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    2011, Volume 18 Issue 6
    25 November 2011
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    Soil carbon pool in the northeast Inner Mongolia and its influencing factors.
    YANG Zhong-Fang, JIA Hua-Ji, TU Chao, HOU Jing-Xie, FENG Hai-Yan
    2011, 18(6): 1-10. 
    Abstract ( 1807 )   PDF (2947KB) ( 881 )  

    527 surface soil samples were collected and analyzed in the semiarid area in the northeast Inner Mongolia to investigate the distribution of the organic and inorganic carbon pool, its influence factors and to access the change of the carbon pool under the climate change. The results showed that the carbon pool in the study area is still dominated by the total organic carbon (TOC) with the variation of 61%-97% under different soil types. The spatial distribution of soil organic and inorganic carbon was controlled significantly by the climate conditions such as temperature and precipitation. Soil organic carbon has a trend of decreasing with mean annual temperature (MAT), but increasing with mean annual precipitation (MAP). However, soil inorganic carbon has an opposite trend of increasing with MAT and decreasing with MAP. Based on the extent of temperature and precipitation change predicted by IPCC 2007, the overall carbon density in 2090-2099 caused by the climate change will decrease by about 1.22 kg/m2.

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    Distribution and influencing factors of paddy soil organic carbon content in Chinas major farming areas.
    TU Chao, YANG Zhong-Fang, HOU Jing-Xie, JIA Hua-Ji, ZONG Sai-Feng, LI Biao
    2011, 18(6): 11-19. 
    Abstract ( 2047 )   PDF (2752KB) ( 911 )  

    Paddy soil is one of the major agricultural soils in China. The content of organic carbon in paddy soil varies with the change of global climate, and therefore, it is significant to clarify the distribution of organic carbon in paddy soil of Chinese major agricultural lands and its influence factors. In this research, the distribution of organic carbon in paddy soil of different administrative divisions were investigated based on a national multipurpose geochemical survey (1:250000) soil database. Besides, the influence of soil pH, annual average air temperature, annual average precipitation, cultivating methods etc. on the content of organic carbon in paddy soil were discussed.  Principal components analysis and stepwise multiple regression models were also used to detail these researches.  The results indicate that the content of organic carbon in the paddy soil of Heilongjiang Songnen plain is the highest (15.1 g/kg) and those of Guangdong Pearl River Delta and Hainan Island are less.  The organic carbon in soil can be hardly affected by soil pH, however, content of organic carbon can be phenomenally influenced by soil pH in a negative way when the soil pH ranges from 7.5 to 8.5.  In some high latitude areas like Heilongjiang province and Jilin province, organic carbon in soil is significantly influenced by air temperature. The content of organic carbon in paddy soil reduces 2.51g/kg with the annual average air temperature increase of 0.1 ℃ according to a linear regression model. Cultivating and land managements can influence the content of organic carbon in soil slightly. Among several major influence factors, like annual average precipitation, annual average air temperature and soil pH, the influence of annual average air temperature is the most important.

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    Profile distribution of organic carbon of four typical soils in China.
    LIU Fei, YANG Ke, LI Kuo, BANG Min, NIE Hai-Feng
    2011, 18(6): 20-26. 
    Abstract ( 2156 )   PDF (2517KB) ( 883 )  

    The organic carbon contents, C/N ratios and organic carbon density of four typical cropland soil types (black soil, cinnamon soil, paddy soil and latosol) were studied. The result indicated that the SOC (organic carbon content) decreases with soil depth. While the SOC of cinnamon soil is the lowest, the carbon sequestration potential is large. The C/N ratios of black soil and latosol were higher than cinnamon and paddy soil. All the C/N values of the topsoil of farmlands are lower than those of the second national soil survey in China. As a consequence, it may influence the nitrogen cycling and the ecological environment. There is obvious difference in organic carbon content and organic carbon density among these soils under different land use.

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    Estimation of soil carbon storage and its change since 1986 in Zhalong wetland and its surrounding areas, Heilongjiang Province.
    DIAO Chuan-Dong, LIU Guo-Dong, YANG Ke, NIE Hai-Feng, BANG Min, LI Kuo, LIU Fei, LI Yan-Sheng
    2011, 18(6): 27-33. 
    Abstract ( 1882 )   PDF (2884KB) ( 629 )  

    On the basis of data obtained from National Multipurpose Regional Geochemical Survey (NMPRGS) and National Soil Survey in Zhalong wetland and its surrounding areas of Heilongjiang Province, we studied the change of soil carbon storage in  the last twenty years, by estimating soil total carbon density(STCD), soil organic carbon density(SOCD) and soil carbon storage of different land uses. The results indicated that: (1)SOCD (0100 cm) is about 37884 t/km2 in Zhalong wetland; (2)the loss of soil organic carbon was as high as 66.7%70.2%, when wetland degraded to grass land or crop land; (3) from 1986 to 2006, surface soil (00.2 m) organic carbon storage decreased about 21% in the study area, while in Zhalong wetland, surface soil (00.2 m) organic carbon storage increased about 7%.

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    A comparison of predictive methods for mapping the spatial distribution of soil organic matter content with different sampling densities.
    SU Xiao-Yan, DIAO Yong-Cun, YANG Gao, LIU Fang-Yi, SUN Wei-Xia, WANG Huo-Yan, HUANG Biao, HU Wen-You
    2011, 18(6): 34-40. 
    Abstract ( 1765 )   PDF (1298KB) ( 1187 )  

    Soil organic matter (SOM) is extremely important for maintaining soil fertility and linking carbon cycle within terrestrial ecosystem. In order to quantify the spatial patterns of SOM content in Hailun County of China, ordinary kriging (OK), universal kriging (UK), cokriging (CK), regression kriging (RK), and secondary data derived from soil total nitrogen (TN), cation exchangeable capacity (CEC) and digital elevation model (DEM) were employed to map the spatial distribution patterns of SOM with different sampling densities. The results of SOM spatial structures identified by different sampling densities indicated that the increase of soil sampling densities may not benefit the identification of SOM continuous component and optimal design of sampling locations was even more important than improving sampling densities. With respect to spatial predictive performance, CK with TN as covariable always had the highest accuracy, and more than 50% of the SOM variation can be explained by CK method. The local detail of SOM variability derived from CK method also outperformed OK, UK, and RK, and the predictive accuracy of RK method may not be improved when compared with univariate OK method. The soil sampling density is not the exclusive factor affecting the spatial predictive accuracy of SOM, and secondary data (ancillary information) significantly correlated to SOM as well as denser coverage of the study area would be more helpful for improving the spatial predictive performance of SOM with limited number of soil samples.

