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    2011, Volume 18 Issue 5
    18 September 2011
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    Principles, methods and applications of hydrodynamic studies of mineralization.
    CHE Guo-Xiang, XUE Chun-Ji
    2011, 18(5): 1-18. 
    Abstract ( 2503 )   PDF (4111KB) ( 3635 )  

     Fluid flow is an integral part of hydrothermal mineralization, and its analysis and characterization constitute an important part of a mineralization model. The hydrodynamic study of mineralization deals with analyzing the driving forces, fluid pressure regimes, fluid flow rate and direction, and their relationships with localization of mineralization. This paper reviews the principles and methods of hydrodynamic studies of mineralization, and discusses their significance and limitations for ore deposit studies and mineral exploration. The driving forces of fluid flow may be related to fluid overpressure, topographic relief, tectonic deformation, and fluid density change due to heating or salinity variation, depending on specific geologic environments and mineralization processes. The study methods may be classified into three types, megascopic (field) observations, microscopic analyses, and numerical modeling. Megascopic features indicative of significantly overpressured (especially lithostatic or supralithostatic) fluid systems include horizontal veins, sand injection dikes, and hydraulic breccias. Microscopic studies, especially microthermometry of fluid inclusions and combined stress analysis and microthermometry of fluid inclusion planes (FIPs) can provide important information about fluid temperature, pressure, and fluidstructural relationships, thus constraining fluid flow models. Numerical modeling can be carried out to solve partial differential equations governing fluid flow, heat transfer, rock deformation and chemical reactions, in order to simulate the distribution of fluid pressure, temperature, fluid flow rate and direction, and mineral precipitation or dissolution in 2D or 3D space and through time. The results of hydrodynamic studies of mineralization can enhance our understanding of the formation processes of hydrothermal deposits, and can be used directly or indirectly in mineral exploration.

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    Relationship between hydrocarbon generation and basinal fluid flow and uranium mineralization in the Ordos Basin.
    XUE Chun-Ji, CHE Guo-Xiang, XUE Wei, CAO Ji-Hu
    2011, 18(5): 19-28. 
    Abstract ( 2810 )   PDF (3703KB) ( 1289 )  

    The Ordos Basin is not only an important uranium mineralization province but also a major producer of oil, gas and coal in China. The genetic relationship between uranium mineralization and hydrocarbons has been recognized by a number of previous studies, but it has not been well understood in terms of hydrodynamics of basin fluid flow. In a previous study we have demonstrated that the preferential localization of uranium mineralization in the upper part of the Jurassic strata may have been related to the interface of an upward flowing, reducing fluid and a downward flowing, oxidizing fluid, and that this interface may have been controlled by the interplay between the fluid overpressure which was related to disequilibrium sediment compaction and drove the upward flow and the topographic relief which drove the downward flow. In the present study, we carried out numerical modeling for the contribution of oil and gas generation to the development of fluid overpressure, in addition to sediment compaction and heating. Our results indicate that when hydrocarbon generation was taken into account, fluid overpressure during the Cretaceous was more than doubled in comparison with the simulation when hydrocarbon generation was not considered. Furthermore, the fluid overpressure dissipation after the ceasing of sedimentation slowed down relative to the nonhydrocarbon generation case. These results suggest that hydrocarbon generation may have played an important role in uranium mineralization, not only in providing reducing agents required for the mineralization, but also in contributing to the driving force to maintain the upward flow against the pushing of topographydriven, downward flow, thus helping stabilize the interface between the two fluid system and the localization of uranium mineralization.

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    Observations of clastic injection and hydraulic fracturing structures in the Jinding ZnPb deposit, Yunnan, China and hydrodynamic analysis.
    CHE Guo-Xiang, XUE Chun-Ji, QING Hai-Re, XUE Wei, ZHANG Jiang-Wei, SUN Yuan-Jiang
    2011, 18(5): 29-42. 
    Abstract ( 2365 )   PDF (11242KB) ( 2883 )  

    The Jinding ZnPb deposit has been generally considered to have formed from circulating basinal fluids in a relatively passive way, with fluid flow being controlled by structures and sedimentary facies, similar to many other sedimentshosted base metal deposits. However, several recent studies revealed the presence of sand injection structures, intrusive breccias, and hydraulic fractures in the open pit of the Jinding deposit and suggested that the deposit was formed from explosive release of overpressured fluids. This study reports new observations of fluid overpressure related structures from underground workings (Paomaping and Fengzishan), which show clearer crosscutting relationships than in the open pit. The observed structures include: (1) sand (± rock fragment) dikes injecting into fractures in solidified rocks;(2) sand (± rock fragment) bodies intruding into unconsolidated or semiconsolidated sediments;(3) disintegrated semiconsolidated sand bodies; and (4) veins and breccias formed from hydraulic fracturing of solidified rocks followed by cementation of hydrothermal minerals. The development of ore minerals (sphalerite) in the cement of the various clastic injection and hydraulic fractures indicate that these structures were formed at the same time as mineralization. The development of hydraulic fractures and breccias with random orientation indicates small differential stress during mineralization, which is different from the stress field with strong horizontal shortening prior to mineralization. Fluid flow velocity may have been up to more than 11 m/second based on calculations from the size of the fragments in the clastic dikes. The clastic injection and hydraulic fracturing structures are interpreted to have formed from explosive release of overpressured fluids, which may have been related to either magmatic intrusions at depth or seismic activities which episodically tapped an overpressured fluid reservoir. Because the clastic injection and hydraulic structures are genetically linked with the mineralizing fluid source, they can be used as a guide for mineral exploration.

