地学前缘 ›› 2010, Vol. 17 ›› Issue (1): 120-130.

• 论文 • 上一篇    下一篇

滇西地区富碱斑岩中地幔流体作用踪迹及其成矿作用意义

  

  1. 1成都理工大学 地球科学学院, 四川 成都 610059
    2中国地质大学(武汉) 地质过程与矿产资源国家重点实验室, 湖北 武汉 430074
  • 出版日期:2010-01-28 发布日期:2010-01-28
  • 作者简介:刘显凡(1957—),男,博士,教授,博士生导师,主要从事矿物学、岩石学和矿床地球化学研究。Email: liuxianfan@cdut.cn
  • 基金资助:

    国家自然科学基金项目(40773031,40473027),中国地质大学(武汉)地质过程与矿产资源国家重点实验室开放基金项目(GPMR2007,GPMR0509);成都理工大学矿物学、岩石学、矿床学国家重点(培育)学科建设项目(SZD0407)

 Actual traces of mantle fluid from alkalirich porphyries in western Yunnan, and associated implications to metallogenesis.

LIU  Xian-Fan, CA  Yong-Wen, LEI  Qiu-Xia, DAO  Zhuan, DIAO  Fu-Feng, CA  Fei-Ti, LI  Chun-Hui, SONG  Xiang-Feng   

  1. ,
    Li Chunhui1,Song Xiangfeng11Institute of Earth Science, Chengdu University of Technology, Chengdu 610059,  China
    2State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences(Wuhan), Wuhan 430074, China
  • Online:2010-01-28 Published:2010-01-28

摘要:

滇西地区大量产出的富碱斑岩及其包体岩石的形成和演化与该区新生代陆内变形、构造作用、幔源岩浆和深源流体活动,及其与此有关而广泛发育的内生多金属矿产存在必然的联系。本文通过岩相学、岩石化学、电子探针、扫描电镜和能谱分析,较为系统地分析论证了这一关联的内在统一制约和联系的纽带即深部地质过程和由此相伴的含矿地幔流体作用,初步揭示了这种深部过程和地幔流体作用的微观踪迹和方式可以直接表现为:(1)呈脉状和浸染状穿插于深源包体岩石中的富钠玻璃,透光镜下呈微晶和雏晶,颜色随成分差异而不均匀,化学成分以高硅、铝、钠、铁,低钾、钙、镁为特征,矿物成分以钠长石、角闪石、磁铁矿(镜铁矿)、钛铁矿组合为特征,是富碱岩浆携带包体岩石之前即已存在的上地幔流体;(2)呈脉状、团块状和浸染状穿插于主岩和各类包体岩石的富铁玻璃;(3)呈独立包体产出于霓辉正长斑岩中的富铁熔浆包体。后两者物质在透光镜下无光性,呈黑色不透明,反光镜下不反光,但在电子显微镜下呈显微晶质结构,化学成分以高硅、铝、铁,低钙、镁、钠、钾为特征,矿物组成上以硅酸盐和石英为主,含有碳硅石、含铬自然铁、钛铁矿、磷灰石等地幔标志矿物,其中微晶金属和非金属矿物之间呈熔离结构交生,反映了地幔流体的熔浆性质及其与富碱岩浆不混溶的特征;由地幔流体对岩石的交代浸染作用,引起主岩和包体岩石中普遍发育各种蚀变作用,如角闪石化、硅化和绿泥石化等,并导致矿物组合总体上表现为暗色矿物由辉石→角闪石→黑云母→绿泥石的退变序列。该地幔流体微观踪迹的三种表现形式与富碱岩浆共存,并共同运移,但两者由于组成和性质的差异而互不混溶;结合透岩浆流体成矿作用理论和本文论证的综合分析认为,当富碱岩浆和地幔流体系统封闭较好,地幔流体则伴随富碱岩浆的结晶过程对富碱斑岩进行同步自交代蚀变,在斑岩体或其深部形成矿床,构成正岩浆成矿体系,典型成矿实例如马厂箐斑岩钼矿床;若在此成岩成矿过程中发生构造作用扰动,则地幔流体进入岩体与围岩的接触带,或紧邻接触带的地层围岩中进行交代蚀变成矿,构成接触带成矿体系,典型成矿实例如马厂箐矿区中赋存于夕卡岩—大理岩带中的斑岩型铜矿和主要赋存于地层围岩中的斑岩型金矿,若金矿出现在斑岩体内,则一般受控于穿切斑岩体的成岩后断裂;若岩浆和流体运移通道的深大断裂体系发育,环境相对开放,则地幔流体伴随富碱岩浆的成岩过程而脱离岩浆沿分支断裂通道进入远离岩体的不同地层岩石中进行交代蚀变成矿,构成远程热液成矿系统,典型成矿实例如兰坪金顶超大型铅锌矿床;在这一成矿过程中,地幔流体可以随深度和环境变化引起的物理化学条件变化,其性质由熔浆→超临界流体→液相流体转化,并运载和沿途活化成矿物质至适宜容矿部位集中,促使幔壳物质叠加成矿;进而有利于深部成矿并形成大型和超大型矿床。