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    Research on organic carbon storage and sequestration mechanism of soils in the Hebei Plain.
    ZHANG Xiu-Zhi, DIAO Xiang-Lei, LI Hong-Liang, WANG Zhi-Jun, LAO Xiao-Guang, XIE Wei-Meng
    2011, 18(6): 41-55. 
    Abstract ( 2066 )   PDF (5314KB) ( 3390 )  

    Based on soil organic carbon data obtained by multipurpose regional geochemical survey in 2005 and the Second Soil Survey over the whole province in 1970s, this paper studies the issues such as temporal and spatial variation of soil organic carbon density and soil organic carbon reserves, mechanism of soil carbon sequestration, and soil carbon sequestration potentials in the Hebei Plain. The results showed that the soil organic carbon density in the plain was 2.21 kg/m2, which was significantly lower than that nationwide. The soil organic carbon storage was 124.86 Mt in the period of the Second Soil Survey in 1979, and 176.08 Mt in 2005, which increased by 41.02% over the 26 years, showing the effect of a “carbon sink”. The soil carbon sequestration potential was 188.6Mt according to the maximum value of organic carbon content of different types of soils. The factors including the soil physical and chemical properties, such as the stable soil organic carbonnitrogen ratio, the high soil nitrogen, phosphorus, selenium content etc., and agricultural management measures, such as the agricultural fertilizer application, the strawreturning, shallow tillage, notillage etc., promoted the accumulation of soil organic carbon. On the opposite side, factors such as droughty climate, abundant calcium, alkalisaline, high silicon and kalium sandy soils and the natural wetland environment disturbed by people, induced the loss of soil organic carbon.

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    Soil carbon source/sink caused by landuse change in the last decades of the last century in  Northeast China.
    JIA Hua-Ji, YANG Zhong-Fang, TU Chao, HOU Jing-Xie, BAI Rong-Jie, CUI Yu-Jun
    2011, 18(6): 56-63. 
    Abstract ( 1990 )   PDF (2154KB) ( 2162 )  

    Landuse change is one of the most important factors that influence the variation of the soil organic carbon pool. Soil organic carbon density (SOCD) under different landuses and the effect of soil carbon source/sink caused by landuse change in Northeast China was investigated using soil data from the regional multipurpose geochemical survey and landuse data of two temporal points: 1980s and the year of 2000. The following conclusions were drawn: (1) SOCD varied significantly with different landuses; bog and thick forest have the highest SOCD, and sand land, saline land and thin grass land are the landuse types with low SOCD; (2) the reserve of surface soil (020 cm) organic carbon in the study area is 482.1×1010 kg, and the two most large soil carbon pools are the thick forest and the dry farm land, which account for, respectively, 43.8% and 21.4% of the total organic carbon pool of the study area;(3) the carbon source caused by landuse change is 5.73×1010 kg, and the carbon sink is 3.56×1010 kg, so the aggregate effect of the landuse changes results in an effect of soil carbon source of 2.17×1010 kg (21.7 Tg) in the study area; (4) the typical landuse change types that caused soil carbon sinks are the change of dry farm land to paddy field, and the change of thin forest and other forest to thick forest; and the typical landuse change types that caused soil carbon sources are the changes of thick forest and thick grass land to dry farm land, and the change of bog to dry farm land, paddy field, etc.

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    Chen Hao. Corrosion of limestone in farmland ecosystems and its carbon sink effect in the karst area of Southwest China:A case study in Sanquan Town, Nanchuan City, Chongqing Municipality.
    LUO Fu-Liang, YUAN Dao-Xian, CHEN Gao
    2011, 18(6): 64-71. 
    Abstract ( 1728 )   PDF (2233KB) ( 761 )  

    The carbon cycle in karst area is the perfect joint combining geological process with biological process, so it is very important for accurately estimating the carbon sink effect of karstification to systemically study limestone weathering in farmlands. Taking a hydrological year as a period, corrosion experiment of the standard limestone tablets in farmland samples such as yearround flooded paddy field, seasonal rotation paddy field, vegetation plot, dry land, grassland, unutilized land and so on has been observed. Based on the limestone corrosion experiment, on the investigation of soil profiles and biomass of vegetation in the same farmlands, and on the analytical experimentation of soil and the standard limestone tablets, the characteristics of corrosion of limestone in farmland ecosystems in the area and its influence factors have been analyzed. The result shows that the corrosion ratio decreases successively from seasonal rotation paddy field, to vegetation plot, to dry land and to yearround flooded paddy field. There are obvious differences, and complex changes among corrosion ratio at different soil layers of farmlands in Sanquan Town, Nanchuan City. Karstification in farmland ecosystem in the area is more intense than that in nonfarmland ecosystems, and the average annual flux of CO2 absorbed by karstification in farmland ecosystems in the town is 163.1264×105 gC/(km2·a). The annual flux of CO2 absorbed by karstification in farmland ecosystems in the region is larger than that in nonfarmland of other areas at the same latitude. Principal component analysis shows that karstification in farmland in the region is mainly affected by the location of soil layer, the kinds of farmland, the seasonal change of farmland and the matter sources of soil in farmland ecosystem.