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    Microstructural analysis of a subhorizontal goldquartz vein deposit at Donalda, Abitibi greenstone belt, Canada: Implications for hydrodynamic regime.
    CHE Guo-Xiang, Jayanta Guha
    2011, 18(5): 43-54. 
    Abstract ( 2389 )   PDF (3321KB) ( 1953 )  

    The Donalda gold deposit in the southern part of the Archean Abitibi greenstone belt consists mainly of a subhorizontal goldquartz vein perpendicular to subvertical shear zones. The 0305 m thick vein is characterized by veinparallel banding structures indicating multiple episodes of fracture opening and mineral precipitation. Measurement of the caxis of primary growth quartz indicates that quartz preferentially grew perpendicular to the fracture, suggesting open space filling and/or extensional nature of the fracture. Measurement of the orientations of microfractures, veinlets and fluidinclusion planes (FIPs) crosscutting primary growth quartz indicates that the vein minerals were subject to a vertical maximum principal stress (σ1), which is inconsistent with the subhorizontal σ1 inferred from the regional stress field with NS shortening. This apparent discrepancy is explained by invoking episodic fluid pressure fluctuation between supralithostatic and hydrostatic regimes accompanied by episodic opening and closing of the subhorizontal fracture. When fluid pressure was higher than the lithostatic value, the fracture was opened and primary growth minerals were precipitated, whereas when fluid pressure decreased toward the hydrostatic value, the hanging wall of the fracture collapsed, causing collision of protruding primary growth minerals from both sides of the fracture and resulting in formation of veinparallel deformation bands. The columns where the two facing sides of the fracture collided were subject to higherthanlithostatic stress due to the bridging effect and reduced support surface area, explaining the development of vertical σ1. This hypothesis is consistent with the faultvalve model, and explains the flipping of σ1 without having to change the regional stress field.

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    Tectonicmineralizing fluids in the Sarbulak gold deposit, Ertix metallogenic belt, Xinjiang.
    WANG Yan-Hai, XU Jiu-Hua, LIU Ze-Qun, WEI Gao, DING Ru-Fu, LIN Yuan-Jun
    2011, 18(5): 55-66. 
    Abstract ( 1814 )   PDF (3745KB) ( 1222 )  

    The Sarbulake gold deposit, located in the Kalatongkes island arc zone in the northeastern margin of the Zhuigaer Basin, occurred in the Sarbulake shear zone, which is a secondary structure of the NWWtrending Erqisi compressive tectonic zone to the north. Based on deformationhydrothermal alterationmineral assemblages, the structuralmineralization process can be divided into four stages: 1) the ductile deformationpyritesilicification stage; 2) the ductilebrittle deformationpyritearsenopyritequartz stage; 3) the stockwork quartz stage (polymetallic sulfide stage); and 4) the quartzcarbonate stage. The fluids in the early and middlestage were rich in CO2 (CH4) (represented by the carbonic inclusions) and had high CO2/H2O ratios. The homogenization temperatures (Th) of inclusions in the stage 1 are concentrated in the ranges of 290350 ℃ and 200269 ℃, those in the stage 2 are mainly in the range of 204358 ℃ and 170203 ℃, whereas the homogenization temperatures in the stage 3 are concentrated in 215310 ℃. Primary aqueous inclusions are associated with carbonic inclusions in the early and middle stages, while secondary aqueous inclusions also occurred widely in the stage 1, 2 and 3. These secondary inclusions probably represent meteoric water during crustal uplift in the late metamorphism. The evolution from mesothermal, CO2(±CH4)rich fluids to epithermal, aqueous fluids appears to have been accompanied by the transition from compressive, ductile regime to extensional, brittle regime along the Erqisi orogen. The Sarbulake gold deposit is similar to most orogenic gold deposits, with the mineralization process being mostly in the latetectonic stage and accompanied by the transition from compressive to extensional stress regimes.

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    Structurefluid related mineralization during the mylonitization process in the Hetai goldfield, Guangdong Province.
    SHU Jiang-Jian, CHEN An-Gao, GONG Gui-Lun, YI Jin, CA Jian-Xin, GONG Chao-Yang, HUANG Dong-Lin, CENG Jiao-Song, LIN Ge
    2011, 18(5): 67-77. 
    Abstract ( 2021 )   PDF (3469KB) ( 1049 )  

    A numerical modeling of the structurefluid process during mylonitization was conducted in order to investigate the possibility of gold mineralization related to mylonitization. Based on stress analysis and microstructural studies and comparison with modeling results, it is proposed that the study area was under compression in the direction of 108° during the formation of the mylonitized zones. The results of numerical modeling, together with previous studies, suggest that anomalous belts of volumetric strain increment are favorable for mylonitization and synmylonitization mineralization, and provide favorable site for later hydrothermal mineralization. It is proposed that mylonitization took place from 212 to 168 Ma at temperature from 300 to 500 ℃, and the synmylonitization mineralization process occurred from 197 to 168 Ma at temperature from 300 to 340 ℃. Uneconomic mineralization may have been produced during mylonitization, which was upgraded by later hydrothermal mineralization to form the Hetai gold deposit.

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    Fluid overpressure and rock fracturing caused by shallow intrusion and their constraints on hydrothermal mineralization.
    LIU Liang-Meng
    2011, 18(5): 78-89. 
    Abstract ( 1793 )   PDF (2980KB) ( 5567 )  

