of triple junctions. These microblocks, within the oceanic basin or along the oceanic margin, are significant not only for developing deep ocean fine structural analysis and plate reconstruction, but also for explaining the causes of microblocks in orogens, intra-continent, intra-ocean, intra-mantle and continental margins to improve research precision towards a more detailed understanding of orogenic belt evolution, intraplate deformation and mantle processes, or even extending our study into the early Precambrian pre-plate tectonic mechanisms.
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