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    Driving mechanisms for the DOC increases in surface waters released from Northern Peatlands under global change.
    XIANG Wu, Jiasong Fang, MO Xiang, HE Ling, SUN Xin-Ting, BI Xiang-Yang
    2011, 18(6): 72-78. 
    Abstract ( 6599 )   PDF (1344KB) ( 10101 )  

    Peatlands are the most efficient terrestrial ecosystems in storing carbon,which contain approximately one third of the world’s soil carbon pool and play an important role in global carbon cycling. During the last two decades, increases in dissolved organic carbon (DOC) concentrations have been observed in freshwaters across large areas of Northern Hemisphere. It is generally considered to be related to large scale DOC releasing from Northern Peatlands. Several hypotheses have been put forward as potential driving mechanisms for the increase in DOC, including (1) changes in  temperature; (2) elevated CO2 concentrations; (3) changes in Hydrological processes; (4) Decrease in sulphur deposition. However, none of the proposed hypotheses is completely convincing. After reviewing previous studies, we proposed that the combining forces of temperature and hydrological processes under global change possibly  are the main dominant drivers of DOC change, though multiple mechanisms for rising DOC exist. 

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    Effect of temperature on methane oxidation in rice field and irrigative agriculture soil.
    JIANG Li-Zhen, FENG Hai-Yan, JIANG Hong-Chen, YANG Zhong-Fang, WANG Cheng-Yu, LI Miao, JIA Hua-Ji, ZHANG Cai-Xiang
    2011, 18(6): 79-84. 
    Abstract ( 2027 )   PDF (1571KB) ( 1033 )  

    Temperature affects methane oxidation in soils. We studied CH4 consumption in agricultural soils including dark brown earth (Jilin),fluvoaquic soil (Hebei),and paddy soils (Anhui and Jiangxi) that were incubated at 5, 15, 25 and 35 ℃ for up to 44 days. All of the soils except paddy soils (Jiangxi) showed that the suitable temperature for CH4 consumption was 2535 ℃,but no activity at 5 ℃ and 15 ℃. Both dark brown soil (Jilin) and paddy soil (Anhui) had similar ability at 25 ℃ and 35 ℃,the maximum average rates of CH4 oxidation were 4.42 μg·g-1·d-1and 5.60 μg·g-1·d-1. The average rate of CH4 oxidation of fluvoaquic soil (Hebei) at 25 ℃ was twice as big as the rate at 35 ℃. Paddy soil (Jiangxi) could consume CH4 at any temperature. The average rates of CH4 oxidation increase with rising temperature and the rate at 35 ℃ was 3 times as the rate at 5 ℃. The maximum rate of CH4 oxidation at 2535 ℃ follows this sequence:paddy soil (Jiangxi)>fluvoaquic soil (Hebei)>paddy soil (Anhui)>dark brown earth (Jilin). We concluded that temperature can be an important factor affecting the CH4 consumption in agricultural soils and the temperature 2535 ℃ would be suitable for CH4 oxidation than 515 ℃. Both dry farm and rice field had significant ability of CH4 consumption. This study will provide an important evidence for agricultural soil carbon pool research.

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    Research on temperature sensitivity of soil respiration and different active organic carbon fractions of QinghaiTibet Plateau permafrost.
    LIAO Yan, YANG Zhong-Fang, JIA Hua-Ji, JIANG Hong-Chen
    2011, 18(6): 85-93. 
    Abstract ( 1855 )   PDF (2034KB) ( 1185 )  

     Four soil samples of highaltitude permafrost from the QinghaiTibet Plateau were incubated in the laboratory for 90 days at 5 ℃, 15 ℃, 25 ℃ and 35 ℃ temperatures. The results showed that with increasing temperature, the soil respiration rate and cumulative amount of organic carbon decomposition presented a trend of increasing; during the incubation, the soil respiration rate reached a peak at first, then decreased continually, and tended to be steady after 15 days. At the same temperature, the soil respiration rate showed the following order: Tuotuohe (meadow marsh soil)>Wuli (alpine meadow soil)>Wudaoliang (alpine steppe soil)>Geermu (greybrown desert soil), but the last three soil samples had no significant difference. Through the methods of density separation, acid hydrolysis, and chloroform fumigation, the soil organic carbon fractions were divided based on physical, chemical and biological views, respectively; meanwhile decomposition dynamic of organic carbon was simulated using the kinetic equations in two pools and three pools. It showed that dividing soil carbon fractions with different methods had significantly different results, and the proportion of active organic carbon accounting for total organic carbon was as follows: microbial biomass carbon 1.26%10.31%, lightfraction organic carbon 9.13%20.22%, easily oxidized organic carbon 28.35%49.35%; that the results of model fitting through  by dividing two or three pools were 0.50%3.65% and 0.51%3.26%, respectively, and MRT were 856 d and 850 d, respectively, which were close; and that in addition, the proportion of active carbon from model approaches was significantly lower than that from experimental methods. Using linear, exponential and Gaussian models, the rule of change of soil respiration rate with temperature was analyzed. It was found that all of the three models can describe this relationship well, and Gaussian model was the best; the Q10 values from Gaussian model was also more agreed with that from incubation experiment. And Q10 decreased with increasing temperature, indicating that the response of the QinghaiTibet Plateau permafrost to climate warming will be more sensitive.

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    Soil respiration in riparian zone of Zhalong wetland, northeastern China.
    YANG Ke, LIU Guo-Dong, LIU Fei, DIAO Chuan-Dong, LIU Ying-Han, BANG Min, LI Kuo
    2011, 18(6): 94-100. 
    Abstract ( 2049 )   PDF (2399KB) ( 705 )  

    Wetland, as one of the most important components of terrestrial ecosystems, was recognized as the important carbon storage. In decades, the cultivation of wetland made the soil carbon storage lose seriously. CO2 emission of wetland had amounted to 1/10 of the total world emission. To study the impact of the change of land use on soil respiration will help to understand wetland carbon cycle, to calculate carbon budget, and then, to put forward the countermeasures to mitigate the carbon emission. By using LI8100A dynamic closed chamber survey, we analyzed soil respiration of three different land uses, which are uncultivated land, fallow land and crop land, in riparian zone of Zhalong wetland during midMay to midAugust in 2011. The results indicated that the soil respiration rate is 4.44±1.84 μmol·m-2·s-1(uncultivated land), 5.16±3.43 μmol·m-2·s-1(fallow land), and 3.70±2.34 μmol·m-2·s-1(crop land), respectively. The ratio of day time respiration to night time respiration is 6∶4. The main factors impacting on soil respiration are air temperature, moisture, and soil temperature. Q10, the temperature sensitivity of respiration, decreases in the order of uncultivated land (1.86)>fallow land (1.65)>crop land (1.56).