     The metallogenic systems related to shallow magmatic intrusions are the very important and complicated dynamic systems. In such a system, fluid overpressure caused by the shallow intrusion and consequent rock fracturing are critical dynamic processes for mineralization. This paper presents systemic analysis on the importance of fluid overpressure for mineralization related to shallow intrusions, the mechanisms for generating overpressure and the constraints of overpressured fluids on mineralization, with examples of skarntype mineralization from the TonglingAnqing district. The close association of skarn ore deposits with breccias and the characteristics of such orerelated breccias indicate the important role played by hydraulic fracturing in mineralization. The mechanisms for generating fluid overpressure associated with ore formation are very complex, including magma exsolution and degassing, expansion of pore fluids sealed in the country rocks due to heating by magma, and metamorphic reactions of the carbonate rocks with the magma. The contribution of the overpressured fluid to mineralization is realized through hydraulic fracturing followed by a series of dynamic events, mainly including the decompression of the fluids and consequent phase separation as well as mixing and reactions of fluids from different sources. The fluid overpressuringhydraulic fracturing and  the fluid decompressioncrack sealing, the two opposite processes, are coupled with fluid flow through changing the porosity and permeability of the rocks. These processes, governed by the magmatic dynamic input and tectonic stress field, selforganized the system towards a higher order state, leading to mineralization. Because rock fracturing is caused both by fluid pressure and tectonic stress, and is critical for ore formation, the combination of fluid pressure and stress field control not only the patterns and mechanisms of fracturing, but also the styles of ore formation.

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    The classification of oreforming fluid and the efficiency of ore formation of magmatic hydrothermal solution.
    ZHANG De-Hui, JIN Xu-Dong, MAO Shi-De, WANG Li-Li
    2011, 18(5): 90-102. 
    Abstract ( 2320 )   PDF (1804KB) ( 1384 )  

     Oreforming fluids are divided into meteoric, seawater, basinal settings, metamorphic and magmatic fluids, according to the contents of H2O, CO2 and NaCl phase components, as well as the critical pressure and halite meltcurvetemperature in the H2ONaCl system. This kinds of classification has a great value in understanding the variety of flowing fluids along geothermal and geopressure gradient, and fluid mixing and unmixing in the earths crust. Compared with other hydrothermal fluids, the magmatic hydrothermal fluid has a highest metalenrichment efficiency by the following reasons: 1) the magmatic hydrothermal fluid has the energy required to carry out the mineralization from the magma; 2) it has a high concentration of volatile components, which not only greatly affects the hydrothermal pH and oxygen fugacity, but also enhances the extraction efficiency of metals, and the huge released energy causes the expansion of wall rock permeability and produces fluid convection; and 3) the characteristics of high temperature and high salinity also lead to much higher metal extraction and enrichment efficiency of magmatichydrothermal fluids than other fluids. Compared with the magmatic melts, the hydrothermal system has higher mineralization efficiency, which can be attributed to the high partition coefficient of liquidmelts for most oreforming elements. The latest estimates of electronegativity and chemical hardness of the fluid phase and the melt phase indicate that, compared with the melt phase, the fluid phase has a greater electronegativity and chemical hardness. According to the hard and soft acidbase theory and the principle of maximum hardness, as the metals show the higher electronegativity and chemical hardness, the fluids are very attractive and of higher extraction ability for the metals compared to the silicate melt phase, which is consistent with the experimental results showing that the vast majority of the metals favor the hydrothermal fluid than the melt phase.

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    Oreforming fluids of the oxidized and reduced porphyry deposits.
    XU Wen-Gang, FAN Hong-Rui-*, HU Fang-Fang, YANG Kui-Feng
    2011, 18(5): 103-120. 
    Abstract ( 2147 )   PDF (3081KB) ( 1809 )  

    It is widely accepted that porphyry type deposits were formed from some oxidized ore fluids. But recently, some typical ilmenitebearing, reduced TypeI granite related porphyry CuMoAu deposits with relatively reduced oreforming fluids were found, in which primary hematite, magnetite and sulfate minerals are absent. Some classification schemes of porphyryrelated granitoids are discussed in this paper, and the porphyry related deposits are subdivided into the oxidized (OPD) and reduced (RPD) types accordingly. According to related research results, the CH4 contained in RPD fluid system is proposed to be derived from the contamination of TypeI granite with Stype granite, but it is also possible that CH4 comes from the degassing process of the Earth interior. A chemical model is set in order to interpret the role of reduced fluids in porphyry metallogenesis. According to the model, H2S and CO2 are derived from the reaction between CH4 and SO2, both of which come from the same evolved igneous system, which inhabits the formation of sulfate. The characteristics of oreforming fluid sources, metalsolubility, transportation, precipitation, enrichment and depletion are obviously different in OPD and RPD systems. The low oxygen fugacity is not propitious for transportation and enrichment of Cu and Mo, which causes the poor prospective of RPD system, whereas the Au will be transported under reducing conditions and deposit in some sites far away from the granite system, forming a cogenetic subclass porphyry Au deposits. An “end member metallogenic model”, with sulfide ores in the bottom and porphyry Au ores on the top, is speculated if the contents of metals and reduced S in primary magma are appreciably enriched.

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    Comparison of characteristics of ore forming fluids between quartzvein tungsten deposits and porphyry copper deposits associated with granitic rocks.
    WANG Die, LEI Huan-Zhang, BI Xian-Wu
    2011, 18(5): 121-131. 
    Abstract ( 1623 )   PDF (1664KB) ( 1790 )  

    We reviewed the characteristics of ore forming fluids of quartzvein tungsten deposits associated with S type granites and porphyry copper deposits associated with Itype (some associated with Atype) granitic rocks.  The two fluid systems are similar in that both of them are derived from magmatic evolution, with involvement of meteoric water in the late stage. On the other hand, they are different in the following  aspects: (1) the ore forming fluids of quartzvein tungsten deposits belong to the H2ONaCl±CO2 system with moderatehigh temperature and moderatelow salinity, whereas those associated with porphyry copper deposits belong to the H2ONaClKCl±CO2 system with high temperature and high salinity; (2) boiling and phaseseparation are common in porphyry copper deposits and may have played important roles for the transport and deposition of Cu, but are uncommon in quartzvein tungsten deposits, in which fluid mixing may have played a more important role; (3) W is more associated with O and Na in fluid systems while Cu is with Cl and S, so the formation and the type of deposits depend in part on availability of these elements in the fluids.