关键词: 关键词:富碱斑岩, 富铁熔浆包体, 富钠与富铁玻璃, 地幔流体与岩浆不混溶作用, 流体交代蚀变成矿, 滇西地区

Abstract:

The formation and evolution of plentiful alkalirich porphyries with deepxenoliths have an inevitable connection to the Cenozoic continental deformations, tectonisms, mantle magmas, anatectic fluids, and associated abundant polymetallic deposits. By the petrographical and petrochemical studies and the analyses using electron microprobe, scanning electron microscopy and energy spectroscopy, we confirmed that the connection was brought about by the deep geological processes and the action of orebearing mantle fluids. Microscopic traces and existing modalities of the processes and the action can be directly manifested as the following: (1)Narich glasses, which show as microlites and embryonic crystals under optical microscope, interpenetrated among deepxenoliths in a veined or disseminated manner. The colour of the glass changes with its composition and it is not uniform. The chemical composition of the glass is characterized by high Si, Al, Na and Fe, and low K, Ca, and Mg; the mineral composition is characterized by the assemblage of albite, amphibole, magnetite (specularite) and ilmenite. The microlite glass was formed from the upper mantle fluid before the xenoliths having been caught by the alkalirich magma.(2)Ferich glasses interpenetrated in a veined, agglomerated or disseminated manner among the host rocks and various xenoliths.(3)Black microcrystalline ironrich melt xenoliths as independent xenoliths existed in aegerine syenite porphyry. Both the above (2) and (3) entities are of submicroscopic crystalline texture under electron microscope, but almost no any demonstration of optical properties under transmitted or reflected light, only appeared as black opaque materials under optical microscope. Their chemical compositions are characterized as high Si, Al and Fe, and low Ca, Mg, Na and K. Their main mineral compositions are silicate and quartz, as well as moissanite, native iron with chromium, specularite with titanium, ilmenite, apatite etc. The unmixing texture, which is assumed to be caused by the unmixing of minerals between micrometal and nonmetal, indicates that the mantle fluid has the properties of magmatic melt and is unmixing with alkalirich magma. Alterations developed widely, such as hornblendication, silification and chloritization etc., and the corresponding retrograde reaction in order of pyroxeney→amphibole→biotite→chlorite resulted in the mantle fluid disseminating and replacing the host rocks and xenoliths Both of alkalirich magma and mantle fluid, which showed abovementioned three microscopic traces and modalities, coexisted and migrated together, but unmixed because of the differences of compositions and properties. On the basis of synthesis analyses and in combination with the theory of metallogenesis by transmagmatic fluid, we may draw the following conclusions: that the alkalirich porphyries were synchronically selfreplaced and alterated by the mantle fluid accompanying the process of alakalirich magma crystallizing while the fluid and magma was trapped well, and the orthomagmatic metallogenic system was formed in magma body or its depths, and the typical deposit of orthomagmatic metallogenic system is the Machangqing porphyry Modeposit; that if the perturbation of tectonization happened in the process of diagenesis and metallogenesis, the mantle fluid would enter into the contact zone between magma body and wall rock or strata next to the contact zone, and the replacing and alterating took place to form the contactmetasomatic metallogenic system, the typical ones of which are the Machangqing porphyry Cudeposit existing in skarnmarble zone, and the porphyry Audeposit existing mainly in stratum rocks; that if the Audeposit existed in porphyry body, it was commonly controlled by the fractures occurring after diagenesis; that if the deep fractures, as magma and fluid channels, were well developed, and environment was relatively open, the orebearing mantle fluid would flow far from the alkalirich magma along branch fractures, entered into different strata and rocks, and the replacing and alterating occurred along with the process of diagenesis to form the remote epithermal metallogenic system, the typical one of which is the Lanping Jinding superlarge PbZn deposit; in this process, the mantle fluid's properties were changed from magma→supercritical fluid→liquid by the changes of depth and environment, and the corresponding changes of physical and chemical conditions, and the moving fluid carried, activated and enriched orematerial to suitable places; it was the deep process and the action of fluid that accelerated crustmantle materials overlapping mineralization, facilitated the deep oreforming and benefited the formation of large and superlarge deposits.

Key words: alkalirich porphyry, ironrich melt xenoliths, Narich and Ferich glasses, unmixing action for mantle fluid and magma, fluid replacing and alternating mineralization, western Yunnan

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