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    A study of soil respiration of typical black soil in Songnen Plain, northeastern China.
    LIU Guo-Dong, YANG Ke, CUI Yu-Jun, LI Ying
    2011, 18(6): 101-106. 
    Abstract ( 1986 )   PDF (1176KB) ( 735 )  

    We measured soil respiration in different land uses, such as crop land, fallow land and uncultivated land, located in typical black soil area of Songnen Plain. Autotrophic and heterotrophic soil respiration was distinguished by trenching. Temperature sensitivity of soil respiration (Q10) was calculated in different land use respectively. The results indicated that soil respiration was controlled by many factors, such as soil temperature, soil moisture, vegetation types and cultivation activities. Diurnal soil respiration was dominated by temperature. Autotrophic respiration by plant root occupies 50% of the soil respiration in summer, but the ratio in spring and autumn is less than that in summer. Because of different vegetation types and different proportion of autotrophic soil respiration occupied, autotrophic soil respiration in different land use decreases in order of uncultivated land>fallow land>crop land. Q10 of soil respiration with plants is bigger than those without plants.

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    Influences of the decadal variation of ENSO on the carbon flux in the terrestrial ecosystems.
    JIANG Chao, XU Yong-Fu, JI Jin-Jun, LI Yang-Chun
    2011, 18(6): 107-116. 
    Abstract ( 1433 )   PDF (1112KB) ( 2788 )  

    The Atmosphere Vegetation Interaction Model version 2 (AVIM2) is used to make an offline simulation of terrestrial carbon cycle and its response to climatic variation under the forcing of the meteorological reanalysis data from the National Center for Environmental Prediction. The spatial distribution and its temporal characteristics of global net primary production (NPP) and net ecosystem production (NEP) in the terrestrial ecosystem are simulated from 1953 to 2004. Results show that 52year averaged global NPP and NEP from 1953 to 2004 are 65 Pg/a and 1.2 Pg/a respectively, and reveal that NPP obviously increases with time, while the trend of increase in NEP is not statistically significant. Although the trends of decadal increases in NPP and NEP are different, in the middle of the 1970s their decadal changes all revealed an abrupt change. Their growing trends were all decreased after the abrupt point. This is because the Pacific decadal oscillation (PDO) affected the decadal change of El Nin~oSouthern Oscillation (ENSO), which also affected the decadal variation of NPP and NEP. Before 1976, when PDO was in the cool phase, the strength and frequency of the cool phase of ENSO was increased, which led to the cooler and humid climate in the tropical region so that it was beneficial to the increase in NPP and NEP. On the contrary, while the PDO was in a warm phase after 1976, El Nin~o took place frequently, so that in the equatorial region the drier and warmer climate reduced the increasing trends of NPP and NEP.

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    Characteristics of humic substances in soil and its implication to longterm stability of organic carbon: A case of Luochuan loess profile
    SUN Xu-Hui, LI Fu-Chun, SHI Huan-Zhi, DAI Jing-Yu, TUN Feng, JIN Zhang-Dong
    2011, 18(6): 117-124. 
    Abstract ( 1779 )   PDF (1573KB) ( 1011 )  

    Understanding the compositions of humic substances (HS) and its humification in soil on a longterm scale are important to evaluate the stability of soil organic matter. In this study, humic acid (HA), fulvic acid (FA) and humin (HM) in 17 samples of loess and paleosol from above S8 of the Luochuan loess/paleosol profile were analyzed quantitatively. The values of E465 and E665 of both HA and FA were also measured. By combining the contents of HA, FA and HM with the results of mineral compositions and total organic carbon, the characteristics of HS in soil and its implication to longterm stability of organic carbon were focused. The results indicated the following four aspects. (1) The order of the contents of HS in most of paleosol samples is HM>HA>FA, whereas that in loess is FA>HM>HA, with higher HA and HM but lower FA in paleosol than in loess; along with the increase in burial time, HA, FA, and HM in paleosol and FA and HM in loess decrease gradually to different extent; finally HA and FA in both loess and paleosol will not decrease till older than 200 ka, whereas HM till older than 700 ka. (2) HA/FA ratios in most paleosol samples are larger than 1 and decrease gradually with increased burial time (with an exception of S6); HA/FA ratios in loess are lower than those in paleosol; E4/E6 ratios of FA in both loess and paleosol decrease with increased burial time, indicating an increased humification degree; meanwhile, C/H and O/C ratios suggest that the condensation and oxidation degrees of HA and FA in paleosol increase slightly with increased burial time. The results in (1) and (2) indicate that the evolution direction of HS in both paleosol and loess may be as FA→HA→HM (→kerogen). (3) There are good correlations of TOC with HA, HA+FA, and HA+FA+HM (r=0.89, 0.94, and 0.96, respectively). (4) There are also good correlations of kaolinite content with HA, HA+FA, and HA+FA+HM (r=0.62, 0.57, and 0.65, respectively),indicating that the stability of HS in both loess and paleosol might be relevant with kaolinite. These results shed further light on organic geochemistry of loess and paleosol and on longterm stability of organic carbon in soil.