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    A new synthetic “fluid inclusion”: The technique of optical fused silica capillary.
    Ni-Pei, DING Dun-Yang, I-Ming Chou, Jean Dubessy
    2011, 18(5): 132-139. 
    Abstract ( 1585 )   PDF (1281KB) ( 1741 )  

    Synthetic fluid inclusions in the systems of pure H2O, of pure CO2, of H2ONaCl and of H2OCO2 were made using the technique of optical fused silica capillary. Those capillary samples were analyzed by microthermometry and microspectroscopy. The experiment shows that the fluids in silica capillary are the representative of loading fluids, and the microthermometry and microspectroscopy, the two common approaches for measuring the fluid inclusion, are suitable to be applied to the analysis of capillary samples. The microthermometric and microspectroscopic results reveal that the technique of silica capillary gives us a better means to understand the phase equilibria during the progress of microthermometry and to characterize the spectra of inclusion fluids and to develop the methods of analyzing the fluid inclusion. This study demonstrates that the technique of optical fused silica capillary provides a new means for the study of fluid inclusion, which may be widely applied to the fluid inclusion study.

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    Insitu Raman microspectroscopy study of  fluids in the H2OCO2 system  in optical fused silica capillary.
    DING Dun-Yang, NI Pei, GUAN Shen-Jin, WANG Guo-Guang
    2011, 18(5): 140-146. 
    Abstract ( 1818 )   PDF (1603KB) ( 2271 )  

     A Raman microspectrometer combined with a Linkam heatingfreezing stage was used to acquire Raman spectra of fluids in a H2OCO2 system in optical fused silica capillary sample at the temperature from -120 ℃ to 31 ℃ and in the 1200 and 1500 cm-1 regions. The results show that the fluids in fused silica capillary are the representative of loading fluids. Through the acquisition of Raman spectra of fluids in capillary, the Raman spectra of vapor CO2, liquid CO2, solid CO2, CO2 hydrate and CO2 in aqueous solution in fluid inclusion are characterized. These spectra reveal that the characteristic peak positions in solid CO2 and CO2 hydrate spectra are stable in the range of experimental temperature, which is helpful in identifying the bands in Raman spectra, and that the Fermi resonance peak positions of the spectra of vapor CO2, liquid CO2 and CO2 in aqueous solution are changed with the variation of pressure or the density of CO2. This study also analyzed the Raman spectra of different phases at different temperatures, which indicates that the technique of Raman microspectroscopy combined with microthermometry can effectively identify the different phases in fluid inclusions, catch on the process of phase changes, and determine the temperatures of phase changes.

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    Characteristics of fluid inclusions and mineralization of the Dehelongwa copper(gold) deposit, Qinghai Province.
    CAO Yong-Hua, LAI Jian-Qing, KANG E-Long, FAN Dun-Chang
    2011, 18(5): 147-158. 
    Abstract ( 2606 )   PDF (2765KB) ( 1065 )  

    The Dehelongwa copper (gold) deposit, located in the northeast part of QinghaiTibet Plateau, is a magmatic hydrothermal deposit. Three types of inclusions hosted in quartz are found in the orebodies, i.e., liquidrich twophased aqueous inclusions (type Ⅰ), vaporrich aqueous inclusions (type Ⅱ), and aqueous inclusions with daughter mineral(s) (type Ⅲ). Inclusions of type Ⅰ homogenize to liquid at temperatures of 187413 ℃ and have salinities from 2.0% to 19.0% (NaClequiv.). Inclusions of type Ⅱ homogenize to vapor at temperatures from 350 ℃ to 413 ℃ and the salinities are 5.3% to 9.8% (NaClequiv.). Inclusions of type Ⅲ can be further classified into two subtypes (Ⅲa,Ⅲb) depending on dissolution of daughter minerals before or after the disappearance of the gas bubbles during the heating processes. Inclusions of subtype Ⅲa have liquidvapor homogenization temperatures of 276 ℃ to 520 ℃,with daughter minerals melting temperatures from 192 ℃ to 491 ℃ and corresponding salinities from 31.5% to 57.1% NaClequiv.. Inclusions of subtype Ⅲb have homogenization temperatures (daughter minerals melting temperatures) from 250 ℃ to 500 ℃, with corresponding salinities from 33.0% to 59.8% (NaClequiv.), and liquidvapor homogenization temperatures of 195325 ℃. Based on the fluid inclusion data, three types of oreforming fluids are deduced, they are strongly overpressured and high salinity magmatic hydrothermal fluid A, mediumhigh salinity boiling hydrothermal fluid B, and lowmedium salinity fluid C. These fluids were all originated from different evolutional stages of the primitive fluids derived from the magmatic intrusion. Based on the highest boiling ceasing temperature of fluid B (350 ℃) and calculated pressure (160 bar), the mineralization depth is interpreted to be 1.6 km. It is suggested that oreforming elements were transported by high salinity magmatic fluids, with Cu mainly as chlorocomplex such as CuCl2(aq) and CuCl- and Au mainly as sulfurarsenic complex. The oreforming components were precipitated due to boiling and fluid mixing as well as the decrease in salinity, temperature, and pressure of the fluids.

