地学前缘 ›› 2019, Vol. 26 ›› Issue (5): 129-145.DOI: 10.13745/j.esf.sf.2019.8.4

• 矿床地质地球化学 • 上一篇    下一篇

南秦岭夏家店金矿床赋矿黑色岩系元素地球化学及其成矿意义

李声浩,朱赖民,丁乐乐,熊潇,刘凯   

  1. 1. 西北大学 地质学系; 大陆动力学国家重点实验室, 陕西 西安 710069
    2. 西北有色地质勘查局713总队, 陕西 商洛 726000
  • 收稿日期:2018-06-19 修回日期:2019-08-29 出版日期:2019-09-28 发布日期:2019-09-28
  • 通讯作者: 朱赖民(1966—),男,教授,博士生导师,主要从事矿床学、矿床地球化学研究。
  • 作者简介:李声浩(1994—),男,硕士研究生,矿物学、岩石学、矿床学专业。E-mail:lshnwu@foxmail.com
  • 基金资助:
    国家自然科学基金项目(41730426,41421002,41272092);西北大学大陆动力学国家重点实验室科学技术部专项基金和研究生创新人才培养项目(YZZ17190)

Elemental geochemistry of the ore-bearing black rock series in the Xiajiadian gold deposit, South Qinling and their metallogenic significance

LI Shenghao,ZHU Laimin1,DING Lele,XIONG Xiao,LIU Kai   

  1. 1. Department of Geology, Northwest University; State Key Laboratory of Continental Dynamics, Xian 710069, China
    2. Number 713 Team of Northwest Mining and Geological Exploration Bureau for Nonferrous Metals, Shangluo 726000, China
  • Received:2018-06-19 Revised:2019-08-29 Online:2019-09-28 Published:2019-09-28
  • Supported by:
     

摘要: 夏家店金矿床位于扬子板块早古生代被动大陆北缘的柞水—山阳盆地内,其赋矿黑色岩系的岩性主要为浅红色硅质岩、蓝灰色蚀变硅泥质岩、灰黑色薄层碳硅质板岩、土黄色泥质板岩和黑色碳硅泥质岩。黑色岩系主量元素、微量元素以及稀土元素分析结果表明:其主要成分为SiO2,并在硅质岩中含量最高,其中大离子亲石元素及成矿元素明显富集,如Sr、Ba、U、Cu、Zn、V、Au和Ag等元素含量均较高,是地壳丰度的几倍到几十倍;硅质岩样品总体呈弱负Ce异常、弱负异常或正Eu异常,泥质岩类显示Ce、Eu负异常,而少数碳硅质岩样品则表现出Eu的正异常,它们的北美页岩标准化稀土配分模式曲线均为向左缓倾。结合黑色岩系的岩石学特征和产出的大地构造环境以及主量、微量和稀土元素特征参数比值和判别图解,研究表明夏家店黑色岩系的成岩物质来源具有多样性,其下部的硅质岩主要为热水沉积的产物,随着海水及陆源物质的逐渐加入,在热水沉积逐渐向正常沉积所转化的过程中,形成碳硅质岩与泥质岩。夏家店金矿床赋矿黑色岩系形成于大陆边缘深水半深水滞留缺氧盆地环境,属扬子板块被动陆缘裂陷沉积区。夏家店金矿床赋矿黑色岩系超常富集Au、Ag、Ni、Cu、Zn、V和Ba等元素,黑色岩系可能是该矿床的重要矿源层。

 

关键词: 夏家店金矿床, 黑色岩系, 元素地球化学, 成矿环境

Abstract: The Xiajiadian gold deposit is located at the passive continental northern margin of the Yangtze Block in the Early Paleozoic and within the ZhashuiShanyang Basin. The black rock series of the Xiajiadian gold deposit consist of light-red siliceous rocks, blue-grey altered siliceous argillaceous rocks, gray-black thin-layer carboncaceous-siliceous slate, khaki argillite and black carbonaceous-siliceous argillaceous rocks. In this study, we carried out systematic analyses of the major and trace elements and REEs in the black rock series. The main component of the series was SiO2, the highest abundant component in the siliceous rocks. These rocks were significantly enriched in LILE and ore-forming elements (e.g. Sr, Ba, U, Cu, Zn, V, Au and Ag), whose contents reached several or even dozens of times higher than their crustal abundance. The North American shale-normalized REE patterns of the black rock series were left inclined and characterized by weak negative Ce and negative to positive Eu anomalies for the siliceous rocks, negative Ce and Eu anomalies for the argillite, and positive Eu anomalies for some minor carboncaceous-siliceous rocks. Combining the petrologic characteristics and tectonic settings, as well as characteristic parameter ratios and discrimination diagrams of major and trace elements and REEs, the results indicate that the diagenetic materials of these black rock series had diverse sources. The lower siliceous rocks are mainly products of hydrothermal sedimentation. They formed carboncaceous-siliceous rocks and argillite during the transformation from hydrothermal to normal sedimentation with added seawater and terrestrial materials. The black rock series in the Xiajiadian gold deposit are formed in a deep to semi-deep water retention and hypoxia basin at the continental margin belonging to the rift deposition area of passive continental margin of the Yangtze Block. The fertile black rock series of the Shuigoukou Formation in the Xiajiadian gold deposit are likely to be an important source bed with super high level enrichment of Au, Ag, Ni, Cu, Zn, V, Ba and other elements.

Key words: Xiajiadian gold deposit, black rock series, elemental geochemical characteristic, metallogenic environment

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