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    Investigation on content and composition characteristics of labile carbon and recalcitrant carbon in farmland soils of Yangtze River Delta.
    ZHANG Ting, LI Gen, YANG Zhong-Fang, JI Jun-Feng
    2011, 18(6): 125-133. 
    Abstract ( 2288 )   PDF (3473KB) ( 710 )  

    Soil carbon pool is one of the major concerns about farmland soil today. Soil carbon pool contains the recalcitrant carbon with turnover time of thousands of years, and the labile carbon with turnover time of hundreds of years. Effective separation and exploration of the two are essential for modeling precise SOC dynamics and assessing soils carbon storage potential. In this study, 24 soil samples collected in Yangtze River Delta were selected for analysis. According to the difference in antioxidant capability, disodium peroxodisulphate oxidation method was chosen to separate recalcitrant carbon and labile carbon, and then, the nearinfrared (NIR) and midinfrared (MIR) spectroscopy were applied to probe into SOMs composition changes before and after oxidation treatment as well as verify the effectiveness of the method and find the possible factors affecting the distribution of labile carbon and recalcitrant carbon. Carbon oxidized by Na2S2O8 took up 64%92% of total organic carbon (TOC), manifesting that labile carbon accounted for 64%92% of TOC while recalcitrant carbon accounted for 8%36% of TOC. Element analyses show that the ratio of labile carbon to recalcitrant carbon in the south Yangtze River region is around 68, more stable than that in the north. Enrichment of Ca results in an increase in recalcitrant carbon content. When analyzing NIR spectrum, an overall rise of the samples reflectivity after oxidation was detected, especially among the 400600 nm band. According to the MIR spectrum, the group peaks having been reduced after Na2S2O8 treatment are mainly those of alkyl, carboxyl and amide, indicating that when compared with recalcitrant carbon, labile carbon contains lots of alkyl, carboxyl and amide, which can serve as the spectrum indication of labile carbon.

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    Microbial carbon distribution and its controlling factors in arable soils of eastern China.
    WANG Chang, JIANG Hong-Chen, HUANG Liu-Qin, TU Chao, YANG Zhong-Fang
    2011, 18(6): 134-142. 
    Abstract ( 1644 )   PDF (1191KB) ( 751 )  

    The soil microbial carbon in arable soils of Eastern China was investigated by using the fumigationextraction (FE) method. The investigated arable soils span from 46.69846°N  to 28.39281°N, and are of different tillage types. The results show that, from north to south, the soil microbial C (MicroC) content in Northeast China is much higher than that in other locations, and the total organic carbon (TOC) and total nitrogen (TN) have the same trends. The correlation analysis showed that the soil type determined by specific environmental climatic condition and thus the geographic position plays a key role in controlling the MicroC distribution. The soil quality, an index for which is the ratio of MicroC to TOC calculated, is much related to the tillage type. Average annual temperature, pH, moisture, TOC and TN are the five main factors affecting the MicroC content and the ratio of microbial C to TOC for a certain soil type, but the key controlling factors varies among different soil types.

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    The characteristics of Palynofacies of surface sediments collected from the Changjiang Estuary and its significance in carbon cycle.
    CA Jin-Gong, XU Jin-Li, FENG Xiao-Ping, DENG Bing
    2011, 18(6): 143-149. 
    Abstract ( 1652 )   PDF (1182KB) ( 596 )  

    Palynofacies and pyrolysis were applied to four surface sediment samples (F2F5) from the Changjiang estuary and their 18Φ particle size fractions to discuss the characteristics of organic matter (OM) and their fate in carbon cycle. The palynofacies of bulk samples are mainly comprised of woody tissue, charcoal, and black mass OM, which indicates a large contribution of terrestrial organic matter input. After fractionation, the feature of palynofacies changed significantly. Fine particle size fraction (8Φ) dominated in amorphous OM, while other fractions (27Φ) were comprised of structural OM. Fine particle size fraction (8Φ) was characterized by high HI, S2 and low Tmax value, which suggests an aquatic organic matter origin. However, the OMs of other size fractions (27Φ) were characterized by terrestrial organic matter input and great oxidative degradation. In samples of F4 and F5, which are far from the Changjiang estuary, about 70% of the TOC was contributed by fine particle size fraction (8Φ),while the TOC is homogeneous in different size fractions of samples of F2 and F3 which are near the estuary. The amorphous OM in fine size fraction (8Φ) was protected by clay minerals from biodegradation and oxidative degradation. These OM flocculate and precipitate rapidly, and shortened the process from biosphere, hydrosphere to lithosphere. As a result,this may prolong the period of carbon cycling. The OMs in other fractions (27Φ) underwent oxidative degradation and were preserved in sediments with  the longest period of carbon cycling. Consequently, the relationship between sedimentary OM and clay mineral and their influence on the time of carbon cycling should be concerned. This may help us to get some future understanding of carbon cycle which is still uncertain.

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    Origin of particulate organic carbon in the Wuyuer River: Carbon isotopic evidences.
    HOU Jing-Xie, YANG Zhong-Fang, TU Chao, GU Zhao-Tan, JIA Hua-Ji, CHEN Cheng-De
    2011, 18(6): 150-160. 
    Abstract ( 1463 )   PDF (1631KB) ( 831 )  

    Suspended solids were sampled at 9 sites on the Wuyuer River and its main tributaries in 20082009. Contents, stable carbon isotopes (13C) and cosmogenic carbon isotope (14C) compositions of particulate organic carbon (POC) in suspended solids were used to constrain the relationship between the sources of particulate organic carbon and soil erosion in drainage basin. Particulate organic carbon is mainly of organic matter of deep soil. Also, the organic matter in deep soil is dominated by grassland vegetation residue, and lack of corn root residue. Particulate organic carbon of suspended solids in Zhalong wetlands is mainly determined by modern carbon formed in it, with little or absence of terrestrial influence. 14C apparent ages of  POC  of Wuyuer River and its main tributaries in high water periods are older than those in low water periods. The migration distance of particulate matter in rainfall season is shorter than that in rainless season. Compared to the other rivers, the characteristic and variability of 14C apparent ages of particulate organic carbon suggested that soil erosion in Wuyuer River is very severe, and show obvious seasonal difference. Considering the difference of origin and migration distance of particulate organic carbon, we calculated the contribution of main tributaries to Wuyuer River in high water periods from the mixing model.