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    Ore geology and oreforming fluid geochemistry of Zhouzhuang AgPbZn deposit, southwestern Henan Province.
    CAO Ji-Hu, XIANG Shi-Gong, XUE Chun-Ji, ZHANG Xu, LI Yong-Feng, LI Bing-Ai, CHENG Wen-Hou
    2011, 18(5): 159-171. 
    Abstract ( 2756 )   PDF (3183KB) ( 1076 )  

    The Zhouzhuang AgPbZn ore deposit was recently discovered in the southwestern Henan Province where there are some other AgPbZn ore deposits. It occurred in an interplate tectonicmagmatic geological environment after Indosinian orogeny. The orebody is mainly in the Erlangping Group and the veins of quartz(AgPbZn) sulfides filled in the fault fractures whose strikedirections are perpendicular to the orogenic belt. The AgPbZn hydrothermal mineralization shows three stages: the early stage is characterized by quartzpyrite; the main stage is quartz (AgPbZn) sulfide; and the late stage is quartzcalcite. Three types of fluid inclusions were trapped in the quartz in the AgPbZn ores; they are the water solution, the CO2H2O, and the daughter mineralbearing inclusions. The oreforming fluid temperatures of the early, the main and the late mineralization stages are 310270 ℃, 230200 ℃, and 180150 ℃, respectively. The oreforming fluid salinity of the early stage is 10%6% NaCleq., the main stage is 18%14% NaCleq., and the late stage 12%8% NaCleq.. The temperature decreased, and the salinity increased first and then decreased during the mineralization. The mineralization were accompanied with the rising of the crust; the oreforming fluid pressures in the early, the main and the latemineralization stages are 270235 MPa, 230200 MPa, and 79.3939.37 MPa, respectively; and the corresponding depths are 108.7 km, 8.57.4 km, and 2.91.5 km, respectively. The δDH2O VSMOW decreased from -59‰-70‰ to -70‰-82‰ and the δ18OH2O VSMOW also decreased from 5.19‰6.53‰ to 2.32‰2.46‰ when the mineralization developed from the early to the main stage, and the δ18OH2O VSMOW further decreased to -0.05‰ in the late mineralization stage. The oreforming fluid was mainly from the magma or the metamorphic water, and mixed by some meteoric water in the late stage. This study gives some new information for understanding the metallogeny of AgPbZn in southwestern Henan Province.

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    Geological characteristics and the geochemistry of oreforming fluid inclusions in Dashankou gold deposit, Western Tien Shan, Xinjiang.
    DONG Xin-Feng, XUE Chun-Ji, DAN Fu-Pin
    2011, 18(5): 172-181. 
    Abstract ( 2341 )   PDF (3210KB) ( 1406 )  

    The Dashankou gold deposit in Hejing County, Xinjiang Province is located at the east part of the southern Tien Shan metallogenic belt, and near suture zone between the Tarim and KazakhstanErie Plates. The deposit  occurred in the SahentuohaiDashankou brittleductile shear zones, the gold orebody is hosted in the clastic rocks of the Dashankou Formation and the  Upper Silurianlower Devonian diorite porphyry and dacite porphyry, and the host rocks had undergone the brittleductile deformation. The boundaries between the ore bodies and wall rock are blurred. The ore bodies which are confined to the brittleductile deformation zone obviously show characteristic of thinout reappearing along its strike and tendency, presenting parallel slaty and lenticular ore grops or belts. The natural types of the ore are mainly goldbearing mylonite and quartz veins. The ore contains a small amount of pyrite. The fluid inclusions in the veinquartz of the main mineralization stage were studied. There are two major types of fluid inclusions at room temperature, i.e., the aqueous  and CO2bearing inclusions. The oreforming fluid mainly contains H2O and CO2, and the temperature is between 260320 ℃, the salinity peak is between 500%850% NaCleq., and the density between 075095 g/cm3. The oreforming fluids is mesothermal, low salinity and low density hydrothermal system. The oreforming pressure of 397810977 MPa and corresponding oreforming depths of 499900 km is estimated by the fluid inclusions. The oreforming fluid is a H2ONaCl system bearing CO2. The Dashankou gold deposit shows obviously characteristics of orogenic type of gold deposit with better exploration potentiality.

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    Dissolution and supracrustal rocks dating of Xilin Gol Complex,Inner Mongolia,China.
    GE Meng-Chun, ZHOU Wen-Xiao, XU Xiang, SUN Dun-Dun, BAO Jian-Quan, WANG Shi-Hai
    2011, 18(5): 196-205. 
    Abstract ( 2245 )   PDF (4080KB) ( 1948 )  

     There are different opinions on the existence of microcontinents in Central Asian Orogenic Belt (CAOB) and on the formation age and original rock property of the widely outcropped Xilin Gol Complex. The Xilin Gol complex comprises geologic bodies of different rock types, different metamorphic degrees, various structural styles and different forming ages. We proposed to disintegrate the Xilin Gol Complex and select the supercrustal rocks there among to be named as “Xilinhot Group”, which are aluminumrich argillaceous clastic rocks with amphibolite facies metamorphism and with volcanic and magnetitequartzite intercalated. The group was emplaced by a metagabbro at 739.6 Ma (SHRIMP age) and by an Stype gneissose tourmaline twomica granite formed during the Ordovician with the zircon metamorphotic cores of UPb ages concentrated in 10051026 Ma. The study of isotopic geochronology also shows that the group was reformed by a series of thermal events later. In combination with the regional tectonic evolution, it is suggested that the Xilinhot Group was possibly formed during the Mesoproterozoic, which may prove the existence of Precambrian metamorphic basement rock series in the region, and provide the corroboration for the existence of Xilinhot microblocks.

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    Diagenetic numerical modeling and tight sandstone reservoir types prediction of the Member 3 of the Denglouku Formation of  the Xujiaweizi Fault Depression.
    CHENG Zhong-Beng, MENG Yuan-Lin, TIAN Wei-Zhi, MENG Fan-Jin, WANG Jian-Wei, XU He, BO Xue-Mei, WANG Wei-An, JIANG Hua-Feng
    2011, 18(5): 196-205. 
    Abstract ( 3023 )   PDF (1799KB) ( 1073 )  

     To predict the reservoir type and quality of the tight sandstones of  the Member 3 of the Denglouku Formation in the deep horizons of the Xujiaweizi Fault Depression, Songliao Basin, the diageneses of clastic rocks are divided into the period A of early diagenetic stage, the period B of early diagenetic stage, the subperiod A1 of middle diagenetic stage, the subperiod A2 of middle diagenetic stage, the subperiod B1 of middle diagenetic stage, the subperiod B2 of middle diagenetic stage, the period A of late diagenetic stage and the period B of late diagenetic stage on the base of the exploration results of the deep horizons and the reservoir testing data. The tight sandstone reservoirs in the period A and period B of late diagenetic stage can not produce commercial gas flows. As the result of statistical analysis of the reservoir porosity and permeability data show, the tight sandstone reservoir property or reservoir qualities in the Xujiaweizi Fault Depression are dominantly controlled by sedimentary facies and diageneses, and the combinations of different sedimentary facies and diagenetic facies form three kinds of different tight sandstone reservoirs, typeⅡ, typeⅢ, and type Ⅳ. By modeling the variation of paleotemperature, vitrinite reflectance, sterane isomerization, clay mineral transformation, and authigenic quartz formation with time, the diagenetic evolution history is modeled and the lateral distribution of the diagentic stage and diagentic facies are predicted. Considering the integrated effects of sedimentary facies and diageneses on the reservoir property, the tight sandstone reservoir types and quality of the Member 3 of the Denglouku Formation are predicted laterally by diagenetic numerical modeling and diagenetic facies analysis combining the sedimentary facies. At present the well producing commercial gas flows are mainly located in the reservoirs of typeⅡ or typeⅢ.No commercial gas flow is produced in the tight sandstone reservoirs of type Ⅳ which are mainly distributed in the period A and the period B of late diagenetic stage or located in the shallow lake facies. The main factor caused the diagenetic differences is depth.

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    Precise IDTIMS zircon UPb age and wholerock geochemistry of the Nanlinshan mafic intrusion in the southern Lancangjiang arc terrane, Sanjiang area, SW China.
    LI Gang-Zhu, SU Chang-Guo, LEI Wei-Yan, DUAN Xiang-Dong
    2011, 18(5): 206-212. 
    Abstract ( 1862 )   PDF (1427KB) ( 1002 )  

     The Nanlinshan gabbroic intrusion occurred in the southern Lancangjiang arc terrane, Sanjiang area, SW China, which consists of gabbro and diorite. The UPb age of zircons from the diorite determined by IDTIMS is 29844±033 Ma. The diorite and gabbro samples are all characterized by moderate enrichment of light rareearth elements relative to heavy rareearth elements and depletion in some high field strength elements such as Nb, Ta, Zr, and Hf. These characteristics are similar to that of the island arc, and the Nanlinshan intrusion can be considered as an evidence for intraoceanic subduction in the Early Permian in the region.

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    Insitu zircon geochronology and Hf isotope of muscovitebearing leucogranites from Fanjingshan, Guizhou Province, and constraints on continental growth of the Southern China block.
    WANG Min, DAI Chuan-Gu, WANG Xue-Hua, CHEN Jian-Shu, MA Hui-Zhen
    2011, 18(5): 213-223. 
    Abstract ( 2137 )   PDF (2261KB) ( 1575 )  

    The Fanjingshan Mountain in northeast Guizhou Province is located in the southwestern segment of the Jiangnan orogenic belt, and consists of the early Neoproterozoic, late Neoproterozoic and Paleozoic strata. The early Neoproterozoic strata were strongly folded and then intruded by numerous muscovitebearing leucogranites. Both the folded strata and granites were unconformably covered by the Nanhua to Paleozoic strata. Insitu zircon U/Pb analyses reveal the emplacement age of 8385±15 Ma for the leucogranite. Geochemical studies demonstrate that the leucogranite is strongly peraluminous with low to medium CaO/Na2O values (009052) and high A/CNK value >11 (127130), suggesting that they likely have resulted from a high temperature (>875 ℃) partial melting of clayrich psammitic rocks. The supposed super mantle plume started at ca. 840 Ma may have provided extra heat for the hightemperature partial melting. Insitu zircon Hf isotope suggests two stages of continent growth before the Neoproterozoic for the South China block.

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    Geochemical characteristics and zircon LAICPMS UPb dating  of Galale skarn gold(copper) deposit, Tibet and its significance.
    LV Li-Na, CUI Yu-Bin, SONG Liang, DIAO Yuan-Yi, QU Xiao-Meng, WANG Jiang-Peng
    2011, 18(5): 224-242. 
    Abstract ( 2477 )   PDF (4877KB) ( 2189 )  

    The Galale gold (copper) deposit is located in the west section of Bangong lakeNujiang suture zone in Tibet. It is a gold (of large scale) and copper (of small scale) skarn deposit. There are mainly huge porphyritic quartz diorite, middlefine grain granodiorite and diorite porphyrite in the mine area. The REE differential degree of rock sample in this ore deposit has a relatively higher value, and Eu negative anomaly is weak. The content of Al2O3 is 14.45%15.84%. The aluminum supersaturation index (A/CNK) ranges between 1.33 and 1.46, which is greater than 1, indicating its being Stype granite. According to the analysis of trace elements, the magmatic body belongs to MPG. The forming stage is close to the collision stage. The result of zircon LAICPMS dating indicates that the age of huge porphyritic quartz diorite is 131±17 Ma, that of the middlefine grain granodiorite is 86.52±0.41 Ma, and those of the two diorite porphyrites are 88.59±0.45 Ma and 88.09±0.41 Ma. Among them, the huge porphyritic quartz diorite is a nonmineralization magmatic body, and the dating data represents the lower limit of the mineralization age. The coppergold orebody was only produced in the contact zone of the middlefine grain granodiorite and the diorite porphyrite magmatic body with the limestone and the siltstone with silicalite. So it was mineralized in the stage of Yanshan. According to the result of dating, the evolutionary process of this ore deposit can be approximately divided into two stages: the invasion of nonmineralization magmatic bodyhuge porphyritic quartz diorite in the early cretaceous and the formation of mineralization magmatic body in the late Cretaceous. They occurred in the Cretaceous, the fourth stage of Prototethys tectonic evolution, i.e., the orogenesis stage of arccontinent collision.