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    Seasonal variation in the flux and isotopic composition of particulate
     organic carbon along the mainstream of the Changjiang River.
    MAO Chang-Beng, JI Jun-Feng, LUO Yun, YUAN Xu-Yin, YANG Zhong-Fang, SONG Ken-Xian, CHEN Jun
    2011, 18(6): 161-168. 
    Abstract ( 1628 )   PDF (1393KB) ( 2304 )  

    Suspended particulate matter (SPM) samples were collected along the Changjiang mainstream in summer and winter 2007 to investigate the distribution of organic particulate organic carbon (POC) concentrations and the stable isotopic composition of POC (δ13C) within the river system. The results indicate that the POC% has a range from 0.4% to 1.3% in summer and 0.7% to 2.2% in winter. The mean δ13C values of the POC in winter and summer are -24.74‰,-24.83‰, respectively. The C/N ratio has no significant seasonal variability. The δ13C values of upper reaches are higher than the values of the middle and lower reaches in winter (low flow season). The relative decrease in δ13C values during the low flow season from the upper to lower reaches could be interpreted as the result of an increase in the soil erosion rate and channel erosion in the middle and lower reaches after dam construction, except for flood events during which rivers are also strongly influenced by relative more contribution of phytoplankton from the middle and lower reaches. We got a total organic carbon flux of 1.46 Mt/a after impoundment of the Three Gorges Dam which could have caused a sharp reduction in sediment load of the Changjiang River.

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    Chemical weathering and CO2 consumptions in  Poyang Lake Basin.
    DI Da-Xin, YANG Zhong-Fang, LIU Jing-Jing, HOU Jing-Xie, JIA Hua-Ji, TU Chao, YUAN Guo-Li, FENG Hai-Yan
    2011, 18(6): 169-181. 
    Abstract ( 1631 )   PDF (3150KB) ( 807 )  

     Carbon sink produced during rock weathering is an important part of global carbon cycle. Therefore, more and more attention has been paid to this field by the scientists who focus on the global warming. In this work, the source of ion of the rivers and carbon sink produced by rock weathering in Poyang Lake drainage basin are studied based on the systematic sample collection and chemical composition analysis of river water samples from this area. Taking precipitation, evaporation rock, silicate rock and carbonate rock as four endmember components, we have calculated their contribution rates to the total dissolved mass(TDS) of Poyang Lake water system, which are 10.4%, 21.9%, 30.0% and 37.8% respectively. The chemical weathering rates of the basin of Xiushui River, Ganjiang River, Fuhe River, Xinjiang River and Raohe River are 27.22, 5050, 7030, 64.62 and 63.94  t·km-2·a-1, respectively, while the erosion rates in these areas are 1134, 2104, 29.29, 26.92 and 26.64 mm · ka-1. Two models were used to calculate the quantity of CO2 consumption during chemical weathering in the drainage area. One method is based on the result of ionic source analysis. In the basin of Poyang Lake, Xiushui, Ganjiang River, Xinjiang River and Raohe River, the CO2 consumptions are 74.39, 4.92, 4106, 4.49, 4.85, 4.09×109 mol · a-1, and the contribution of silicate weathering rates are 34.3%, 76.6%, 28.9%, 604%, 58.8% and 32.8%. The other method is using GEMCO2 model to calculate chemical weathering rate in drainage areas respectively. The CO2 consumption are 45.08, 4.23, 23.26, 3.14, 6.76 and 3.94×109 mol · a-1. Compared the data from  the two methods, the results of the CO2 consumption are considered between 4.5×1010 mol · a-1 and 7.4×1010 mol · a-1.

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    Variations of dissolved carbon and δ13CDIC of surface water during rainfall events in a typical karst peak clusterdepression catchment, SW China.
    DING Hu, LIU Cong-Jiang, LANG Bin-Chao, LIU Wen-Jing
    2011, 18(6): 182-189. 
    Abstract ( 1905 )   PDF (2072KB) ( 681 )  

     Continuous samplings of surface water, including stream flow and surface flow, in a small karst catchment (Huanjiang Karst Agricultural Ecological Station, Chinese Academy of Sciences) were conducted during two rainfall events on Aug. 23 and Aug. 24, 2007, with the main purpose of understanding the responses of dissolved carbon (DOC and DIC) and stable carbon isotopic composition of DIC (δ13CDIC) to the rainfall. Both the dissolved carbon concentrations and δ13CDIC values varied quickly in response to the rainfalls. About 107.1 kg of DOC and 812.5 kg of DIC were transported out of the catchment during two rainfall events, about 64 and 8 times respectively those of normal days during the same period. According to δ13CDIC values of the water, about 56%61%, 56%63%,and 50%58% of DIC in surface flow, upstream flow and downstream flow, respectively, were estimated to be originated from soil CO2. About 406.2 kg soil CO2 was dissolved in downstream water during rainfall periods, while the amount during the same period of normal days was only about 48.3 kg. It is concluded that rainfall can significantly affect the carbon cycling of the catchment,and the studies of cycling of carbon and other nutrients on different time scales and rainfall events are important for understanding local and global carbon cycling.

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    Experimental study of CO2 residual gas sequestration applied to Ordovician reef limestone of Tarim Basin.
    LI Xu-Feng, CHANG Chun, GUO Jian-Jiang, XU Jing-Chun
    2011, 18(6): 190-194. 
    Abstract ( 1658 )   PDF (1843KB) ( 711 )  

     The geological storage of CO2 is widely accepted as an effective method to reduce the release of greenhouse gases to the atmosphere. Saline aquifer has the most sequestration potential and the most complicated mechanisms among all the sites that could implement CO2  geological sequestration. Of all the mechanisms, residual gas sequestration has the extremely vital significance in respect of storage capacity and security, and residual gas saturation is a key parameter to calculate the capacity. In this study, an experimental method applied to a rock sample taken from Ordovician reef limestone of Tarim Basin was used to measure the residual gas saturation. Through simulating water flooding supercritical CO2 saturated core under 40 ℃ strata temperature, 8 MPa strata pressure, the pressure and flux change with time were observed during the course, and  residual gas saturation was measured as 0.368. Before the flooding experiment, sample porosity and permeability coefficient were measured as 2.83% and 5.56×10-9 m/s, respectively, by saturated weighing and permeating experiments.