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    Research on the nappe structure and its relevance to the mineralization in the  Huangbi deposit, North Wuyi, Southeast China.
    QIU Jun-Ting, TU Xin-Qi, TUN Gan-Guo, JUE Wen-Dun, DI Yong-Jun, ZHANG Da, LUO Beng, DU An-Dao
    2011, 18(5): 243-255. 
    Abstract ( 1966 )   PDF (7778KB) ( 1242 )  

    The nappe structures in Huangbi mining district, North Wuyi, Southeast China are NNE oriented with dip angles towards WNW. It was found in field investigation that the nappe structures  destroyed the previous Mo deposit on one hand, while their secondary fissures  obviously controlled the distribution of later PbZn deposit. Integrating SHRIMP UPb zircon, ReOs and 39Ar40Ar dating results, this paper reports the order of the tectonicsmagmatismmineralization processes in Huangbi district. The ReOs dating result of 154 Ma shows that the molybdenite was formed during the Late Jurassic. The SHRIMP UPb zircon analyses yield consistent ages of 138±1 Ma for trachyandesite porphyry and 131±2 Ma for rhyolitic crystal tuff from Shengmikeng ore block in Huangbi ore field, indicating that the magmatic activity took place during the Early Cretaceous. And the 39Ar40Ar age of 129 Ma for Kfeldspar from fault zone F1 suggests that the regional nappe structures occurred no later than 129 Ma. PbZn ore body occupied the crannies caused by thrust faults, so its formation is later than that of the nappe structures, which indicating another magmatic hydrothermal activity once occurred after the one in the early Cretaceous. Thus, the nappe structures in Huangbi mining district have both ore destruction and  formation properties.

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    Some problems in the study of the genesis of Xigeda Formation.
    XU Ze-Min, LIU Wen-Lian
    2011, 18(5): 256-270. 
    Abstract ( 1588 )   PDF (5940KB) ( 2187 )  

    The vertical superimposition relationship between the Xigeda Formation and its overlying, underlying fluvial gravel layers is of great significance for indicating sedimentary environment. The Xigeda Formation, which is mainly made of horizontally laminated mottled finegrained deposits often containing sandwiches of tens of centimeters of fluvial gravel layers, and the silt layers frequently contain crossbedding and crosslamination. The fluviallacustrine characteristics and the bottom currents in Xigeda lakes should be taken into account in the study of the genesis of the formation. The mineral components of Xigeda finegrained deposits and the rock types of gravel layers within Xigeda Formation change with the geographic locations of outcrops. Contemporaneous deformation structures and faults develop in some Xigeda Formation distribution regions. Xigeda outcrops are scattered at the southeast margin of QinghaiTibet plateau, but highly depend on the current river systems, either tracking some master stream and its tributaries to form branchy structures or only distributing along the master stream to form rodlike structures, which suggests that Xigeda Formation deposited after current river system had arisen and has a genetic relation with the river systems. The highest height difference among Xigeda outcrops is up to 2290 m and there are often outcrop elevation jumps among different Xigeda Formation distribution regions. Xigeda Formation deposited primarily in landslidedammed lakes; secondly in sag ponds derived from local subsidence of rivers, which developed along the fault zone.

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    Some problems in the study of the genesis of Xigeda Formation.
    Liu-Chang-Zheng, CHEN Yue-Long, HU Guang, DIAO Juan, LI Yue, LI Lin-Ye, JI Bing-Yan, HONG Yuan-Kui
    2011, 18(5): 271-282. 
    Abstract ( 1748 )   PDF (2158KB) ( 1072 )  

    The vertical superimposition relationship between the Xigeda Formation and its overlying, underlying fluvial gravel layers is of great significance for indicating sedimentary environment. The Xigeda Formation, which is mainly made of horizontally laminated mottled finegrained deposits often containing sandwiches of tens of centimeters of fluvial gravel layers, and the silt layers frequently contain crossbedding and crosslamination. The fluviallacustrine characteristics and the bottom currents in Xigeda lakes should be taken into account in the study of the genesis of the formation. The mineral components of Xigeda finegrained deposits and the rock types of gravel layers within Xigeda Formation change with the geographic locations of outcrops. Contemporaneous deformation structures and faults develop in some Xigeda Formation distribution regions. Xigeda outcrops are scattered at the southeast margin of QinghaiTibet plateau, but highly depend on the current river systems, either tracking some master stream and its tributaries to form branchy structures or only distributing along the master stream to form rodlike structures, which suggests that Xigeda Formation deposited after current river system had arisen and has a genetic relation with the river systems. The highest height difference among Xigeda outcrops is up to 2290 m and there are often outcrop elevation jumps among different Xigeda Formation distribution regions. Xigeda Formation deposited primarily in landslidedammed lakes; secondly in sag ponds derived from local subsidence of rivers, which developed along the fault zone.

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     The study of characteristics and types of geomagnetic field.
    LIU Quan-Wen
    2011, 18(5): 283-288. 
    Abstract ( 1445 )   PDF (990KB) ( 1190 )  

    Aiming at the problem of magnetic axis of the earth in the study of geomagnetic field origin, and based on analyzing geomagnetic field characteristics, the geomagnetic field may be categorized as different types in terms of its origin and its array configuration of formation. This paper proposes that the geomagnetic field not only has mutability and bipolarity but also has instantaneity and invariance, and the influencing factors are analyzed. The paper indicates that the geomagnetic field has a bipartite structure, and that different classified methods have different results, e.g., the geomagnetic field can be classified into dynamic magnetic field and law magnetic field, and it can be also classified into the magnetic field that turns around its own axis and the magnetic field that turns around the ecliptic pole axis. The geomagnetic field is a resultant magnetic field assembled by some individual magnetic fields. This study provides the condition for correctly understanding the constitution of the geomagnetic field.