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    Centimeterscale sedimentary sequence description of Upper Cretaceous Nenjiang Formation (lower numbers 1&2): Lithostratigraphy,facies and cyclostratigraphy, based on the scientific drilling (SK1) borehole in the Songliao Basin.
    GAO Wei-Feng, WANG Pu-Jun, CHENG Ri-Hui, WANG Guo-Dong, MO Xiao-Qiao, TUN He-Yong, WANG Shu-Hua, LIANG Mo-Lin
    2011, 18(6): 195-217. 
    Abstract ( 2209 )   PDF (13299KB) ( 1330 )  

     China Cretaceous Continental Scientific Drilling (CCSD) in the Songliao Basin, called SK1 project, collected 29553 m of the lower members 1&2 of Nenjiang Formation which correspond to the late Santonian to early Campanian. The borehole got a highly continuous core section with recovery of 9745%,that is the most complete and precise sedimentary records up to now in the basin. Thicknesses of the description can be as thin as 25 cm for the interbedding sequences. We described  the sedimentary sequence, lithology, lithofacies and cyclic stratigraphy at the drilling spot in cmscale. Twelve lithotypes were recognized in the section. Sedimentary facies are predominantly lacustrine that can be subdivided into seven microfacies including dolomite, marl, argillaceous limestone, oil shale, turbidite, deep lake mudstone and volcanic ash microfacies. The whole sequence is composed of 213 meterscale cycles (sixthorder cycle), 54 fifthorder cycles, 12 fourthorder cycles and 2 thirdorder cycles. Centimeterscale depiction of the section revealed some previously unknown horizons such as special kind of mudstone, dolomite and volcanic ash of the formation. The new found evidences are very important for us to interpret basin evolution features such as lake anoxic, source rock development and the potential linkage between lake and adjacent sea. That is to say, the scientific drilling provides us with powerful insight into the basin. Researchers who are interested in the basin can do their reasonable analysis of the basin  on the basis of the precise original materials of the paper.

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    Centimeterscale sedimentary sequence description of Upper Cretaceous Nenjiang Formation (upper numbers 35): Lithostratigraphy,facies and cyclostratigraphy, based on the scientific drilling (SK1) borehole in the Songliao Basin.
    WANG Pu-Jun, GAO Wei-Feng, CHENG Ri-Hui, WANG Guo-Dong, TUN He-Yong, MO Xiao-Qiao, YANG Gan-Sheng, HONG Zhong-Xin
    2011, 18(6): 218-262. 
    Abstract ( 2361 )   PDF (24911KB) ( 1273 )  

    China Cretaceous Continental Scientific Drilling (CCSD) in the Songliao Basin, called SK1 project, collects 53207 m of members 35 of the Upper Nenjiang Formation which correspond to the middle Campanian. The borehole gets a highly continuous core section with recovery of 948%,that is the most complete and precise sedimentary records obtained up to now in the basin. The minimum thickness of the subdivided layers is generally 2 to 5 cm for the whole drilling sequence. We describe  the sedimentary sequence in cmscale, revealing lithology, lithofacies and cyclic stratigraphy at the drilling spot. Nine lithotypes are recognized in the section. Sedimentary facies are predominantly lacustrine, delta and fluvial, which can be subdivided into fifteen microfacies including channellag deposit, point bar, natural levee, crevasse splay, crevasse channel, flood plain, flood lake, distributary mouth bar, subaqueous distributary channels, subaqueous natural levee, subaqueous interdistributary bay, distal bar, mudstone of still water, adjacent shore sand bar and lake turbidite. The whole sequence is composed of 417 meterscale cycles (sixthorder cycle), 94 fifthorder cycles, 26 fourthorder cycles and 3 thirdorder cycles. Centimeterscale depiction of the coresection revealed some previously unknown horizons such as special kind of mudstone, dolomite and volcanic ash of the formation. The red beds in the fifth member of Nenjiang Formation, being an important case study of midCretaceous continental red beds found in the northeast Asia, will become a standard of potential formulation section for the studies of late Cretaceous global oxygenenriched events. The detailed description of the third and fourth members of Nenjiang Formation is significant for their further exploration in the Songliao Basin.

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    Centimeterscale sedimentary sequence description of Upper Cretaceous Sifangtai Formation: Lithostratigraphy, facies and cyclostratigraphy, based on the scientific drilling (SK1) borehole in the Songliao Basin.
    WANG Guo-Dong, CHENG Ri-Hui, WANG Pu-Jun, GAO Wei-Feng, WANG Cheng-Shan, LIN Yan-An, HUANG Qing-Hua
    2011, 18(6): 263-284. 
    Abstract ( 1991 )   PDF (9506KB) ( 1286 )  

    China Cretaceous Continental Scientific Drilling (CCSD) in the Songliao Basin, called SK1 project, collected 20902 m of Sifangtai Formation which correspond to middle to late Campanian. The borehole got a highly continuous core section with recovery of 97.5%,that is the most complete and precise sedimentary records up to now in the basin. Thicknesses of the description can be as thin as 25 cm for the interbedding sequences. We described in cmscale the sedimentary sequence, lithology, lithofacies and cyclic stratigraphy at the drilling spot. Eleven lithotypes were recognized in the section. Sedimentary facies are predominantly meandering river and lacustrine that can be subdivided into ten microfacies including point bar, natural levee, crevasse splay, crevasse channel, floodplain, flood lake, nearshore bar,mudstone of still water, and turbidite. The whole sequence is composed of 174 meterscale cycles (sixthorder cycle), 43 fifthorder cycles, 13 fourthorder cycles and 2 thirdorder cycles. Centimeter scale description of the section revealed some previously unknown horizons such as special kind of mudstone, favorable sand reservoir of the formation. The new found evidences are very important for us to interprete basin evolution features such as lake oxic and the reservoircap rock assemblages in shallow stratigraphy. That is to say, the scientific drilling provides us with powerful insight in to the basin. Researchers who are interested in the basin can do their reasonable analysis about the basin based on the precise original materials of the paper.

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    Centimeterscale sedimentary sequence description of Upper CretaceousLower Paleocene Mingshui Formation: Lithostratigraphy,facies and cyclostratigraphy, based on the scientific drilling (SK1) borehole in the Songliao Basin.
    CHENG Ri-Hui, WANG Guo-Dong, WANG Pu-Jun, GAO Wei-Feng, LIN Yan-An, WANG Cheng-Shan, ZHANG Shi-Gong, HONG Qing-Yuan
    2011, 18(6): 285-328. 
    Abstract ( 1947 )   PDF (19528KB) ( 1766 )  

    China Cretaceous Continental Scientific Drilling (CCSD) in the Songliao Basin, called SK1 project, collected 55894 m of Mingshui Formation which corresponded to the late Campanian to Danian. The borehole got a highly continuous core section with recovery of 93.69%,that is the most complete and precise sedimentary records up to now in the basin. Thicknesses of the description can be as thin as 25 cm for the interbedding sequences. We described in centimeterscale the sedimentary sequence, lithology, lithofacies and cyclic stratigraphy at the drilling spot. Fifteen lithotypes were recognized in the section. Sedimentary facies are predominantly river and lacustrine that can be subdivided into fifteen microfacies including point bar, natural levee, crevasse splay, crevasse channel, flood plain, flood lake, mudstone of still water, nearshore bar,tempestite,sandy beach,mudy beach,turbidite and gravity flow channel microfacies. The whole sequence is composed of 361 meterscale cycles (sixthorder cycle), 109 fifthorder cycles, 29 fourthorder cycles and 3 thirdorder cycles. Centimeter scale depiction of the section revealed some previously unknown horizons, which is  very important for us to interpret basin evolution features such as lake oxic events, K/Pg boundary,tectonism in late sag basin stage and the sourcereservoircap rock assemblages in shallow stratigraphy. That is to say, the scientific drilling provides us with powerful insight into the basin. Researchers who are interested in the basin can do their reasonable analysis of the basin on the basis of the precise original materials in the paper.

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    The analysis of microfacies and paleaoenvironment reconstruction of Panxian Fauna from the Guanling Formation (Middle Triassic) of Xinmin, Panxian County, Guizhou.
    LI Mei-Zheng, LIU Chu-Xiong, JIANG Da-Yong, HAO Wei-Cheng, SUN Yuan-Lin, SUN Zuo-Yu
    2011, 18(6): 341-346. 
    Abstract ( 1545 )   PDF (9057KB) ( 883 )  

     Through the field measurement and microscopic observation, 10 microfacies types have been recognized from the layers of 78 to 91 in the Middle Triassic Upper Member of Guanling Formation, where the Panxian Fauna occurs. The fossilbearing beds also include their overlying layer of 92 and underlying layer of 77. The division and analysis of microfacies is based on particle types, the content contrast of particles and matrix, depositional fabric, fossil assemblages and taphonomic types. By comprehensive microfacies analyses, it is shown that the sedimentary facies of the fossilbearing beds change upward from opencarbonate platform to restricted carbonate platform and to tidal channel. The presence and abundance of pyrite indicates that the paleoenvironment was somewhat anoxic, which helped the exquisite preservation of Panxian Fauna. The grain size and content show that the hydrodynamic condition changed from weak to strong,then weak again upward to the fossilbearing beds. It is consistent with the changes of the body size of the marine reptiles. According to the analysis of microfacies types and petrographic characteristics, the Panxian Fauna probably lived in a restricted carbonate platform.

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    A species of high pressure mineral:The highchromium corundum(ruby) as an inclusion in diamond from the Yuanshui, Hunan, China.
    SHI Ni-Cheng, LIU Qi, LI Guo-Wu, LIU Hui-Fang
    2011, 18(6): 347-357. 
    Abstract ( 1480 )   PDF (2018KB) ( 994 )  

    The mineralogy of a diamond inclusion that is the corundum containing high chromium from Yuanshui, Hunan, China has been investigated. It is confirmed that the highest content of chromium in the chromiumcontained corundum may reach 19.31%. According to the EPMA analysis, the formula of the highchromium corundum is(Al1.683,Cr0.298,Fe0.010,Mn0.008,Ti0.004, Si0.001)2.004O3. Based on the Xray powder diffraction pattern and the method of full spectrum Rietveld fitted refinement, the crystallographic parameters were obtained as the following: R3c, a=04765 nm, c=1.3007 nm, Z=6, and the trivalent chromium and aluminum ions occupy the same crystalchemical position. Although the crystallographic parameters of the corundum suggest that it has regressed to the ordinary pressure state, the high chrome content implied that it had undergone a highpressure environment. Thus, it can be regarded as a kind of index mineral indicating a highpressure environment. The discovery of high Cr content of the Yuanshui corundum as a diamond inclusion suggested that the diamonds in this area were possibly from eclogite xenoliths.

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     Restriction on the application of thermochronologic agetemperature and ageelevation relationships: Some insights into sampling strategies and age interpretation.
    CAO Kai, WANG Guo-Can, Peter van der Beek
    2011, 18(6): 347-357. 
    Abstract ( 2274 )   PDF (1615KB) ( 1196 )  

    Thermochronologic agetemperature and ageelevation relationships are commonly used to quantitatively constrain the longterm tectonic evolution of an orogen. In contrast to the agetemperature relationship, the ageelevation relationship has more advantages in calculating exhumation rates of rocks without the imposed geothermal gradient. However, the potential functions of the ageelevation relationship in extracting cooling and exhumation signals of rocks need the presupposition of stable geothermal gradient.But the complicated effects (e.g. the relief change, exhumation rate, magma emplacement, etc.) will unpredictably perturb the geothermal field, producing the unstable geothermal gradient. As such, aiming at some specific projects, it is essential to adopt suitable sampling strategies and promising methods to unveil the information hidden in the thermochronologic ages.

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    Transboundary aquifers analysis in LancangMekong River Basin.
    HE Jing, HAN Zai-Sheng, NIU Lei
    2011, 18(6): 358. 
    Abstract ( 1537 )   PDF (2119KB) ( 817 )  

    Transboundary aquifer is an aquifer system that exists in more than one state. As an important component of the groundwater system, proper management and rational utilization of transboundary aquifers are significantly important for promoting sustainable development and goodneighbor relationships. The paper analyzes hydrogeological conditions of LancangMekong River Basin and delimits transboundary aquifer systems, as well as explores the groundwater resources and environmental problems. The paper puts forward transboundary aquifers comprehensive evaluation index system, and applies it to the four transboundary aquifers in the LancangMekong Basin. The study is of significance for the management of LancangMekong River transboundary aquifers and the construction of harmonious international environment in Southeast Asia.

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