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     Abundance of elements in stream sediment in South China.
    CHENG Zhi-Zhong, XIE Hua-Jin, BO Han-Jiang, YANG Rong, SHANG Yun-Chao
    2011, 18(5): 289-295. 
    Abstract ( 1672 )   PDF (659KB) ( 1125 )  

    The stream sediment samples were collected from 12 provinces in South China covering 230 million km2. About 100 samples within each 1∶50000 map sheet were mixed to make up one composite sample. 5244 composite samples were submitted for analysis. The 76 elements were analyzed including 39 elements originally analyzed in the RGNR Projects, and 37 new elements. The analytical scheme is based largely on ICPMS, ICPAES and XRF, supplemented with other techniques. The lowest levels of detection of all elements are less than their crustal abundances. The background values of 76 elements were calculated in Southern China and compared them with the average of national stream sediments, the flood plain sediments, and national sediments and soil. Hg, Cd are highly enriched, REE, As, B, Co, Ni, Pb and other 24 kinds of elements are enriched in Southern China, Na2O, CaO, Ba, and Sr in the sediments are depleted in Southern China.

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     The key technologies of advanced reservoir characterization.
    WANG Zhi-Zhang, HAN Hai-Yang
    2011, 18(5): 296-302. 
    Abstract ( 1434 )   PDF (3603KB) ( 1909 )  

     Modern reservoir description advocates the integration of exploration and development, the match of seismic and logging information, the combination of static and dynamic information, and finally to advance the description from qualitative to quantitative. This paper focuses on the modern reservoir characterization which integrates the high resolution petrophysical data, the middle resolution logging data and the low resolution seismic data. In the modern reservoir characterization, the technology of automatic division and correlation of reservoirs and reservoir architecture analysis, the technology of sedimentary microfacies automatic identification, and the technology of waveform diversity analysis, which are the technologies applied in the highyield gas area prediction, are applied to the description and prediction of different types of reservoirs in different exploration and development stages.

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    Model study of monitoring and early warning of rainstorm induced landslide and debris flow based on digital landslide technology.
    WANG Chi-Hua, GUO Zhao-Cheng, DU Meng-Liang, CHENG Zun-Lan
    2011, 18(5): 303-309. 
    Abstract ( 1550 )   PDF (994KB) ( 1592 )  

    Chinese research on the rainstorm induced landslide and debris flow forecast have promoted the digital landslide technology to be applied for landslide, debris flow motoring and early warning. There are three basic principles of modeling for rainstorm induced landslide, debris flow monitoring and early warning based on digital landslide technology. The primary is the modeling must be abided by the geology principles of landslide and debris flow. Moreover, the actual situation of the study area must be taken into account during modeling. And finally, the model factors selected is limited by remote sensing methods. According to the three principles, the modeling progress divided into six steps: (1)establishing the conceptual model in view of physical relationship between geological environment and rainfall conditions of landslide and debris flow; (2)defining the essential geological environment factors and establishing the hazard evaluation expression; (3)finding some index to impress moderately the essential geological environmental factors; (4)determining the weight of indexes according to the study area, the disasters status and the environmental characteristics; (5)defining the critical value for rainfall; (6)building mathematical expression.

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    Stability of biogenic schwertmannite in acidic solution.
    XIE Huo, ZHOU Li-Xiang
    2011, 18(5): 310-318. 
    Abstract ( 1703 )   PDF (1505KB) ( 836 )  

    Schwertmannites are secondary minerals widespread in acid mine drainages, and their development and transformations are controlled by environmental factors such as temperature, pH, and coexisting ions. In this study, the effects of temperature and ion concentration on the stability and transformation of biogenic and Ascontaining schwertmannites were investigated. The results showed that the increase of aging temperature favored mineral phase transformations (MPT): for schwertmannites with and without As incubated for 15 weeks, MPT did not take place at 4 ℃, but partially occurred at 40 ℃. In addition, the change of potassium ion concentration resulted in different aging products of schwertmannites: for the biogenic schwertmannites incubated  for 15 weeks, the major aging products were goethite and jarosite/goethite at potassium ion concentrations of 0.01 mM and 100 mM, respectively; for the As(Ⅲ)containing schwertmannites incubated for 15 weeks, MPT did not occur when potassium ion concentration was 0.01 mM, whereas partial MPT took place and jarosite was the major aging products. Moreover, when exposed to temperature or pH fluctuation, As(Ⅲ)containing schwertmannite appeared to be more stable than pure schwertmannite.

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    The effect of deepsea hydrothermal vent organisms on the mineralization.
    YOU Ji-Yuan, ZHOU Ding-Wu, SHU Xiao-Hui
    2011, 18(5): 319-330. 
    Abstract ( 1683 )   PDF (3067KB) ( 1575 )  

     The discovery of deepsea hydrothermal vents and associated biological group is one of the most important scientific achievements in global ocean science in the last 20 years. Around the Black Smoker, there is an extreme environment with hightemperature, highpressure, darkness, hypoxia, sulfur, etc., and there is a special biological community in the deepsea. As the primary producers, thermophilic bacteria and archaea not only affect the deposition of minerals around the vents, but also directly or indirectly affect the dissolution, adsorption, extraction, and transformation of mineral elements, which causes the generation of Fe, Mn, nonferrous metal oxide, sulfide, silicate and carbonate minerals and compounds in precipitation. It is important for the deepsea mineral deposit enrichment.

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